• 한국전기전자재료학회논문지
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• 제37권4호
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• pp.445-450
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• 2024

The expansion of lithium-ion battery usage beyond portable electronic devices to electric vehicles and energy storage systems is driven by their high energy density and favorable cycle characteristics. Enhancing the stability and performance of these batteries involves exploring solid electrolytes as alternatives to liquid ones. While sulfide-based solid electrolytes have received significant attention for commercialization, research on amorphous-phase glass solid electrolytes in oxide-based systems remains limited. Here, we investigate the glass transition temperatures and sintering behaviors by changing the molecular ratio of Li₂O/B₂O₃ in borate glass comprising Li₂O-B₂O₃-Al₂O₃ system. The glass transition temperature is decreasing as increasing the amount of Li₂O. When we sintered at 450℃, just above the glass transition temperature, the samples did not consolidate well, while the proper sintered samples could be obtained under the higher temperature. We successfully obtained the borate glass ceramics phases by melt-quenching method, and the sintering characteristics are investigated. Future studies could explore optimizing ion conductivity through refining processing conditions, adjusting the glass former-to-modifier ratio, and incorporating additional Li salt to enhance the ionic conductivity.

• Elastomers and Composites
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• 제39권2호
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• pp.95-104
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• 2004

방진고무의 내한성을 향상시키기 위하여 NR 컴파운드에 유리전이온도가 상대적으로 낮은 BR을 섞거나 오일 함량을 늘리는 방법을 이용하여 새로운 컴파운드를 제작하였다. 저온환경에서 기계적물성 실험을 수행하여 NR/BR 조성비 및 오일 함량에 따른 영향을 조사하였다. BR 함량이 증가할수록 경도 및 모듈러스가 증가한 반면 인장강도 및 신율은 감소하였고, 오일 함량이 많을수록 경도, 모듈러스 및 인장강도는 감소하였으나 신율은 거의 변화가 없었다. NR/BR 블렌드 고무컴파운드는 NR과 BR의 유리 전이 온도인 $-50^{\circ}C$와 $-90^{\circ}C$에서 저장탄성계수의 급격한 전이와 손실계수인 tan ${\delta}$가 최대값을 보여 두 컴파운드간의 비상용성을 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제29권6호
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• pp.1167-1172
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• 2008

We investigated the glass transition temperatures ($T_g$) of dendrons consisting of conformationally mobile aliphatic polyether dendritic cores plus glassy peripheral polystyrenes (PSs), and linear PSs in the molecular weight range of 1000-8500 g/mol. We compared their $T_g$ behavior depending on their polymeric architecture. The linear PSs show a typical growth of $T_g$ up to 92.5 ${^{\circ}C}$ as the molecular weight increases to 8300 g/mol, while the dendrons display nearly constant $T_g$ values of 58-61 ${^{\circ}C}$, despite the increase of molecular weight with each generation. The striking contrast of Tg behavior would be mainly attributed to the fact that the dendrons keep the ratio of $N_e$/M ($N_e$: number of peripheral chain ends, M: molecular weight) over all the generations. Additionally, for the influence of dendritic spacers on glass transition temperature we prepared dimeric PSs with different linkage groups such as aliphatic ether, ester and amide bonds. We found that the dimer with the ether spacer exhibited the lowest glass transition at 55.4 ${^{\circ}C}$, while the amide linked dimer showed the highest glass transition temperature at 74.2 ${^{\circ}C}$. This indicates that the peripheral PS chains are effectively decoupled by the conformationally flexible ether spacer. The results from this study demonstrated that polymeric architecture and dendritic core structures play a crucial role in the determination of glass transition behavior, providing a strategy for the systematic engineering of polymer chain mobility.

• Carbon letters
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• 제17권1호
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• pp.53-64
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• 2016

Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were promoted by the dual transition metals of iron and cobalt (Fe, Co), which were incorporated into the N-doped carbons lattice by subsequently heat treatments. All the prepared carbons were characterized by via transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). To evaluate the activities of synthesized doped carbons, linear sweep was recorded in an acidic solution to compare the ORR catalytic activities values for the use in the PEMFC system. The dual transition metal promotion improved the ORR activity compared with the single transition metal promotion, due to the increase in the quaternary nitrogen species from the structural change by the dual metals. The effect of different ratio of the dual metals into the N doped carbon were examined to evaluate the activities of the oxygen reduction reaction.

• 보건행정학회지
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• 제24권3호
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• pp.242-253
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• 2014

Background: The low benefit coverage rate of South Korea's health security system causes catastrophic health expenditure. And catastrophic health expenditure can be the cause of the transition to and persistence of poverty. This study was conducted to ascertain the effect of catastrophic health expenditure on the transition to and persistence of poverty, using 6 years of the Korea Welfare Panel Study Data. Methods: This study was conducted among the 22,528 households that participated in the Korea Welfare Panel Study, 2007-2012. Catastrophic health expenditure was defined as equal to or exceeds thresholds (10%, 20%, 30%, and 40%) of household's capacity to pay. The effect of catastrophic health expenditure on the transition to and persistence of poverty was ascertained via multivariate logistic regression. Results: Four-point-seven percent to 20.6% of the households are facing catastrophic health expenditure. Rates of the transition to (relative risk [RR], 18.6 to 30.2) and persistence of (RR, 74.8 to 76.0) poverty of households facing catastrophic health expenditure was higher than households not facing catastrophic health expenditure. Even after adjusting the characteristics of the household and the household head, catastrophic health expenditure was found to affect transition to (odds ratio [OR], 2.11 to 3.04) and persistence of (OR, 1.53 to 1.70) poverty. Conclusion: To prevent catastrophic health expenditure and transition to and persistence of poverty resulting from catastrophic health expenditure, the reinforcement of South Korea's health security system including the benefit coverage enhancement is required.

• 한국철도학회논문집
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• 제17권4호
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• pp.260-269
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• 2014

본 논문의 목적은 철도교량 단부 전환부 궤도의 구조적 거동특성을 평가하는 것이다. 국내 고속철도 교량상 궤도표준단면을 이용하여 전환부 궤도구조를 설계 및 제작하여 피로시험 전, 후에 대한 전환부 궤도시스템의 중립축 및 동특성(고유진동수 및 감쇠비)의 변화를 비롯하여 피로균열 발생경향을 수치해석 결과와 비교, 검토하였다. 연구결과, 국내 고속철도 궤도설계기준을 준용하여 설계한 전환부 궤도시스템에 대한 동특성을 실험적으로 산정하였으며 국내 철도하중 및 충격효과를 고려한 피로하중에 대한 구조적 건전성을 실험 및 해석적으로 입증하였다.

• 지구물리와물리탐사
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• 제26권4호
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• pp.199-210
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• 2023

CO₂ 주입 후 저류층은 암석물리 특성이 변하므로 이 연구에서는 저류층을 물성이 선형으로 변하는 전이대 지층모델로 구성한다. 울프 반사계수 함수는 전이대 상하지층의 속도비, 주파수, 전이대 두께 함수로 구성되어 있어 저류층 두께나 해저면 전이대 두께를 추정하는데 활용할 수 있다. 이 연구에서는 심층학습을 이용하여 전이대 두께를 예측 방법을 제안한다. 심층학습을 적용하기 위해 사암 저류층, 셰일 덮개암으로 구성한 인공 전이대 지층모델에 두께에 따른 울프 반사계수 모델링을 수행하고 시간-스펙트럼 영상자료를 확보하였다. 두께별 시간-주파수 스펙트럼 영상과 중합단면도 트레이스에서 구한 시간-주파수 스펙트럼 비교로부터 구한 두께 추정결과는 항상 정확하게 전이대의 두께를 제시하지는 못하였다. 그러나 다양한 환경에서 학습자료를 확보하고 정확도를 높이면 현장자료적용이 가능할 것으로 본다.

• 공업화학
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• 제10권7호
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• pp.1008-1013
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• 1999

펙틴/전분 블렌드의 열가소성과 펙틴/전분 비와 가소제 함량이 블렌드의 기계적 물성과 형태에 미치는 영향을 조사하였다. 블렌드는 이축 압출기로 제조하였으며 시험용 필름은 슬릿 다이가 부착된 일축 압출기로 제조하였다. 대부분의 블렌드는 열가소성 성질을 가지고 있었으나, 펙틴/전분비가 아주 높은 블렌드는 열가소성 성질이 매우 약하였다. 필름의 인장 물성은 가소제인 글리세롤의 함량에는 크게 변화였으나 펙틴/전분 비의 변화에 대하여는 상대적으로 적게 변화하였다. 습조성 블렌드의 DSC 곡선은 $125^{\circ}C$에서 유리전이온도와 유사한 전이온도를 포함하고 있었다. 파단면의 전자현미경사진은 펙틴과 전분의 계면에서는 접착 현상이 좋다는 것을 보여주었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.689-692
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• 2001

In this paper, the pizoelectric and dielectric properties of 0.95Pb(ZrxTil-x)O$_3$- 0.05Pb(Mn$\_$0.2/Fe$\_$0.4/W$\_$0.4/)O$_3$piezoelectric ceramics is investigated as a function of Zr/Ti mole ratio. Also, MPB(Morphotropic Phase Boundary) and optimal sintering temperature is studied using XRD and SEM. As a results, when Zr/Ti mole ratio is 52/48, electromechanical coupling factor, k$\_$p/, is 58[%], permittivity, $\varepsilon$$\^$T/$\_$33//$\varepsilon$0, is 1360 and piezoelectric strain constant, d$\_$33/ is 265[pC/N] and the piezoelectric and dielectric properties become maximum. Phase transition temperature of its ternary piezoelectric system is about 350[$^{\circ}C$]. From the XRD analysis, when Zr/Ti mole ratio is 52/48, tetragonal phase transits to rhombohedral phase. Also, From measuring results of the sintering density, when sintering temperature is 1050[$^{\circ}C$], sintering density become maximum and is about 7930[kg/㎥], and average grain size is about 2-3[$\mu\textrm{m}$].

• International Journal of Aeronautical and Space Sciences
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• 제2권1호
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• pp.12-19
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• 2001

Study of turbulent mixing layers has been a popular subject from the point of view of both practical application and phenomenological importance in engineering field. Turbulent mixing layers can be applied in many fields where rapid transition to turbulence is desirable in order to prevent boundary layer separation or to enhance mixing. The ability to control mixing, structure and growth of the shear flow would obviously have a considerable impact on many engineering applications. In addition to practical applications, free shear flows are one of the simplest flows to understand the fundamental mechanism in the transition process to turbulence. After the discovery of large-scale vortical structure in free shear flows many researchers have investigated the physical mechanism of generation and dissipation processes of the vortical structure. This study investigated the role of the large-scale vortical structures in the turbulent mixing layer using LES(Large-Eddy Simulation). The result shows that the pairing interaction of the vortical structure plays an important role in the growth rate of a mixing layer. It is found that the turbulence quantities depend strongly on the velocity ratio. It is also found that the vorticity in the high-velocity-side can extract energy from the mean flow, while the vorticity in the low-velocity-side lose energy by the viscous dissipation. Finally the results suggest the guideline to obtain the desired flow by control of the velocity ratio.