• 제목/요약/키워드: transition density

검색결과 718건 처리시간 0.023초

셀룰로오스 단열재의 연기발생에 관한 연구 (Studies of the Smoke Emission from Cellulose Fiber Insulation)

  • 김홍;강영구
    • 한국안전학회지
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    • 제9권2호
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    • pp.12-17
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    • 1994
  • Smoke evolved from burning cellulose insulation treated with boric acid-borax-alum as combustion retardants has been studied using a light absorption method. It has been shown that the quantity of smoke are decreased with the increase of oxygen concentration. Applied fire retardants did not increase smoke generation from investigated cellulose insulation in range of themal degradation without flaming. These same fire retardants increased from in the range of flaming combustion. The results of this work have been analysed using imperical equation, which correlated the smoke density at oxygen content of combustion transition. This equation may be. $\sigma$=$\sigma$$_{T}$ exp{-7.24$\times$10$^{-7}$ ( $O_2$ $O_{2.T}$)}Where $O_2$is the concentration of oxygen in the oxidizing gas, and $O_{2.T}$ refers to oxygen concentration of combustion transition.n.n.n.

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Synthesis and pressure effects on the La doped CaFe2As2

  • Shin, Soohyeon;Shang, T.;Yuan, H.Q.;Park, Tuson
    • 한국초전도ㆍ저온공학회논문지
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    • 제16권3호
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    • pp.1-3
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    • 2014
  • We have synthesized La doped $CaFe_2As_2$ single crystals with Sn flux in an evacuated quartz ampule. Doping and pressure effects on the magnetic and superconducting properties of the under-doped $Ca_{1-x}La_xFe_2As_2$ (x=0.08, 0.1) were studied by measuring electrical resistivity under quasi-hydrostatic pressure up to 21 kbar. Magnetic transition temperatures for all studied concentrations were sharply suppressed with slight amplitude of pressure, less than 3 kbar, while superconducting transition temperatures were robust against pressure. In this communication, we report temperature-pressure phase diagram for the La-doped $CaFe_2As_2$ single crystals.

다공성 세라믹스와 다공질층을 포함하는 적층체의 제조에 관한 연구;I. 기공구조 (Fabrication of Porous Ceramics and Multi-layered Ceramics Containing Porous Layers; I. Pore Structure)

  • 이해원;윤복규;송휴섭
    • 한국세라믹학회지
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    • 제31권9호
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    • pp.1044-1052
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    • 1994
  • Tape casting technique was successfully applied to produce porous ceramics and multi-layered ceramics containing porous layers, where spherical hollow polymer particles were introduced as pore precursors. In the presence of extreme differences in density and size between Al2O3 and pore precursor particles, hindered settling was effective in preventing segregation of component particles and packing behavior of mixed powders was improved through bimodal packing. There were two transitions in packing behavior of mixed powders. The first transition took place at 40~50 vol% pore precursor addition, where majority of pores changed from close to open pore state. The other transition occured at 60~70 vol% pore precursor addition, where pore precursor particles formed a continuous network structure.

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Observation of Elusive CF2Cl…Cl in Matrix Infrared Spectra and Density Functional Calculations

  • Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3274-3278
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    • 2013
  • $CF_2Cl{\cdots}Cl$, an elusive photo-isomer of $CF_2Cl_2$, has been observed in matrix IR spectra from the precursors exposed to radiation from laser ablation of transition-metals. Other plausible products, $CFCl_2{\cdots}F$ and $FClC{\cdots}F-Cl$ are not detected due to their considerably higher energies. Parallel to its previously reported analogues, the C-X bonds are considerably stronger than those of the reactant, and particularly the Cl atom that is weakly bound to the residual Cl atom forms an unusually strong carbon-halogen bond. NBO analysis reveals that the C-Cl bond is a true double bond, and the weak $Cl{\cdots}Cl$ bond is largely ionic, $F_2C=Cl^{\delta+}{\cdots}Cl^{\delta-}$. IRC computation reproduces smooth inter-conversion between the reactant and product, and the transition state is energetically close to the product, consistent with its prompt disappearance in the early stage of photolysis.

Zero-Voltage-Transition Pulse-Width-Modulation Boost 컨버터의 전달 특성 (Transfer Characteristics of the Zero- VoltageTransition Pulse-Width - Modulation Boost Converter)

  • 김진성;박석하;김양모
    • 전자공학회논문지B
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    • 제33B권10호
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    • pp.148-156
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    • 1996
  • Increasing the switching frquency is essential to achieve the high density of switched mode power supplies, but this leads to the increase of switching losses. A number of new soft switching converters have been presented ot reduce switching losses, but most of them may have some demerits, such as the increase of voltage/current stresses and high conduction losses. To overcome these problems, the ZVT-PWM converter has recently been presented. in this paper, the operation characteristics of the ZVT-PWM boost converter is analyzed, and the steady-states (DC) and small-signal model of this converter are derived and analyzed, and then the transfer functions of this converter are derived. The transfer functions of ZVT-PWM boost converter are similar to those of the conventional PWM boost converter, but the transfer characteristics are affecsted by te duty ratio and the switching frequency.

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YBaCo_20_5 화합물에서의 구조변형에 의한 전하, 궤도, 스핀상태 전이 연구 (Charge and Orbital Ordering and Spin State Transition Driven by Structural Distortion in YBaCo_20_5)

  • Se Kyun Kwon;Jin Ho Park;Byung II Min
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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    • pp.461-461
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    • 2000
  • We have investigated electronic structuresof antiferromagnetic YBaCo_2O_5 using the local spin-density approximation (LSDA) + U method. The charge and orbital ordered insulating ground state is correctly obtained with the strong on-site Coulomb interaction. Co^{2+} and Co^{3+} ions are found to be in the high spin (HS) and intermediate spin (IS) state, respectively. The tetragonal to orthorhombic structural transition is responsible for the ordering phenomena and the spin states of Co ions. The large contribution of the orbital moment to the total magnetic moment indicates that the effect of the spin-orbit coupling is very important in YBaCo_2O_5.

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A New PWM DC/DC Converter with Isolated Dual Output Using Single Power Stage

  • Lee, Dong-Yun;Hyun, Dong-Seok;Ick Choy
    • Journal of Power Electronics
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    • 제2권4호
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    • pp.312-324
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    • 2002
  • This paper presents a new PWM DC/DC converter with dual output power using single power stage, which has the isolation characteristics between each dual output. The proposed converter topology consists of two switches ($S_B$ and $S_F$) and only single secondary winding. Therefore, the proposed converter has better advantages of not only low cost and small size but also high power density because of using minimum components and devices compared with conventional methods which use multi winding transformers or several converters. The operating principle of the proposed converter topology, which includes the conventional auxiliary ZVT (Zero-Voltage-Transition) circuit to implement soft switching of the main switch, is illustrated in detail and the validity of the proposed converter is verified through several simulated and experimental results.

Semi-analytical Modeling of Transition Metal Dichalcogenide (TMD)-based Tunneling Field-effect Transistors (TFETs)

  • Huh, In
    • EDISON SW 활용 경진대회 논문집
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    • 제5회(2016년)
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    • pp.368-372
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    • 2016
  • In this paper, the physics-based analytical model of transition metal dichalcogenide (TMD)-based double-gate (DG) tunneling field-effect transistors (TFETs) is proposed. The proposed model is derived by using the two-dimensional (2-D) Landauer formula and the Wentzel-Kramers-Brillouin (WKB) approximation. For improving the accuracy, nonlinear and continuous lateral energy band profile is applied to the model. 2-D density of states (DOS) and two-band effective Hamiltonian for TMD materials are also used in order to consider the 2-D nature of TMD-based TFETs. The model is validated by using the tight-binding non-equilibrium Green's function (NEGF)-based quantum transport simulation in the case of monolayer molybdenum disulfide ($MoS_2$)-based TFETs.

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$(TMTSF)_2BF_4$의 압력-온도 상태도 연구 (Pressure-Temperature Phase Diagram of $(TMTSF)_2BF_4$)

  • 조연정
    • Progress in Superconductivity
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    • 제14권1호
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    • pp.24-29
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    • 2012
  • $(TMTSF)_2BF_4$ containing non-centrosymmetric anions is well known to exhibit a metal insulator transition around 37 K by ordering of the anions with a $q_2$=(1/2, 1/2, 1/2) wave vector. We established pressure-temperature phase diagram of the $(TMTSF)_2BF_4$ compound and showed that it can belong to the general phase diagram of the $(TMTSF)_2X$ family. Application of hydrostatic pressure decreases the anion ordering transition temperature and the superconducting state is finally stabilized below 3.77 K under 7.7 kbar. Magnetoresistance measurement on the $(TMTSF)_2BF_4$ under 7.8 kbar is performed but neither the field-induced spin-density-wave state nor the rapid oscillation is observed up to 9 T.

저탄소 HSLA강의 천이 온도 미치는 미세 조직의 영향 (Effects of microstructure on impact transition temperature of low carbon HSLA steels)

  • 강주석;이창우;박찬경
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 춘계학술대회 논문집
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    • pp.431-434
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    • 2008
  • Effects of microstructure on the toughness of low carbon HSLA steels were investigated. Nickel decreased the ferrite-austenite transformation temperature, resulted in increase of the fraction of bainitic ferrite. However, it was decreased with increasing deformation amount at austenite region. Since fine austenite grains formed by dynamic recrystallization under large strain transformed to acicular ferrite or granular bainite rather than bainitic ferrite. The effective grain size, thus, was decreased by deformation and it resulted in lower ductile-brittle transition temperature (DBTT). The bainitic ferrite was thought to inhibit the fracture crack initiation and to delay the crack propagation by its high dislocation density and hard interlath $2^{nd}$ phase constituents, respectively. Thus, DBTT was also decreased by Ni addition in low carbon HSLA steels.

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