• 제목/요약/키워드: transition ratio

검색결과 808건 처리시간 0.033초

Effect of phenothiazine derivatives on the thermotropic phase transition of liposomal phospholipid membrane

  • Han, Suk-Kyu;Kim, Nam-Hong;Lee, Yong-Soo
    • Archives of Pharmacal Research
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    • 제9권2호
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    • pp.75-79
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    • 1986
  • The effect of phenothiazine derivatives on the thermotropic transition of liposomal lipid bilayer made of dipalmitoyl phosphatidylchline and dipalmitoyl phosphatidic acid was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayer incorporated with levomepromazine, chlopromazine, prochloperazine, perphenazine and fluphenazine were obtained and the size of cooperative unit of the transition were calculated from the ratio of the van't Hoff enthalpy change to the calculated enthalpy change of the transition. The results showed that incorporation of phenothiazine derivatives into the liposomal bilayer reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. Phenothiazine derivatives also significantly reduced the size of cooperative unit of the transition. The effect of the drugs was proportional to the concentration of the drug in the bilayer. This means that phenothiazine derivatives might have significant fluidizing effects on the biomembrane. The sizes of cooperative unit were successfully corrlated with phar-macological activities of the drugs and the surface pressure increases of lipid monolayer by these drugs. These correlations might be ascribed to a possible hydrophobic nature of interaction between the biomembrane and the drugs involved in their pharmacology.

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일체형 로켓-램제트 모드 천이 및 불안정 연소 유동장 해석 (Numerical Analysis on the Mode Transition of Integrated Rocket-Ramjet and Unstable Combusting Flow-Field)

  • 고현;박병훈;윤웅섭
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2005년도 제24회 춘계학술대회논문집
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    • pp.334-342
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    • 2005
  • A numerical analysis is performed using two dimensional axisymmetric RANS (Reynolds Averaged Navier-Stokes) equations system on the transition sequence of the Integrated Rocket Ramjet and the unsteady reacting flow-field in a ramjet combustor during unstable combustion. The mode transition of an axisymmetric ramjet is numerically simulated starting from the initial condition of the boost end phase of the entire ramjet. The unsteady reacting flow-field within combustor is computed for varying injection area. In calculation results of the transition, the terminal normal shock is occurred at the downstream of diffuser throat section and no notable combustor pressure oscillation is observed after certain time of the inlet port cover open. For the case of a small injection area at the same equivalence ratio, periodic pressure oscillation in the combustor leads to the terminal shock expulsion from the inlet and hence the buzz instability occurred.

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스크램제트 엔진에서의 모드 천이에 관한 수치해석 연구 (Numerical Study on Mode Transition in a Scramjet Engine)

  • 하정호;;;김태호;김희동
    • 한국추진공학회지
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    • 제21권6호
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    • pp.21-31
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    • 2017
  • 본 연구에서는 모드 천이가 발생하는 동안 상세한 유동 특성을 조사하기 위해, 이론분석과 수치해석을 수행하였다. 이론분석은 기존의 기체역학과 종래 보고된 이론식들 재정립하였으며, 수치해석은 2차원 비정상 압축성 Navier-Stokes 방정식을 풀기 위해 fully implicit finite volume scheme을 사용해 수행하였다. 해석의 검증을 위하여 실험 결과와 비교하였다. 격리부 입구 전온도와 수소 연료의 당량비를 변화시키면서 모드 천이에 미치는 영향을 조사하였다. 해석과 실험 결과는 정성적으로 잘 일치하였다. 당량비가 증가하면 스크램제트 모드에서 램제트 모드로 천이가 발생하였다. 이 때, 천이는 당량비에 따라 불연속적으로 나타나며, Non-allowable region이 존재하였다. 한편 격리부 입구에서 전온도의 증가는 모드 천이 경계를 변화시켰다.

Synchronic time ratio를 이용 시간 페트리 네트로 모델링된 시스템의 최적 성능에 필요한 초기 조건 결정 (Initial requirements to the optimal performance of systems modeled by timed place Petri nets using the synchronic time ratio)

  • 고인선;최정환
    • 제어로봇시스템학회논문지
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    • 제3권1호
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    • pp.101-108
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    • 1997
  • The initial token value required to the optimal performance of discrete event systems can be decided by Sum of Delay Time and Synchronic Time ratio, which are new synchronic variables in Timed Place Petri Nets. For the system consisting of two Live-and-Bounded circuits(LB-circuits) fused in common Transition-Transition-Path or common Place-Place-Path, we prove that the Synchronic Time Ratio is the initial token ratio between two LB-circuits to optimally perform system functions. These results are generalized and formulated as a theorem. The initial tokens of a specific place can imply shared resources. Using the theorem, we can decide the minimum number of the shared resources to obtain the optimal performance, and minimize the idling time of resources. As an example, an automated assembly system is modeled by Timed Place Petri Net, and the initial tokens to achieve the optimal system performance are identified. All the values are verified by simulation.

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팽창비가 고정된 듀얼 벨 노즐의 천이특성에 대한 수치해석 연구 (Numerical Study on Transition Characteristics of Dual Bell Nozzle with Expansion Ratio Fixed)

  • 최준섭;허환일
    • 한국추진공학회지
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    • 제21권3호
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    • pp.68-75
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    • 2017
  • 듀얼 벨 노즐은 고도 보정 노즐의 일종으로 일반적인 벨 노즐의 탈설계점에서의 비추력 손실을 최소화할 수 있는 노즐이다. 본 논문에서는 팽창비가 고정된 듀얼 벨 노즐의 천이특성을 파악하기 위하여 전산수치해석을 수행하였다. 주요 설계변수로는 확장부 길이와 변곡각 크기를 선정하였다. 확장부 길이가 증가할수록 천이고도 및 천이지속시간은 증가하였고, 추력계수 감소폭은 감소하였다. 변곡각 크기가 증가할수록 천이고도 및 천이지속시간은 감소하였고, 추력계수 감소폭은 증가하였다.

기체주입식 분사기의 이상유동 변화와 분무특성에 관한 연구 (A Study on the Two-Phase Flow Transition and Atomization Characteristics in Effervescent Injectors)

  • 이강영;정하동;강철웅;안규복
    • 한국분무공학회지
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    • 제27권3호
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    • pp.144-154
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    • 2022
  • Gas injection is a technique applied to improve throttling in liquid rocket engines and atomization in effervescent injectors. When a gas is injected into a liquid, it creates a two-phase flow inside the injector. The changes (bubbly flow, slug flow, annular flow, etc.) in the two-phase flow affect the injector's spray characteristics. In this study, cold-flow tests were performed by using three injectors with different orifice diameters and four aerators with different gas injection hole diameters. The experiments were done by changing the thrust ratio (liquid mass flow rate ratio) and gas-liquid mass flow rate ratio. Two-phase flow transition, breakup length, and discharge coefficient according to the injector/aerator design and flow conditions were investigated in detail.

A multi-phase model for predicting the effective chloride migration coefficient of ITZ in cement-based materials

  • Yang, C.C.;Weng, S.H.
    • Advances in concrete construction
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    • 제1권3호
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    • pp.239-252
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    • 2013
  • Mortar microstructure is considered as a three-phase composite material, which is cement paste, fine aggregate and interfacial transition zone. Interfacial transition zone is the weakest link between the cement paste and fine aggregate, so it has a significant role to determine the properties of cementitious composites. In this study, specimens (w/c = 0.35, 0.45, 0.55) with various volume fractions of fine aggregate ($V_f$ = 0, 0.1, 0.2, 0.3 and 0.4) were cast and tested. To predict the equivalent migration coefficient ($M_e$) and migration coefficient of interfacial transition zone ($M_{itz}$), double-inclusion method and Mori-Tanaka theory were used to estimate. There are two stages to estimate and calculate the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$). The first stage, the data of experimental chloride ion migration coefficient ($M_s$) was used to calculate the equivalent migration coefficient of fine aggregate with interfacial transition zone ($M_e$) by Mori-Tanaka theory. The second stage, the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$) was calculated by Hori and Nemat-Nasser's double inclusion model. Between the theoretical and experimental data a comparison was conducted to investigate the behavior of interfacial transition zone in mortar and the effect of interfacial transition zone on the chloride migration coefficient, the results indicated that the numerical simulations is derived to the $M_{itz}/M_m$ ratio is 2.11~8.28. Additionally, thickness of interfacial transition zone is predicted from $10{\mu}m$, 60 to $80{\mu}m$, 70 to $100{\mu}m$ and 90 to $130{\mu}m$ for SM30, M35, M45 and M55, respectively.

Ferrocene-Based Diimine Pd(II) 촉매로 얻은 폴리(메틸메타크릴레이트)의 유리전이온도 (Glass Transition Temperature of Poly(methyl methacrylate) Obtained with Ferrocene-Based Diimine Pd(II) Catalyst)

  • 박태학;이동호;김태정;박동규
    • 폴리머
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    • 제26권3호
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    • pp.410-414
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    • 2002
  • 중심 금속을 안정화시킬 수 있는 ferrocene-based diimine 리간드를 가지고 낮은 산소 친화성을 가진 후전이금속인 Pd 촉매를 합성하여, 극성 단량체인 메틸메타크릴레이트 (MMA)의 중합에 사용하였다. 중합계 내의 impurity scavenger로 triisobutylaluminium (TIBA)를 사용하였을 때에, 중합온도와 [TIBA]/[Pd] 몰비가 생성 중합체(PMMA)의 수율 및 유리전이온도 ($T_g$)에 미치는 영향을 조사하였다. PMMA의 수율은 40~$50^{\circ}C$의 중합온도 및 2000~3000의 [TIBA]/[Pd] 몰비에서 가장 높았다. PMMA의 $T_g$는 중합온도에는 크게 영향을 받지 않으나, [TIBA]/[Pd] 몰비에 의존한다는 것을 관찰할 수 있었다. PMMA의 $T_g$의 변화를 PMMA의 미세구조와 연관시켜 조사한 결과, PMMA의 $T_g$ 이소탁틱도와 직선적 관계를 가짐을 알았다.

Carbon 화이버-폴리머 복합체의 전기적 특성 (Electrical Conductivity of Carbon Fiber-Polymer Composite)

  • 이재연;최경만
    • 한국세라믹학회지
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    • 제35권6호
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    • pp.603-609
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    • 1998
  • The composites of insulating polymer filled with conducting carbon-fiber were fabricated by molding press method. To understand the fiber aspect-ratio dependence of electrical conductivity the aspect ratio was varied from 4 to 10 The percolation thresholds of transition from the insulator to the conductor de-creased as the fiber aspect ratio increased. The percolation threshold of fiber-segregated composite in this study was smaller than that of fiber-random composite shown in other study. When the electrical con-ductivity curves were fitted by general effective medium equation morphological variable(t) decreased as the fiber aspect-ratio increased.

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이량체액정의 PVT측정과 상전이 거동 (PVT Measurement and Phase Transition Behavior of Dimer Liquid Crystals)

  • 남수용
    • 한국인쇄학회지
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    • 제14권1호
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    • pp.17-29
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    • 1996
  • N-substituted acrylamide hydrogel is reported to have the feature of bing transparent and sensitive enough to response to a temperature stimulus below the temperature of phase transition. Especially at the near of 35 C it becomes shrunk and opaque very quickly. It has also the characteristic of reversing swelling and shrinking. The experiment showed that it is possible to produce a functional gel of super water absorption with the process of free radical polymerizing PVA(polyvinylalcohol) and PAA(polyacrylamide), and crosslinking. The ratio of shrinking and swelling caused by copolymerization rises 10% to 80% at the each temperature of 20 C, 30 C, 40 C, respectively. Phase transition temperature of this gel by copolymerization is50 C while that of ordinary N-substituted acrylamides is between 32~35 C. This temperature reaches the rearing limit of animals and plants so that volumetric transition polymer gel can be ulilized in varying fields such as agriculture/gardening which are water-using field, on-off switch sensing temperature and volumetric variation, processing of liquid wastes and civil engineering works, architecture and electronics. We have no doubt that this material will be the high-functional resin in the hi-tech age of the near future.

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