• Bulletin of the Korean Chemical Society
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• v.29 no.6
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• pp.1167-1172
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• 2008

We investigated the glass transition temperatures ($T_g$) of dendrons consisting of conformationally mobile aliphatic polyether dendritic cores plus glassy peripheral polystyrenes (PSs), and linear PSs in the molecular weight range of 1000-8500 g/mol. We compared their $T_g$ behavior depending on their polymeric architecture. The linear PSs show a typical growth of $T_g$ up to 92.5 ${^{\circ}C}$ as the molecular weight increases to 8300 g/mol, while the dendrons display nearly constant $T_g$ values of 58-61 ${^{\circ}C}$, despite the increase of molecular weight with each generation. The striking contrast of Tg behavior would be mainly attributed to the fact that the dendrons keep the ratio of $N_e$/M ($N_e$: number of peripheral chain ends, M: molecular weight) over all the generations. Additionally, for the influence of dendritic spacers on glass transition temperature we prepared dimeric PSs with different linkage groups such as aliphatic ether, ester and amide bonds. We found that the dimer with the ether spacer exhibited the lowest glass transition at 55.4 ${^{\circ}C}$, while the amide linked dimer showed the highest glass transition temperature at 74.2 ${^{\circ}C}$. This indicates that the peripheral PS chains are effectively decoupled by the conformationally flexible ether spacer. The results from this study demonstrated that polymeric architecture and dendritic core structures play a crucial role in the determination of glass transition behavior, providing a strategy for the systematic engineering of polymer chain mobility.

• Carbon letters
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• v.17 no.1
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• pp.53-64
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• 2016

Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were promoted by the dual transition metals of iron and cobalt (Fe, Co), which were incorporated into the N-doped carbons lattice by subsequently heat treatments. All the prepared carbons were characterized by via transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). To evaluate the activities of synthesized doped carbons, linear sweep was recorded in an acidic solution to compare the ORR catalytic activities values for the use in the PEMFC system. The dual transition metal promotion improved the ORR activity compared with the single transition metal promotion, due to the increase in the quaternary nitrogen species from the structural change by the dual metals. The effect of different ratio of the dual metals into the N doped carbon were examined to evaluate the activities of the oxygen reduction reaction.

• Health Policy and Management
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• v.24 no.3
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• pp.242-253
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• 2014

Background: The low benefit coverage rate of South Korea's health security system causes catastrophic health expenditure. And catastrophic health expenditure can be the cause of the transition to and persistence of poverty. This study was conducted to ascertain the effect of catastrophic health expenditure on the transition to and persistence of poverty, using 6 years of the Korea Welfare Panel Study Data. Methods: This study was conducted among the 22,528 households that participated in the Korea Welfare Panel Study, 2007-2012. Catastrophic health expenditure was defined as equal to or exceeds thresholds (10%, 20%, 30%, and 40%) of household's capacity to pay. The effect of catastrophic health expenditure on the transition to and persistence of poverty was ascertained via multivariate logistic regression. Results: Four-point-seven percent to 20.6% of the households are facing catastrophic health expenditure. Rates of the transition to (relative risk [RR], 18.6 to 30.2) and persistence of (RR, 74.8 to 76.0) poverty of households facing catastrophic health expenditure was higher than households not facing catastrophic health expenditure. Even after adjusting the characteristics of the household and the household head, catastrophic health expenditure was found to affect transition to (odds ratio [OR], 2.11 to 3.04) and persistence of (OR, 1.53 to 1.70) poverty. Conclusion: To prevent catastrophic health expenditure and transition to and persistence of poverty resulting from catastrophic health expenditure, the reinforcement of South Korea's health security system including the benefit coverage enhancement is required.

• Journal of the Korean Society for Railway
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• v.17 no.4
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• pp.260-269
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• 2014

Transition tracks are an alternative for enhancing the long-term serviceability and durability of concrete track components in railway bridges. The goal of this paper is to investigate the structural behavior for transition track systems of railway bridge deck ends. In this study, the structural behavior of transition tracks such as the variations in static, dynamic, and fatigue behaviors and dynamic properties (natural frequency and damping ratio) are assessed and compared through performing loading tests and finite element analyses using actual vehicle impact loadings. As a result, it is found that the structural behavior of the transition track system is expected to satisfy the actual vehicle impact loading, and the variation in the neutral axis and dynamic characteristics are not affected by the fatigue loading. Therefore, it is inferred that the structural capacity and long-term durability of the transition track system is proven.

• Geophysics and Geophysical Exploration
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• v.26 no.4
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• pp.199-210
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• 2023

The physical properties of rocks in reservoirs change after CO₂ injection, we modeled a reservoir with a transition zone within which the physical properties change linearly. The function of the Wolf reflection coefficient consists of the velocity ratio of the upper and lower layers, the frequency, and the thickness of the transition zone. This function can be used to estimate the thickness of a reservoir or seafloor transition zone. In this study, we propose a method for predicting the thickness of the transition zone using deep learning. To apply deep learning, we modeled the thickness-dependent Wolf reflection coefficient on an artificial transition zone formation model consisting of sandstone reservoir and shale cap rock and generated time-frequency spectral images using the continuous wavelet transform. Although thickness estimation performed by comparing spectral images according to different thicknesses and a spectral image from a trace of the seismic stack did not always provide accurate thicknesses, it can be applied to field data by obtaining training data in various environments and thus improving its accuracy.

• Applied Chemistry for Engineering
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• v.10 no.7
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• pp.1008-1013
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• 1999

Mechanical properties and morphology of pectin/starch blend films depending upon the composition and plasticizer ratio were studied. Blends were prepared continuously in a twin-screw extruder. Films were prepared using a single-screw extruder with slit die. Most of the blends showed a good thermoplastic behavior, while the blends with very high ratio of pectin/starch had a poor thermoplasticity. Tensile properties of blend films were changed significantly by the amount of glycerol and relatively little by the ratio of pectin/starch. Differential scanning calorimetry(DSC) curves of wet blends showed a transition similar to glass transition temperature(Tg) at about $125^{\circ}C$. It was found by Scanning electron microscopy(SEM) study that there exists a good interfacial adhesion between pectin and starch.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.689-692
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• 2001

In this paper, the pizoelectric and dielectric properties of 0.95Pb(ZrxTil-x)O$_3$- 0.05Pb(Mn$\_$0.2/Fe$\_$0.4/W$\_$0.4/)O$_3$piezoelectric ceramics is investigated as a function of Zr/Ti mole ratio. Also, MPB(Morphotropic Phase Boundary) and optimal sintering temperature is studied using XRD and SEM. As a results, when Zr/Ti mole ratio is 52/48, electromechanical coupling factor, k$\_$p/, is 58[%], permittivity, $\varepsilon$$\^$T/$\_$33//$\varepsilon$0, is 1360 and piezoelectric strain constant, d$\_$33/ is 265[pC/N] and the piezoelectric and dielectric properties become maximum. Phase transition temperature of its ternary piezoelectric system is about 350[$^{\circ}C$]. From the XRD analysis, when Zr/Ti mole ratio is 52/48, tetragonal phase transits to rhombohedral phase. Also, From measuring results of the sintering density, when sintering temperature is 1050[$^{\circ}C$], sintering density become maximum and is about 7930[kg/㎥], and average grain size is about 2-3[$\mu\textrm{m}$].

• International Journal of Aeronautical and Space Sciences
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• v.2 no.1
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• pp.12-19
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• 2001

Study of turbulent mixing layers has been a popular subject from the point of view of both practical application and phenomenological importance in engineering field. Turbulent mixing layers can be applied in many fields where rapid transition to turbulence is desirable in order to prevent boundary layer separation or to enhance mixing. The ability to control mixing, structure and growth of the shear flow would obviously have a considerable impact on many engineering applications. In addition to practical applications, free shear flows are one of the simplest flows to understand the fundamental mechanism in the transition process to turbulence. After the discovery of large-scale vortical structure in free shear flows many researchers have investigated the physical mechanism of generation and dissipation processes of the vortical structure. This study investigated the role of the large-scale vortical structures in the turbulent mixing layer using LES(Large-Eddy Simulation). The result shows that the pairing interaction of the vortical structure plays an important role in the growth rate of a mixing layer. It is found that the turbulence quantities depend strongly on the velocity ratio. It is also found that the vorticity in the high-velocity-side can extract energy from the mean flow, while the vorticity in the low-velocity-side lose energy by the viscous dissipation. Finally the results suggest the guideline to obtain the desired flow by control of the velocity ratio.

• Journal of the Korean Ceramic Society
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• v.28 no.10
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• pp.819-823
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• 1991

Pure zirconia ceramic fiber experiences severe volume changes through thermal cyclings of heating and cooling. Zirconia fiber was doped with CaO to stabilize the phase and its effect of CaO was studied on volumetric ratio of each phases, phase transition temperature and microstructure. Tetragonal phase was increased as CaO increases up to 10 mol% and cubic phase was stabilized when CaO was added more than 10 mol%. The average grain size of zirconia fiber was increased as CaO increased and transition temperature was shifted to lower temperature.

• Journal of Electrical Engineering and Technology
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• v.12 no.6
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• pp.2237-2246
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• 2017

A nonisolated two-phase bidirectional dc-dc converter (NTPBDC) is a very attractive solution for the battery energy storage system (BESS) applications due to the high voltage conversion ratio and the reduced conduction loss of the switching devices. However, a hard-switching based NTPBDC decreases the overall voltage conversion efficiency. To overcome this problem, this paper proposes a novel NTPBDC with zero-voltage-transition (NTPBDC -ZVT). The soft-switching for the boost and buck main switches is achieved by using a resonant cell, which consists of a single resonant inductor and four auxiliary switches. Furthermore, due to the single resonant inductor, the proposed NTPBDC-ZVT has the advantages of simple implementation, reduced size, and low cost. The validity of the proposed NTPBDC-ZVT is verified through experimental results.