• 제목/요약/키워드: transition element

검색결과 344건 처리시간 0.029초

완전교번하중하(完全交番荷重下)에서의 강판(鋼板)의 파괴기구(破壞機構)에 관한 기차적(基磋的) 연구(研究) (A Fundamental Study on the Fracture Mechanism of Steel Plates under Completely Alternating Load)

  • 장동일;정영화
    • 대한토목학회논문집
    • /
    • 제2권3호
    • /
    • pp.1-13
    • /
    • 1982
  • 원구멍과 타원구멍을 갖는 두 개의 강판(鋼板)에 완전교번하중(完全交番荷重)(completely reversed load, completely alternating load ;같은 크기의 인장(引張) 압축(壓縮)의 반복)을 가할 때 유한요소법(有限要素法)을 써서 강복요소(降伏要素)가 발생하는 단계마다 각 절점(節點)의 변위(變位), 각 요소(要素)의 응력(應力) 및 변형률(變形率), 하중(荷重)의 크기 등을 계산하여 파괴력학적(破壞力學的)인 검토를 행하였다. 이로부터, 강판(鋼板)의 파괴기구(破壞機構)를 밝히는 데에 핵심이 된다고 생각되는 응력확대계수(應力擴大係數)를 계산할 수 있는 토대가 마련되었으며, 흠선단(先端)의 응력집중(應力集中)현상과 소성역(塑性域)의 변화과정이 밝혀졌다. 또, 재하(載荷) 중에 강복(降伏)을 경험한 부분에서는 강하(降荷)때에 영구변형(永久變形)(잔류변형(殘留變形))이 남게 되고 이것이 나머지의 제하(除荷)를 구속(拘束)하여 반대방향의 재하(載荷)의 효과를 일으킴으로서 흠선단(先端)에 가까운 부분에는 인장(引張) 후의 제하(除荷) 때에 심지어 압축재강복(壓縮再降伏)까지, 압축(壓縮) 후의 제하(除荷) 때에는 심지어 인장재강복(引張再降伏)까지 일으키며 이들이 인장(引張) 및 압축(壓縮)의 재하(載荷) 중의 강복(降伏)과 교번(交番)으로 반복됨으로써 흠선단(先端)에 파로(波勞)현상을 초래하게 된다는 사실을 예견할 수 있었다. 아울러 흠이 원구멍일 때와 타원구멍일 때의 계산결과를 비교하여 홈이 예리한 균열에 가까워질수록 빨리 파괴에 달하게 된다는 사실을 확인할 수 있었다.

  • PDF

A-site Ca 및 B-site Zr 첨가에 의한 BaTiO3-CaTiO3복합체의 유전특성 및 미세구조에 미치는 영향 (Effects of A-site Ca and B-site Zr Substitution on the Dielectric Characteristics and Microstructure of BaTiO3-CaTiO3 Composite)

  • 윤만순;박영민
    • 한국세라믹학회지
    • /
    • 제40권1호
    • /
    • pp.37-45
    • /
    • 2003
  • $BaTiO_3$의 Ba 자리에 Ca, Ti 자리에 Zr을 첨가한 $(B a_{1-x}Ca_x)(Ti_{0.96-y}Zr_{y}Sn_{0.04})O_3$ $(0.15 {\leq} x{\leq}0.20,\; 0.09{\leq}y{\leq}$0.14) 조성에 2차상 형성을 유도하여 복합체를 만든 후 유전 및 소결 특성을 조사하였다. Ca량이 15mol% 이상 첨가됨에 따라 $CaTiO_3$를 주성분으로 하는 2차상이 석출하여 복합체가 형성되었으며, Ca량의 증가에 따라 2차상 분율이 증가하였다. Ca량의 증가는 큐리 온도를 mol%당 $1.7^{\circ}C$ 감소시키며, 저유전율 2차상의 영향으로 Ca량 증가에 따라 최대 유전율은 mol%당 200 감소하였다. Zr 첨가는 큐리온도를 mol%당 $10^{\circ}C$ 감소시키며, 확산형 상전이 현상을 증가시켜 최대 유전율을 217 감소시켰다. 2차상의 증가에 의하여 비정상 입성장이 억제되어 소결밀도, 내전압 특성이 향상되었으며, Zr 첨가에 의하여 커패시턴스의 온도 안정성을 제어하여 EIA 규격을 만족하는 고압, 고유전율 Y5U 콘덴서 조성을 개발하였다.

Geochemistry of cordierite-bearing motasedimentary rocks, northern Yeongnam Massif: implications for provenance and tectonic setting

  • Kim, Jeongmin;Moonsup Cho
    • 한국광물학회:학술대회논문집
    • /
    • 한국광물학회.한국암석학회 2003년도 공동학술발표회 논문집
    • /
    • pp.54-54
    • /
    • 2003
  • The metasedimentary rocks together with various granitoids are the main constituents in Taebaeksan gneiss complex, northern Yeongnam Massif. Chemical compositions of sedimentary rocks may reflect the nature of the provenance and could be crucial for understanding the evolution of early continental crust. Previous workers have suggested that the provenance and tectonic studies based on the geochemistry of sediments are applicable to the Precambrian samples. In this study we analyzed the major, trace and REE elements of metasedimentary rocks to understand their provenance and tectonic setting during sedimentation. The overall geochemical characteristics of metasedimentary rocks are similar to those of average shale of the post-Archean. Major element chemistry indicates mature and sorted nature of the sediments. The degree of weathering in the source rocks the is not uniform, as inferred from a large scatter in chemical indices of weathering (CIW). The immobile trace elements such as Th, Sc, and REE can be used to discriminate various sedimentary processes. The Th/sc ratios (0.9 - 4.4) are larger than those of the upper crust and average shale, suggesting that the felsic source predominates. The contents of Ni and Cr and the variations in the ratio of compatible to incompatible elements are similar to the average post-Archean shale. Uniform chondrite-normalized REE pattern with the LREE enrichment (LaN/SmN = 4.9 ${\pm}$ 0.4) and slight negative Eu anomalies (Eu/Eu$\^$*/ = 0.7 ${\pm}$ 0.1) also support this observation. The presence of negative Eu anomaly indicates that intracrustal igneous processes involving plagioclase separation have affected the provenance rocks. The LREE enrichment implies the major role of felsic rocks in source rocks. The eNd (1.9 Ga) values of metasediment rocks vary from 9.4 to 6.7, corresponding to TDM of 2.9 - 2.7 Ga. On the other hand, the 147Sm/144Nd ratios are 0.1079 - 0.1101, corresponding to typical tettigenous sediments. The geochemical features of metasedimentary rocks such as high abundances of large ion lithophile elements, high ratios of Th/Sc and La/Sm, commonly high Th/U ratios, negative Eu anomalies, and negative eNd, suggest a provenance consisting virtually entirely of recycled upper continental crust in passive margin environment. Tectonic discrimination diagrams based upon major element compositions also support this suggestion. In conjunction with igneous activity and metamorphism in the convergent margin setting at 1.8 - 1. 9 Ga, the transition from passive margin to active margin characterize the Paleoproterozoic crustal evolution in northern Yeongnam Massif.

  • PDF

임계응력 하 거친 암석 균열의 Thermoshearing 수치모델링: 국제공동연구 DECOVALEX-2023 Task G (Numerical Modeling of Thermoshearing in Critically Stressed Rough Rock Fracture: DECOVALEX-2023 Task G)

  • 박정욱;박찬희;장리;윤정석;손장윤;이창수
    • 터널과지하공간
    • /
    • 제33권3호
    • /
    • pp.189-207
    • /
    • 2023
  • In the present study, the thermoshearing experiment on a rough rock fracture were modeled using a three-dimensional grain-based distinct element model (GBDEM). The experiment was conducted by the Korea Institute of Construction Technology to investigate the progressive shear failure of fracture under the influence of thermal stress in a critical stress state. The numerical model employs an assembly of multiple polyhedral grains and their interfaces to represent the rock sample, and calculates the coupled thermo-mechanical behavior of the grains (blocks) and the interfaces (contacts) using 3DEC, a DEM code. The primary focus was on simulating the temperature evolution, generation of thermal stress, and shear and normal displacements of the fracture. Two fracture models, namely the mated fracture model and the unmated fracture model, were constructed based on the degree of surface matedness, and their respective behaviors were compared and analyzed. By leveraging the advantage of the DEM, the contact area between the fracture surfaces was continuously monitored during the simulation, enabling an examination of its influence on shear behavior. The numerical results demonstrated distinct differences depending on the degree of the surface matedness at the initial stage. In the mated fracture model, where the surfaces were in almost full contact, the characteristic stages of peak stress and residual stress commonly observed in shear behavior of natural rock joints were reasonably replicated, despite exhibiting discrepancies with the experimental results. The analysis of contact area variation over time confirmed that our numerical model effectively simulated the abrupt normal dilation and shear slip, stress softening phenomenon, and transition to the residual state that occur during the peak stress stage. The unmated fracture model, which closely resembled the experimental specimen, showed qualitative agreement with the experimental observations, including heat transfer characteristics, the progressive shear failure process induced by heating, and the increase in thermal stress. However, there were some mismatches between the numerical and experimental results regarding the onset of fracture slip and the magnitudes of fracture stress and displacement. This research was conducted as part of DECOVALEX-2023 Task G, and we expect the numerical model to be enhanced through continued collaboration with other research teams and validated in further studies.

영남육괴 북동부 내덕리-농거리 화강암내 구성광물의 희토류원소 분포도 및 Rb-Sr 광물연대의 지구화학적 의의 (Geochemical Implication of Rare Earth Element pattern and Rb-Sr mineral isochron from consituent minerals in the Naedeokri-Nonggeori granite, Yeongnam Massif, Korea )

  • 이승구;이승렬
    • 광물과 암석
    • /
    • 제36권2호
    • /
    • pp.125-134
    • /
    • 2023
  • 내덕리 화강암과 농거리 화강암은 영남육괴 동북부의 태백-상동지역에서 분포하는 고원생대 화강암이다. 이 단보에서는 내덕리 화강암과 농거리 화강암에서 추출된 광물들에 대해 희토류원소의 함량측정 및 이들 광물들로 부터의 Rb-Sr 광물연대를 구함으로써 내덕리-농거리 화강암의 지구화학적 진화사를 재조명할 수 있는 틀을 마련하고자 하였다. 운석으로 규격화한 희토류원소 분포도에서는, 저어콘을 제외한 흑운모, 장석, 석영, 전기석 등 모든 주구성광물은 경희토류가 부화되어 있고, 중희토류가 결핍된 희토류원소 분포도를 보여주고 있다. 저어콘의 경우 Eu의 강한 부(-)의 이상과 더불어 경희토류와 중희토류 모두 부화된 특성을 보여주는데. 이는 열수기원임을 지시하는 증거라 할 수 있다. 그리고 Rb-Sr 광물연대에 있어서 광물분리한 시료만을 이용한 Rb-Sr 광물연대는 1.814±142(2σ) Ma의 연대치를 지시해주었고, 기존의 자료와 함께 통합하여 계산했을 때는 1,707±74(2σ) Ma의 연대치를 지시해주었다. 이 광물연대값은 겉보기에서는 기존의 1.72 Ga Rb-Sr 전암연대보다는 더 오래됐고, 1.87 Ga의 Sm-Nd 전암연대보다는 더 젊다. 이와 같이 광물연대와 전암연대가 다르게 나타나는 것은, 저어콘의 희토류원소 분포도가 지시해주는 바와 같이 Rb-Sr 동위원소계가 화강암의 정치 후 열수변질을 받았음을 지시해준다고 해석된다.

간호업무개선에 대한 간호사의 변화수용도 (Nurse호s Adoption on a Planned Organizational Change)

  • 이태화;김조자;박정숙;김소선
    • 대한간호학회지
    • /
    • 제32권2호
    • /
    • pp.155-164
    • /
    • 2002
  • With the dynamically changing environment of society, managing change is the vital element of organizations's survival and growth. Health care organizations have expended enormous resources to restructure patient care delivery. Despite the growing literature describing these organizational innovations, there is a paucity of credible data that reflects systematic measurement and evaluation of such changes. This study examined the nurses' psychological response toward the work process redesign, newly introduced by the nursing department in a acute care hospital. The aim of the study was to figure out how nurses's general perception of change and perceived attributes of change affected their acceptance of change during the organizational transition. This was descriptive- correlational. The sample for the study included 50 head nurses and 135 staff nurses. Data was analyzed using SPSS PC+, version 10.0. The major findings of the study were as follows: First, the mean score of the perception of change was 71.2(SD=13.8) with the range of 0-100, which means nurses generally perceived change positively. There were significant differences in perception of change by gender and education level. Head nurses perceived change more positively than staff nurses. The higher education level showed the more positive view of change. Second, among the perceived attributes of change, trialability had the highest mean score, which means nurses perceived the change more positively if it is testable on a limited basis. Relative advantage was perceived the most negatively. Finally, factors influencing the acceptability of the work-process redesign were perceived comparability, complexity, relative advantage, and observability, which accounted for 43.7% of the variance in the acceptability of change. This study evaluated the preliminary effects of the nursing process for reengineering, focusing on nurses' acceptability towards change. The usefulness of this research study was to determine the factors influencing acceptance of organizational members during transitional periods of change and to suggest effective strategies for increasing adoption as well as for decreasing resistance to change.

중형 풍력터빈의 출력 및 타워 하중저감 제어기 설계 (Design of Power and Load Reduction Controller for a Medium-Capacity Wind Turbine)

  • 김관수;백인수;김철진;김현규;김형길
    • 한국태양에너지학회 논문집
    • /
    • 제36권6호
    • /
    • pp.1-12
    • /
    • 2016
  • A control algorithm for a 100 kW wind turbine is designed in this study. The wind turbine is operating as a variable speed variable pitch (VSVP) status. Also, this wind turbine is a permanent magnet synchronous generator (PMSG) Type. For the medium capacity wind turbine considered in this study, it was found that the optimum tip speed ratios to achieve the maximum power coefficients varied with wind speeds. Therefore a commercial blade element momentum theory and multi-body dynamics based program was implemented to consider the variation of aerodynamic coefficients with respect to Reynolds numbers and to find out the power and thrust coefficients with respect tip speed ratio and blade pitch angles. In the end a basic power controller was designed for below rated, transition and above rated regions, and a load reduction algorithm was designed to reduce tower vibration by the nacelle motion. As a result, damage equivalent Load (DEL) of tower fore-aft has been reduced by 32%. From dynamic simulations in the commercial program, the controller was found to work properly as designed. Experimental validation of the control algorithm will be done in the future.

Novel Synthesis and Nanocharacterization of Graphene and Related 2D Nanomaterials Formed by Surface Segregation

  • Fujita, Daisuke
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
    • /
    • pp.60-60
    • /
    • 2015
  • Nanosheets of graphene and related 2D materials have attracted much attention due to excellent physical, chemical and mechanical properties. Single-layer graphene (SLG) was first synthesized by Blakely et al in 1974 [1]. Following his achievements, we initiated the growth and characterization of graphene and h-BN on metal substrates using surface segregation and precipitation in 1980s [2,3]. There are three important steps for nanosheet growth; surface segregation of dopants, surface reaction for monolayer phase, and subsequent 3-D growth (surface precipitation). Surface phase transition was clearly demonstrated on C-doped Ni(111) by in situ XPS at elevated temperatures [4]. The growth mode was clarified by inelastic background analysis [5]. The surface segregation approach has been applied to C-doped Pt(111) and Pd(111), and controllable growth of SLG has been demonstrated successfully [6]. Recently we proposed a promising method for producing SLG fully covering an entire substrate using Ni films deposited on graphite substrates [7]. A universal method for layer counting has been proposed [8]. In this paper, we will focus on the effect of competitive surface-site occupation between carbon and other surface-active impurities on the graphene growth. It is known that S is a typical impurity of metals and the most surface-active element. The surface sites shall be occupied by S through surface segregation. In the case of Ni(110), it is confirmed by AES and STM that the available surface sites is nearly occupied by S with a centered $2{\times}2$ arrangement. When Ni(110) is doped with C, surface segregation of C may be interfered by surface active elements like S. In this case, nanoscopic characterization has discovered a preferred directional growth of SLG, exhibiting a square-like shape (Fig. 1). Also the detailed characterization methodologies for graphene and h-BN nanosheets, including AFM, STM, KPFM, AES, HIM and XPS shall be discussed.

  • PDF

고온 환경의 영향을 고려한 슈퍼듀플렉스 강의 저온 기계적 거동 평가 (Low-temperature Mechanical Behavior of Super Duplex Stainless Steel Considering High Temperature Environment)

  • 김명수;정원도;김정현;이제명
    • 한국해양공학회지
    • /
    • 제28권4호
    • /
    • pp.306-313
    • /
    • 2014
  • Super duplex stainless steels (sDSS) are excellent for use under severely corrosive conditions such as offshore and marine applications like pipelines and flanges. sDSS has better mechanical properties and corrosion resistance than the standard duplex stainless steel (DSS) but it is easier for a sigma phase to appear, which depresses the mechanical property and corrosion resistance, compared to DSS, because sDSS has a higher alloy element than DSS. In addition, sDSS has a feeble ductile-brittle transition temperature (DBTT) because it has a 50% ferrite microstructure. In the actual operating environment, sDSS would be thermally affected by welding and a sub-zero temperature environment. This study analyzed how precipitated sDSS behaves at a sub-zero temperature through annealing heat treatment and a sub-zero tensile test. Six types of specimens with annealing times of up to 60 min were tested in a sub-zero chamber. According to the experimental results, an increase in the annealing time reduced the elongation of sDSS, and a decrease in the tensile test temperature raises the flow stress and tensile stress. In particular, the elongation of specimens annealed for 15 min and 30 min was clearly lowered with a decrease in the tensile test temperature because of the increasing sigma phase fraction ratio.

희토류 원소 첨가 비정질 찰코지나이드 : 형광 수명과 유리 구조 변화의 관계 (Amorphous Chalcogenide Solids Doped with Rare-Earth Element : Fluorescence Lifetimes and the Glass Structural Changes)

  • 최용규
    • 한국세라믹학회지
    • /
    • 제41권9호
    • /
    • pp.696-702
    • /
    • 2004
  • 찰코지나이드 유리에 첨가된 희토류 원소의 4f 전자 궤도를 구성하는 여기 상태 에너지 준위의 수명은 기지 재료의 단거리 구조 변화뿐만 아니라 중거리 구조 변화에도 매우 민감하다 Pr$^{3+}$ 이온을 첨가한 다양한 조성의 Ge-Sb-Se 계열 찰코지나이드 샘플을 대상으로 Pr$^{3+}$ ($^3$F$_3$, $^3$F$_4$)\$\longrightarrow$$^3$H$_4$천이로부터 발생하는 1.6$\mu\textrm{m}$ 형광의 수명을 측정한 결과, 해당 형광 수명은 mean coordination number가 -2.67이 되는 조성에서 최대 값을 나타내었다. 이는 유리의 구조가 2차원 구조에서 3차원 구조로 전환됨에 따라 희토류 이온의 분포도가 변화하기 때문이며 소위 topological structure 모델과 chemically ordered network모델로써 공유 결합성이 강한 찰코지나이드 유리에 첨가된 희토류 이온의 발광 특성에 대한 해석이 가능하였다. 이러한 결과는 희토류 원소의 분포 및 형광 수명을 단지 찰코지나이드 재료의 성분비만으로 예측할 수 있다는 새로운 관점이 타당함을 의미한다