• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.2
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• pp.199-207
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• 2015

Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.3
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• pp.245-248
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• 2020

The wettability of silicon carbide (SiC) crystal, which has 6H-SiC and 4H-SiC regions prepared using the physical vapor transport (PVT) method, is quantitatively analyzed using dispensed deionized (DI) water droplets. Regardless of the polytypes in SiC, the average of five contact angle measurements showed a difference of about 6° between the Si-face and C-face. The contact angle on the Si-face (C-face) is measured after the removal of the native oxide using BOE (6:1), and revealed a significant decrease of the contact angle from 74.9° (68.4°) to 47.7° (49.3°) and from 75.8° (70.2°) to 51.6° (49.5°) for the 4H-SiC and 6H-SiC regions, respectively. The contact angle of the Si-face recovered over time during room temperature oxidation in air; in contrast, that of the C-face did not recover to the initial value. This study shows that the contact angle is very sensitive to SiC surface polarity, specific surface conditions, and process time. Contact angle measurements are expected to be a rapid way of determining the surface polarity and wettability of SiC crystals.

• Atmosphere
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• v.29 no.4
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• pp.343-353
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• 2019

The seasonal climatology of atmospheric rivers (ARs) and their effects on the seasonal precipitation and temperature in Korea are examined using the AR chronology obtained by a methodology based on the vertically integrated water vapor transport (IVT) in conjunction with a fine-scale gridded analysis of station precipitation and temperature. ARs are found to affect Korea most heavily in the warm season with minimal impacts in winter. This contrasts the AR effects in the western North America and the Western Europe that are affected most in winters. Significant portions of precipitation in Korea are associated with AR landfalls for all seasons; over 35% (25%) of the summer (winter) rainfall in the southern part of the Korean peninsula. The percentage of AR precipitation over Korea decreases rapidly towards the north. AR landfalls are also associated with heavier-than-normal precipitation events for all seasons. AR landfalls are associated with above-normal temperatures in Korea; the warm anomalies increase towards the north. The warm anomalies during AR landfalls are primarily related to the reduction in cold episodes as the AR landfalls in Korea are accompanied by anomalous southerlies/southwesterlies.

• Journal of Korea Water Resources Association
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• v.53 no.11
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• pp.1039-1047
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• 2020

Atmospheric rivers, which transport large amount of water vapor from mid-latitude to the inland, are an important driving force of water cycle and extreme hydrologic phenomenas. The main objective of this study is to analyze the hydrological impact of the AR landfalls on the Korean Peninsula in 2000 - 2015. The result showed that the AR is closely related to the characteristics of precipitation, water level and runoff in the Korean Peninsula. The landfalls of the AR affected about 57% of annual precipitation on the Korean Peninsula, and had a greatest impact on the summer rainfall. It also affected the water level and runoff at the five major rivers of Korea, and water levels exceeding the thresholds of flood warning were observed when the AR landed. Moreover, it was found that the runoff above the third quartile with AR landfalls. These results suggest that the AR not only has a significant influence on the hydrological characteristics of the Korean Peninsula, but also have a close relationship with the extreme hydrological events like floods. The results of this study are expected to be used as the reference for the analysis of the impact of the AR on the various fields in the Korean Peninsula.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E3
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• pp.137-148
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• 2003

In this study, we examined the influence of long-range transport of dust particles and air pollutants on the photochemistry of NO$_3$on Jeju Island, Korea (33.17 N, 126.10$^{\circ}$E) during the Asian Dust-Storm (ADS) period of April 2001. Three ADS events were observed during the periods of 10∼12, 13∼14, and 25∼26 April. Average concentration level of nighttime NO$_3$on Jeju Island during the ADS period was estimated to be about 2 x 10$^{8}$ molecules cm$^{-3}$ ( - 9 pptv). Decreases in NO$_3$levels during the ADS period was likely to be determined mainly by the enhancement of the $N_2$O$_{5}$ heterogeneous reaction on dust aerosol surfaces. The reaction of N20s on aerosol surfaces was a more important sink for nighttime N03 during the ADS due to the significant loading of dust particles. The reaction of $N_2$O$_{5}$ with NMHCs and the gas-phase reaction of N20s with water vapor were both significant loss mechanisms during the study period, especially during the NADS. However, dry deposition of these oxidized nitrogen species and a heterogeneous reaction of NO$_3$were of no importance. Short-term observations of $O_3$, NO$_2$, DMS, and SO$_2$in the MBL indicated that concentrations of most of these chemical species were different between the ADS and non - Asian - Dust-Storm (NADS) periods, implying that their levels were affected sensitively by the differences in air mass trajectories.

• Fashion & Textile Research Journal
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• v.17 no.6
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• pp.1020-1029
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• 2015

This paper investigated the wearing performance of knitted fabrics made of air vortex yarns using PTT/tencel/cotton fibres in comparison with ring and compact yarns for emotional garment. Wicking property of knitted fabric made of MVS yarns was worse than those by ring and compact yarns, however, drying property of knitted fabric made of MVS yarns was better than those by ring and compact yarns, which was explained as more water vapor transport due to larger openness between fibres in the MVS yarns than those in the ring and compact yarns. Thermal conductivity of knitted fabric made of MVS was lower than those of ring and compact yarns and maximum heat flow(Q_max) at the transient state of MVS knitted fabric was lower than those of ring and compact yarns, which may be attributed to MVS yarn structure that has parallel fibres in the core part of the yarn and fasciated fibre bundles on the sheath part with roughness on the yarn surface. However, pilling of MVS knitted fabric was better than those by ring and compact yarns, which was caused by less and shorter hairy fibres protruded from MVS yarn surface than those of ring and compact yarns. It was observed that tactile hand of MVS yarn knitted fabrics was stiffer than those of ring and compact yarns knitted fabrics. It was explained by low extensibility and compressibility and high bending and shear rigidities of the MVS yarn knitted fabrics, which resulted in bad wearing performance of MVS knitted fabric.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.429-429
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• 2002

This study examines the influence of long-range transport of dust particles and air pollutants on photochemistry of OH and NO$_3$ at Jeju Island (33.17$^{\circ}$ N, 126.10$^{\circ}$ E) during the Asian dust-storm (ADS) period in April 2001. The atmospheric concentrations of criteria pollutants (O$_3$, NO$_2$, CO) and sulfur species were measured at a ground station on Jeju Island, Korea as part of the ACE-Asia intensive operation. Three ADS events were observed during the periods of 10-12, 13-14, and 25-26 April, respectively. The concentrations of the criteria pollutants (i.e., $O_3$, NO$_2$, and SO$_2$) were not significantly different from those during the non-Asian-dust-storm (NADS) period. Average OH and NO$_3$ levels at Jeju Island during the study period (ADS and NADS) were estimated to be 4-10 $\times$ 10$^{5}$ moleculescm$^{-3}$ and 2-4 pptv, respectively. Two main sources of OH radical were the primary production from the reaction of water vapor ($H_2O$) and O(1D) radicals and the reaction of HO$_2$ with NO. CO was a dominant sink of OH during the ADS period: whereas NO$_2$ was the most important during the NADS period. for NO$_3$ radical, a reaction of NO$_2$ with $O_3$ was the most important atmospheric source; while $N_2$O$_{5}$ uptake on dust particles was the most dominant sink during the ADS period.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.5.1-5.1
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• 2010

One of the most important environmental problems is global warming. Global warming is caused by increase in the amounts of water vapor, methane, carbon dioxide and other gases being released into the atmosphere as a result of the burning of fossil fuels. It has thus become important to reduce fossil fuel use. Environmentally friendly preparation of functional materials has, therefore, attracted much interest for environmental problems. Furthermore, nature mimetic processes are recently been of great interest as environmentally friendly one. There have been many studies on fabrication of various functional nanocrystals. Among various nanocrystal fabrication techniques, flux growth is an environmentally friendly, very convenient process and can produce functional nanocrystals at temperatures below the melting points of the solutes. Furthermore, this technique is suitable for the synthesis of crystals having an enhedral habit. In flux growth, the constituents of the materials to be crystallized are dissolved in a suitable flux (solvent) and crystal growth occurs as the solution becomes critically supersaturated. The supersaturation is attained by cooling the solution, by evaporation of the solvent or by a transport process in which the solute is made to flow from a hotter to a cooler region. Many kinds of oxide nanocrystals have been grown in our laboratory. For example, zero- (e.g., particle), one- (e.g., whisker and tube) and two-dimensional (e.g., sheet) nanocrystals were successfully grown by flux method. Our flux-growth technique has some industrial and ecological merits because the nanocrystal fabrication temperatures are far below their melting points and because the used reagents are less harmless to human being and the environment.

• Atmosphere
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• v.20 no.2
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• pp.131-151
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• 2010

This study establishes a conceptual model to analyze heavy rainfall events in Korea using multi-functional transport satellite-1R satellite images. Three heavy rainfall episodes in two major synoptic types, such as synoptic low (SL) type and synoptic flow convergence (SC) type, are analyzed through a conceptual model procedure which proceeds on two steps: 1) conveyer belt model analysis to detect convective area, and 2) cloud top temperature analysis from black body temperature (TBB) data to distinguish convective cloud from stratiform cloud, and eventually estimate heavy rainfall area and intensity. Major synoptic patterns causing heavy rainfall are Changma, synoptic low approach, upper level low in the SL type, and upper level low, indirect effect of typhoon, convergence of tropical air in the SC type. The relationship between rainfall and TBBs in overall well resolved areas of heavy rainfall. The SC type tended to underestimate the intensity of heavy rainfall, but the analysis with the use of water vapor channel has improved the performance. The conceptual model improved a concrete utilization of images and data of satellite, as summarizing characteristics of major synoptic type causing heavy rainfall and composing an algorism to assess the area and intensity of heavy rainfall. The further assessment with various cases is required for the operational use.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• v.25 no.1
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• pp.57-81
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• 1997

Numerical prediction of nocturnal thermal high in summer of the 1995 near Taegu city located in a basin has been carried out by a non-hydrostatic numerical model over complex terrain through one-way double nesting technique in the Z following coordinate system. Under the prevailing westerly winds, vertical turbulent fluxes of momentum and heat over mountains for daytime hours are quite strong with a large magnitude of more than $120W/\textrm{m}^2$, but a small one of $5W/\textrm{m}^2$ at the surface of the basin. Convective boundary layer (CBL) is developed with a thickness of about 600m over the ground in the lee side of Mt. Hyungje, and extends to the edge of inland at the interface of land sea in the east. Sensible heat flux near the surface of the top of the mountain is $50W/\textrm{m}^2$, but its flux in the basin is almost zero. Convergence of sensible heat flux occurs from the ground surface toward the atmosphere in the lower layer, causing the layer over the mountain to be warmed up, but no convergance of the flux over the basin results from the significant mixing of air within the CBL. As horizontal transport of sensible heat flux from the top of the mountain toward over the basin results in the continuous accumulation of heat with time, enhancing air temperature at the surface of the basin, especially Taegu city to be higher than $39.3^{\circ}C$. Since latent heat fluxes are $270W/\textrm{m}^2$ near the top of the mountain and $300W/\textrm{m}^2$ along the slope of the mountain and the basin, evaporation of water vapor from the surface of the basin is much higher than one from the mountain and then, horizontal transport of latent heat flux is from the basin toward the mountain, showing relative humidity of 65 to 75% over the mountain to be much greater than 50% to 55% in the basin. At night, sensible heat fluxes have negative values of $-120W/\textrm{m}^2$ along the slope near the top of the mountain and $-50W/\textrm{m}^2$ at the surface of the basin, which indicate gain of heat from the lower atmosphere. Nighttime radiative cooling produces a shallow nocturnal surface inversion layer with a thickness of about 100m, which is much lower than common surface inversion layer, and lifts extremely heated air masses for daytime hours, namely, a warm pool of $34^{\circ}C$ to be isolated over the ground surface in the basin. As heat transfer from the warm pool in the lower atmosphere toward the ground of the basin occurs, the air near the surface of the basin does not much cool down, resulting in the persistence of high temperature at night, called nocturnal thermal high or tropical night. High relative humidity of 75% is found at the surface of the basin under the moderate wind, while slightly low relative humidity of 60% is along the eastern slope of the high mountain, due to adiabatic heating by the srong downslope wind. Air temperature near the surface of the basin with high moisture in the evening does not get lower than that during the day and the high temperature produces nocturnal warming situation.