• Journal of Astronomy and Space Sciences
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• v.34 no.3
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• pp.207-212
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• 2017

During the last glacial-interglacial transition, there were multiple intense climatic events such as the Bølling-Allerød warming and Younger Dryas cooling. These events show abrupt and rapid climatic changes. In this study, the climate events and cycles during this interval are examined through wavelet analysis of Arctic and Antarctic ice-core $^{18}O$ and tropical marine $^{14}C$ records. The results show that periods of ~1383-1402, ~1029-1043, ~726-736, ~441-497 and ~202-247 years are dominant in the Arctic region, whereas periods of ~1480, ~765, ~518, ~311, and ~207 years are prominent in the Antarctic TALDICE. In addition, cycles of ~1019, ~515, and ~209 years are distinct in the tropical region. Among these variations, the de Vries cycle of ~202-209 years, correlated with variations in solar activity, was detected globally. In particular, this cycle shows a strong signal in the Antarctic between about 13,000 and 10,500 yr before present (BP). In contrast, the Eddy cycle of ~1019-1043 years was prominent in Greenland and the tropical region, but was not detected in the Antarctic TALDICE records. Instead, these records showed that the Heinrich cycle of ~1480 year was very strong and significant throughout the last glacial-interglacial interval.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.5 s.236
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• pp.545-553
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• 2005

In the present study, The characteristics of developing steady laminar flows of a straight duct connected to a $180^{\circ}$ curved duct were examined In the entrance region through experimental measurement. Flow characteristics such as shear stress distributions, pressure distributions and friction coefficient experimentally in a square cross-sectional straight duct by using the PIV system. For the PIV measurement by particles produced from mosquito coils particles. The experimental data were obtained at 9 points dividing the test sections by 400mm. Experimental results can be summarized as follows. Critical Reynolds number, $Re_{cr}$ which indicates transition from laminar steady flow to transition steady flow was 2,150. Shear stress per unit length on the wall was stronger than that in the fully developed flow region. This was attributed to the fact that shear stress and pressure loss in the curvature of a duct were increased. Pressure distributions were gradually decreased irrespective of Reynolds number In the whole test section. This trends were in a good agreement with the reference results. Pipe friction coefficient in the steady state flow region was calculate from method of least squares. The co-relationship between fiction coefficient and Reynolds number was established as follow; ${\lambda}=56/Re$.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.1145-1150
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• 2003

Zr-based bulk metallic glasses have a significant mechanical properties such as high strength and elastic strain limit, and a good processing ability due to the deformation behavior such as superplasticity under supercooled liquid region. Recently, many researches on the determination of optimum working condition in various bulk metallic glasses have been carried out. In this study, the deformation behavior and forming conditions of $Zr_{55}Cu_{30}Al_{10}Ni_{5}$ bulk metallic glass were investigated under three different strain rates and at various temperatures between 627K and 727K. The glass transition temperature, crystallization temperature and supercooled liquid region of $Zr_{55}Cu_{30}Al_{10}Ni_{5}$ bulk metallic glass are 680K, 762K and 82K, respectively.

• Bulletin of the Korean Chemical Society
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• v.25 no.9
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• pp.1361-1365
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• 2004

Solvatokinetic and solvatochromic behavior of bis(indolinobenzospiropyranyl) sulfide derivatives 1a-1c have been studied in various solvents. The marked negative solvatochromism is exhibited for 1a and 1b in the whole region of solvent polarity examined. Whereas, it is found only in the polar solvent region ($E_T$ > 37) for 1c. The sensitivity order to the solvent media (slope values) is 1a > 1b > 1c. The branched linear plot with a zero slope was shown for the most sterically-hindered compound 1c in the less polar-solvent region (($E_T$ < 37). The biphasic plot is indicative of dual mechanistic process, i.e., a transition state with increased zwitter-ionic character in more polar solvents and electrocyclic process with an isopolar transition state in less polar solvents.

• Journal of Astronomy and Space Sciences
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• v.36 no.3
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• pp.121-131
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• 2019

The ionospheric mid-latitude trough (IMT) is the electron density depletion phenomenon in the F region during nighttime. It has been suggested that the IMT is the result of complex plasma processes coupled to the magnetosphere. In order to statistically investigate the characteristics of the IMT, we analyze topside sounding data from Alouette and ISIS satellites in 1960s and 1970s. The IMT position is almost constant for seasons and solar activities whereas the IMT depth ratio and the IMT feature are stronger and clearer in the winter hemisphere under solar minimum condition. We also calculated transition heights at which the densities of oxygen ions and hydrogen/helium ions are equal. Transition heights are generally higher in daytime and lower in nighttime, but the opposite aspects are seen in the IMT region. Utilizing the Incoherent Scatter Radar (ISR) electron temperature measurements, we find that the electron temperature in the IMT region is enhanced at night during winter. The increase of electron temperature may cause fast transport of the ionospheric plasma to the magnetosphere via ambipolar diffusion, resulting in the IMT depletion. This mechanism of the IMT may work in addition to the simply prolonged recombination of ions proposed by the traditional stagnation model.

• Bulletin of the Korean Chemical Society
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• v.9 no.6
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• pp.368-376
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• 1988

Transition metal PSSA ionomers containing Co(II), Ni(II), Cr(III), Ru(III), and Rh(III) are investigated by IR, Far-IR, UV-Vis and DSC. Reliable IR Spectroscopic criteria are established for assessing the degree of ion-exchange of PSSA ionomers and the local structures around metal cations in them. In the hydrated transition metal PSSA ionomers, the ionic groups are solvated by water molecules and there is no significant interactions between sulfonate group and metal cations. The visible spectra indicated that metal cations are present as [M$(H_2O)_6$]$^{n+}$ with Oh symmetry. Their $T_g$ values increase as the extent of ionic site concentration increases, but there is no direct dependence of $T_g$ on the nature of metal cations or their oxidation states. Thus, the water content in PSSA ionomer is found to have dominant influence on $T_g$ of hydrated transition metal PSSA ionomers. Dehydration of the hydrated transition metal PSSA ionomers results in direct interaction between ionic groups and significant color changes of the ionomers due to the changes of the local structures around metal cations. On the base of spectral data, their local structures are discussed. In case of dehydrated 12.8 and 15.8 mol % transition metal PSSA ionomers, no glass transition is observed in 25-$250^{\circ}C$ region and this is believed to arise from the formation of highly crosslinked structures caused by direct coordination of sulfonate groups of metal cations. In the 6.9 mol % transition metal PSSA ionomers, the glass transition is always observed whether they are hydrated or dehydrated and this is though to be caused by the sufficient segmental mobility of the polymer backbone.

• Journal of the Korean Magnetics Society
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• v.4 no.2
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• pp.154-159
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• 1994

The magneto-optical Kerr spectra(${\lambda}=250~700nm$) of amorphous RE-Co(RE=Ce, Nd, Pr, Gd, Tb, Er, Ho) are compared with those of Y-Co films. It has been found that the Kerr rotation of RE-Co is mainly due to Co in the long wavelength region, whereas at short wavelength Ce, Pr, Nd, and Gd contribute positively, and Tb, Ho, and Er contribute negatively to the Kerr rotation of RE-Co amorphous films. In the interesting energy region(1.5~5.0 eV), the magneto-optical contribution of Pr and Nd are thought to be related with $4f{\uparrow}->5d{\uparrow}$ interband transition, and the contribution of Ce and Gd might be concerned with d->p interband transition. The magneto-optical effect of Tb in the short wavelength region might be related with $4f{\downarrow}->5d{\downarrow}$ and/or $5d{\downarrow}->4f{\downarrow}$, and that of Ho and Er can be explained by $4f{\downarrow}->5d{\downarrow}$ magneto-optical interband transition.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.687-690
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• 2002

Multimode boundary-layer transition on a NACA0012 airfoil is experimentally investigated under periodically passing wakes and the moderate level of free-stream turbulence. The periodic wakes are generated by rotating circular cylinders clockwise or counterclockwise around the airfoil. The free-stream turbulence is produced by a grid upstream of the rotating cylinder, and its intensity(Tu) at the leading edge of the airfoil is $0.5\;or\;3.5\;{\%}$. The Reynolds number ($Re_c$) based on chord length (C) of the alrfoil is $2.0{\times}10^5$, and Strouhal number ($St_c$) of the passing wake is about 0.7. Time- and phase-averaged streamwise mean velocities and turbulence fluctuations are measured with a single hot-wire probe, and especially, the corresponding wall skin friction is evaluated using a computational Preston tube method. The wake-passing orientation changes pressure distribution on the airfoil in a different manner irrespective of the free-stream turbulence. Regardless of free-stream turbulence level, turbulent patches for the receding wakes propagate more rapidly than those for the approaching wake because adverse pressure gradient becomes larger. The patch under the high free-stream turbulence ($Tu=3.5{\%}$) grows more greatly in laminar-like regions compared with that under the low background turbulence ($Tu=0.5{\%}$) in laminar regions. The former, however, does not greatly change the original turbulence level in the very near-wall region while the latter does it. At further downstream, the former interacts vigorously with high environmental turbulence inside the pre-existing transitional boundary layer and gradually lose his identification, whereas the latter keep growing in the laminar boundary layer. The calmed region is more clearly observed under the lower free-stream turbulence level and for the receding wakes. The calmed region delays the breakdown further downstream and stabilizes more the boundary layer.

• 전기의세계
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• v.30 no.7
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• pp.441-447
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• 1981

As a preceeding work for the study on dielectric characterstics of a kind of low density polyethylene introduced morphological change by mechanical method, glass transition temperature which is regarded as a macroscopic aspect for relaxation of molecular chain segments has been observed by means of temperature dependent dilatometric measurement. The origina specimen clearly shows two knees which correspond to two peaks (.gamma. and .betha. peak) in the intenal friction measurement, suggesting the existence of separated glass transition temperatures at 150.deg.k and 260.deg.k respectively. On the specimen irradiated to 100 Mrad both glass transition temperatures tend to shift towards high temperature sides because of crosslinking by irradiation. furthemore an evidence can be seen that radiation effect, even in amorphous phase, is also slelctive depending on slight morphological differences. The specimen extended to four times in length shows a peculiar nature such as negative linear thermal expansion coefficient increasing with temperature between 220.deg.k and ambient temperature and that this fact is interpreted by considering that c axis of the lattice aligns along the extended direction by drawing, further c axis inherently possesses the characteristics of negative linear thermal expansion coefficient. For the observations that the relatively small positive linear expansion on the specimen extended to ca. two times as well as the part below 220.deg.k of the specimen extended to four times, it is considered for the reason of the facts that the incompletely oriented region indicated as the middle part of Peterlin's model tends to restore partially to orginal arrangement-a kind of phase transition-as increasing with temperature.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2007.04a
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• pp.421-426
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• 2007

A parametric study to investigate the effects of composition variables on the glass transition and mechanical properties of CNT-based nanocomposites was performed using molecular dynamics simulations. In this study, matrix chain length and CNT length were chosen as the candidate characteristic parameters. In order to understand the effect of both parameters in detail, three sample sets having different chain lengths with the same CNT configuration and two sample sets having different CNT lengths with same chain length were prepared. Other parameters such as volume fraction and density were fixed to enable rigorous comparisons. Amorphous polyethylene is used as matrix polymer and (10,0) zigzag CNT is embedded into the matrix to reinforce polymer matrix. As a result, longer polymer chain length of matrix solely increased glass transition temperature but no reinforcing enhancement was observed. CNT length showed similar increase with little enhancement of elastic modulus. In addition to this, nanocomposites showed temperature-dependent elastic modulus jump passing thorough the glass transition region agrees well with experimental results.