• Title/Summary/Keyword: transition ratio

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Effect of phenothiazine derivatives on the thermotropic phase transition of liposomal phospholipid membrane

  • Han, Suk-Kyu;Kim, Nam-Hong;Lee, Yong-Soo
    • Archives of Pharmacal Research
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    • v.9 no.2
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    • pp.75-79
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    • 1986
  • The effect of phenothiazine derivatives on the thermotropic transition of liposomal lipid bilayer made of dipalmitoyl phosphatidylchline and dipalmitoyl phosphatidic acid was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayer incorporated with levomepromazine, chlopromazine, prochloperazine, perphenazine and fluphenazine were obtained and the size of cooperative unit of the transition were calculated from the ratio of the van't Hoff enthalpy change to the calculated enthalpy change of the transition. The results showed that incorporation of phenothiazine derivatives into the liposomal bilayer reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. Phenothiazine derivatives also significantly reduced the size of cooperative unit of the transition. The effect of the drugs was proportional to the concentration of the drug in the bilayer. This means that phenothiazine derivatives might have significant fluidizing effects on the biomembrane. The sizes of cooperative unit were successfully corrlated with phar-macological activities of the drugs and the surface pressure increases of lipid monolayer by these drugs. These correlations might be ascribed to a possible hydrophobic nature of interaction between the biomembrane and the drugs involved in their pharmacology.

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Numerical Analysis on the Mode Transition of Integrated Rocket-Ramjet and Unstable Combusting Flow-Field (일체형 로켓-램제트 모드 천이 및 불안정 연소 유동장 해석)

  • Ko Hyun;Park Byung-Hoon;Yoon Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.334-342
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    • 2005
  • A numerical analysis is performed using two dimensional axisymmetric RANS (Reynolds Averaged Navier-Stokes) equations system on the transition sequence of the Integrated Rocket Ramjet and the unsteady reacting flow-field in a ramjet combustor during unstable combustion. The mode transition of an axisymmetric ramjet is numerically simulated starting from the initial condition of the boost end phase of the entire ramjet. The unsteady reacting flow-field within combustor is computed for varying injection area. In calculation results of the transition, the terminal normal shock is occurred at the downstream of diffuser throat section and no notable combustor pressure oscillation is observed after certain time of the inlet port cover open. For the case of a small injection area at the same equivalence ratio, periodic pressure oscillation in the combustor leads to the terminal shock expulsion from the inlet and hence the buzz instability occurred.

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Numerical Study on Mode Transition in a Scramjet Engine (스크램제트 엔진에서의 모드 천이에 관한 수치해석 연구)

  • Ha, Jeong Ho;Das, Rajarshi;Ladeinde, Foluso;Kim, Tae Ho;Kim, Heuy Dong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.6
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    • pp.21-31
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    • 2017
  • In the present study, theoretical and numerical analyses have been carried out to investigate the detailed flow characteristics during the mode transition. The theoretical analysis rearranged the knowledge of gasdynamics and the previous studies, and the numerical analysis has conducted to solve the 2D unsteady compressible Navier-Stokes equations with a fully implicit finite volume scheme. To validate the numerical analysis, the experiment was compared with it. The total temperature at the inlet of isolator and the hydrogen fuel equivalent ratio were changed to investigate their effects on the mode transition phenomenon. As the results, the numerical analysis reproduced well the experiment qualitatively, the increment in the hydrogen fuel equivalent ratio induced the scram-mode to ram-mode transition which is discontinuous with a non-allowable region, and the variation in the total temperature changed the boundary of the mode transition.

Initial requirements to the optimal performance of systems modeled by timed place Petri nets using the synchronic time ratio (Synchronic time ratio를 이용 시간 페트리 네트로 모델링된 시스템의 최적 성능에 필요한 초기 조건 결정)

  • Go, In-Seon;Choi, Juang-Hwan
    • Journal of Institute of Control, Robotics and Systems
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    • v.3 no.1
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    • pp.101-108
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    • 1997
  • The initial token value required to the optimal performance of discrete event systems can be decided by Sum of Delay Time and Synchronic Time ratio, which are new synchronic variables in Timed Place Petri Nets. For the system consisting of two Live-and-Bounded circuits(LB-circuits) fused in common Transition-Transition-Path or common Place-Place-Path, we prove that the Synchronic Time Ratio is the initial token ratio between two LB-circuits to optimally perform system functions. These results are generalized and formulated as a theorem. The initial tokens of a specific place can imply shared resources. Using the theorem, we can decide the minimum number of the shared resources to obtain the optimal performance, and minimize the idling time of resources. As an example, an automated assembly system is modeled by Timed Place Petri Net, and the initial tokens to achieve the optimal system performance are identified. All the values are verified by simulation.

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Numerical Study on Transition Characteristics of Dual Bell Nozzle with Expansion Ratio Fixed (팽창비가 고정된 듀얼 벨 노즐의 천이특성에 대한 수치해석 연구)

  • Choi, Junsub;Huh, Hwanil
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.68-75
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    • 2017
  • Dual bell nozzle is a type of altitude compensation nozzle, which is a nozzle that minimize the losses of the specific impulse at the off-design point of a typical bell nozzle. In this paper, numerical computations are performed to understand the transition characteristics of dual bell nozzles with fixed expansion ratios. The major design variables are the length of extension and the angle of inflection. As the length of the extension increased, the transition altitude and transition duration increased and the reduction of the thrust coefficient decreased. As the angle of inflection increased, the transition altitude and transition duration decreased and the reduction of the thrust coefficient increased.

A Study on the Two-Phase Flow Transition and Atomization Characteristics in Effervescent Injectors (기체주입식 분사기의 이상유동 변화와 분무특성에 관한 연구)

  • Lee, Kangyeong;Jung, Hadong;Kang, Cheolwoong;Ahn, Kyubok
    • Journal of ILASS-Korea
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    • v.27 no.3
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    • pp.144-154
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    • 2022
  • Gas injection is a technique applied to improve throttling in liquid rocket engines and atomization in effervescent injectors. When a gas is injected into a liquid, it creates a two-phase flow inside the injector. The changes (bubbly flow, slug flow, annular flow, etc.) in the two-phase flow affect the injector's spray characteristics. In this study, cold-flow tests were performed by using three injectors with different orifice diameters and four aerators with different gas injection hole diameters. The experiments were done by changing the thrust ratio (liquid mass flow rate ratio) and gas-liquid mass flow rate ratio. Two-phase flow transition, breakup length, and discharge coefficient according to the injector/aerator design and flow conditions were investigated in detail.

A multi-phase model for predicting the effective chloride migration coefficient of ITZ in cement-based materials

  • Yang, C.C.;Weng, S.H.
    • Advances in concrete construction
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    • v.1 no.3
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    • pp.239-252
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    • 2013
  • Mortar microstructure is considered as a three-phase composite material, which is cement paste, fine aggregate and interfacial transition zone. Interfacial transition zone is the weakest link between the cement paste and fine aggregate, so it has a significant role to determine the properties of cementitious composites. In this study, specimens (w/c = 0.35, 0.45, 0.55) with various volume fractions of fine aggregate ($V_f$ = 0, 0.1, 0.2, 0.3 and 0.4) were cast and tested. To predict the equivalent migration coefficient ($M_e$) and migration coefficient of interfacial transition zone ($M_{itz}$), double-inclusion method and Mori-Tanaka theory were used to estimate. There are two stages to estimate and calculate the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$). The first stage, the data of experimental chloride ion migration coefficient ($M_s$) was used to calculate the equivalent migration coefficient of fine aggregate with interfacial transition zone ($M_e$) by Mori-Tanaka theory. The second stage, the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$) was calculated by Hori and Nemat-Nasser's double inclusion model. Between the theoretical and experimental data a comparison was conducted to investigate the behavior of interfacial transition zone in mortar and the effect of interfacial transition zone on the chloride migration coefficient, the results indicated that the numerical simulations is derived to the $M_{itz}/M_m$ ratio is 2.11~8.28. Additionally, thickness of interfacial transition zone is predicted from $10{\mu}m$, 60 to $80{\mu}m$, 70 to $100{\mu}m$ and 90 to $130{\mu}m$ for SM30, M35, M45 and M55, respectively.

Glass Transition Temperature of Poly(methyl methacrylate) Obtained with Ferrocene-Based Diimine Pd(II) Catalyst (Ferrocene-Based Diimine Pd(II) 촉매로 얻은 폴리(메틸메타크릴레이트)의 유리전이온도)

  • 박태학;이동호;김태정;박동규
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.410-414
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    • 2002
  • The late transition Pd catalyst of low oxophilicity that has ferrocene -based diimine ligand for stabilization of center metal had been synthesized and applied for the polymerization of methyl methacrylate (MMA). In the presence of triisobutylaluminium (TIBA) for impurity scavenger, the effects of polymerization temperature and [TIBA]/[Pd] mole ratio on the yield and glass transition temperature ($T_g$) of PMMA had been examined. For 40~$50^{\circ}C$ of polymerization temperature and 2000~3000 of [TIBA]/[Pd] mole ratio, higher polymer yields were obtained. It was observed that ($T_g$) of PMMA is almost independent to the polymerization temperature but influenced by the [TIBA]/[Pd] mole ratio. With the examination of($T_g$) of PMMA with the structure of polymer, it had been found that T$_{g}$ of PMMA exhibits a linear relationship with the isotacticity of polymer.r.

Electrical Conductivity of Carbon Fiber-Polymer Composite (Carbon 화이버-폴리머 복합체의 전기적 특성)

  • 이재연;최경만
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.603-609
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    • 1998
  • The composites of insulating polymer filled with conducting carbon-fiber were fabricated by molding press method. To understand the fiber aspect-ratio dependence of electrical conductivity the aspect ratio was varied from 4 to 10 The percolation thresholds of transition from the insulator to the conductor de-creased as the fiber aspect ratio increased. The percolation threshold of fiber-segregated composite in this study was smaller than that of fiber-random composite shown in other study. When the electrical con-ductivity curves were fitted by general effective medium equation morphological variable(t) decreased as the fiber aspect-ratio increased.

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PVT Measurement and Phase Transition Behavior of Dimer Liquid Crystals (이량체액정의 PVT측정과 상전이 거동)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.14 no.1
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    • pp.17-29
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    • 1996
  • N-substituted acrylamide hydrogel is reported to have the feature of bing transparent and sensitive enough to response to a temperature stimulus below the temperature of phase transition. Especially at the near of 35 C it becomes shrunk and opaque very quickly. It has also the characteristic of reversing swelling and shrinking. The experiment showed that it is possible to produce a functional gel of super water absorption with the process of free radical polymerizing PVA(polyvinylalcohol) and PAA(polyacrylamide), and crosslinking. The ratio of shrinking and swelling caused by copolymerization rises 10% to 80% at the each temperature of 20 C, 30 C, 40 C, respectively. Phase transition temperature of this gel by copolymerization is50 C while that of ordinary N-substituted acrylamides is between 32~35 C. This temperature reaches the rearing limit of animals and plants so that volumetric transition polymer gel can be ulilized in varying fields such as agriculture/gardening which are water-using field, on-off switch sensing temperature and volumetric variation, processing of liquid wastes and civil engineering works, architecture and electronics. We have no doubt that this material will be the high-functional resin in the hi-tech age of the near future.

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