• Bulletin of the Korean Chemical Society
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• v.31 no.1
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• pp.59-63
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• 2010

Calculations are presented for the $\gamma$-aminobutyric acid-$(H_2O)_n$ (n = 0-5) clusters in both canonical and zwitterionic forms. We examine the effects of microsolvation on the structures and transformation between the canonical and zwitterionic forms. The canonical forms are predicted to be more stable for n = 0-4. With five microsolvating water molecules, the two forms of $\gamma$-aminobutyric acid become quasidegenerate, with the energies of zwitterionic forms slightly (by 1 - 3 kcal/mol) higher. The lowest energy zwitterionic conformer of $\gamma$-aminobutyric acid-$(H_2O)_5$ cluster is calculated to isomerize to canonical form through a barrier-less proton transfer process and is thus predicted to be kinetically unstable. Therefore, we predict that the canonical conformers of $\gamma$-aminobutyric acid should be observed predominantly in the gas phase at low temperature in presence of up to five water molecules.

• Korean Journal of Optics and Photonics
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• v.6 no.4
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• pp.302-309
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• 1995

We desinged a lattice-matched InGaAs/lnGaAsP quantum well laser that lases at $1.55{\mu}m$ at room temperature, and calculated the gain spectrum as a function of injected carrier density and temperature. For the calculation of band structures and momentum matrix elements, we used a transfer JIlatrix method based on a block-diagonalized 8x8 second-order Ii$.$ P Hamiltonian. This lattice-matched quantum well lases in transverse electric mode. As the temperature increases, the lasing wavelength gets longer, the transparency carrier density increases, and the differential gain is reduced. The temperature dependence of the gain spectrum comes from the temperature dependence of the band structure and that of the Fermi function, and the latter contributes dominantly.nantly.

• Corrosion Science and Technology
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• v.14 no.5
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• pp.232-238
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• 2015

Corrosion is of greatest concern for metallic materials exposed to corrosive seawater or aggressive marine atmospheres. Marine structures and components made of metallic materials incur an initial cost and additional large costs for corrosion control and maintenance. There have been worldwide efforts to minimize marine corrosion and extend service life of the materials. It is believed that various factors are associated with corrosion of marine grade metallic materials, particularly the temperature of the solution affecting the corrosion rate by changing dissolved oxygen solubility and concentrations of chloride. In the present study, the electrochemical characteristics of S355ML steel are investigated to identify corrosion acceleration tendencies with changes in solution temperature under marine environments. It was found that increasing seawater temperature, promoted not only activation of chloride ion transfer, but also the formation of porous $Fe(OH)_3$ or $Fe_2O_3$, leading to the acceleration of corrosion.

• Journal of the Korean Applied Science and Technology
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• v.12 no.1
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• pp.93-99
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• 1995

As the surfactants that were used in micellar reaction, emulsion polymerization and phase-transfer reaction etc. have the problems, the cleavable surfactant that was converted to inactive compound after such as the reaction was synthesized to above 90% yield. And this surfactant and intermediates were separated through thin layer chromatography and column chromatatography and their molecular structures were confirmed from IR. $^{1}H$-NMR and elementary analysis spectra. And its surface-active properties and acid hydrolysis will be serialized in II.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05a
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• pp.435-438
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• 2005

The use of new hybrid systems that combine the advantages of steel and reinforced concrete structures has gained popularity. One of these new mixed systems consists of steel beams and reinforced concrete shear wall, which represents a cost- and time-effective type of construction. A number of previous studies have focused on examining the seismic response of steel coupling beams in a hybrid wall system. However, the shear transfer of steel coupling beam-wall connections with panel shear failure has not been thoroughly investigated. The objective of this research was to investigate the seismic performance of steel coupling beamwall connections governed by panel shear failure. To evaluate the contribution of each mechanism, depending upon connection details, an experimental study was carried out The test variables included the reinforcement details that confer a ductile behaviour on the steel coupling beam-wall connection, i.e., the face bearing plates and the horizontal ties in the panel region of steel coupling beam-wall connections. It investigates the seismic behaviour of the steel coupling beams-wall connections in terms of the deformation characteristics. The results and discussion presented in this paper provide background for a companion paper that includes a design model for calculating panel shear strength of the steel coupling beam-wall connections.

• Journal of Periodontal and Implant Science
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• v.45 no.1
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• pp.8-13
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• 2015

Purpose: The aim of this study was to evaluate the transfer of different occlusal forces in various skeletal malocclusions using finite element analysis (FEA). Methods: Three representative human cone-beam computed tomography (CBCT) images of three skeletal malocclusions were obtained from the Department of Orthodontics, Yonsei University Dental Hospital, Seoul, South Korea. The CBCT scans were read into the visualization software after separating bones and muscles by uploading the CBCT images into Mimics (Materialise). Two separate three-dimensional (3D) files were exported to visualize the solid morphology of skeletal outlines without considering the inner structures. Individual dental impressions were taken and stone models were scanned with a 3D scanner. These images were integrated and occlusal motions were simulated. Displacement and Von Mises stress were measured at the nodes of the FEA models. The displacement and stress distribution were analyzed. FEA was performed to obtain the 3D deformation of the mandibles under loads of 100, 150, 200, and 225 kg. Results: The distortion in all three skeletal malocclusions was comparable. Greater forces resulted in observing more distortion in FEA. Conclusions: Further studies are warranted to fully evaluate the impact of skeletal malocclusion on masticatory performance using information on muscle attachment and 3D temporomandibular joint movements.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.06a
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• pp.11-29
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• 2002

Current design of pile group is based on the estimation of the overall bearing capacity of a pile group from that of a single pile using a group efficiency. However, the behaviors of a pile group are influenced by various factors such as method of pile installation, pile-soil-pile interaction, cap-soil-pile interaction, etc. Thus it is practically impossible to take into account these factors reasonably with the only group efficiency, In this paper, a new method for the design of pile groups is proposed, where the significant factors affecting the behavior of a pile group are considered separately by adopting several efficiencies. Furthermore, in the proposed method, the load transfer characteristics of piles and the difference of pile behaviors with respect to the pile locations in group can be taken into account. The efficiencies for the method are determined using the settlement failure criterion, which is consistent with the concept of allowable settlement for structures. The efficiencies calculated from the results of existing model tests are presented, and the bearing capacity of a pile group in the other model test is calculated and compared with that from the test result, to verify the validity of the proposed method.

• Journal of the Korean Society of Safety
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• v.7 no.2
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• pp.71-79
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• 1992

This paper presents a least-square algorithms of lattice structures and their use for adaptive prediction of time series generated from the dynamic system. As the view point of adaptive prediction, a new method of Identification of dynamic characteristics by means of estimating the parameters of linear auto regressive model is proposed. The fast convergence of adaptive lattice algorithms is seen to be due to the orthogonalization and decoupling properties of the lattice. The superiority of the least-square lattice is verified by computer simulation, then predictor coefficients are computed from the linear sequential time data. For the application to the dynamic characteristic analysis of unknown system, the transfer function of ideal system represented in frquency domain and the estimated one obtained by predicted coefficients are compared. Using the proposed method, the damping ratio and the natural frequency of a dynamic structure subjected to random excitations can be estimated. It is expected that this method will be widely applicable to other technical dynamic problem in which estimation of damping ratio and fundamental vibration modes are required.

• Structural Engineering and Mechanics
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• v.53 no.1
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• pp.173-188
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• 2015

Several structural calamities in the second half of the 20th century have shown that adequate collapse-resistance cannot be achieved by designing the individual elements of a structure without taking their interconnectivity into consideration. It has long been acknowledged that membrane behaviour of reinforced concrete structures can significantly increase the robustness of a structure and delay a complete collapse. An experimental large-scale test was conducted on a horizontally restrained, continuous reinforced concrete slab exposed to an artificial failure of the central support and subsequent loading until collapse of the specimen. Within this investigation the development of catenary action associated with the formation of large displacements was observed to increase the ultimate load capacity of the specimen significantly. The development of displacements, strains and horizontal forces within this investigation confirmed a load transfer process from an elastic bending mechanism to a tension controlled catenary mechanism. In this contribution a special focus is directed towards strain and crack development at critical sections. The results of this contribution are of particular importance when validating numerical models related to the development of catenary action in concrete slabs.

• Interaction and multiscale mechanics
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• v.6 no.2
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• pp.173-195
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• 2013

Meshfree methods are known to have the capability to overcome the strict regularization requirements and numerical instabilities that encumber the finite element method (FEM) in large deformation problems. They are also more naturally suited for problems involving material perforation and fragmentation. To take advantage of the high efficiency of FEM and high accuracy of meshfree methods, a coupled finite element (FE) and reproducing kernel (RK, one of the meshfree approximations) formulation is described in this paper. The coupling of FE and RK approximation is implemented in an evolutionary fashion, where the extent and location of the evolution is dependent on a triggering criteria provided by the material constitutive laws. To enhance computational efficiency, Gauss quadrature is applied to integrate both FE and RK domains so that no state variable transfer is required when mesh conversion is performed. To control the hourglassing that might occur with 1-point integrated hexahedral grids, viscous type hourglass control is implemented. Meanwhile, the FEM version of the K&C concrete (KCC) model was modified to make it applicable in both FE and RK formulations. Results using this code and the KCC model are shown for the modeling of concrete responses under quasi-static, blast and impact loadings. These analyses demonstrate that fragmentation phenomena of the sort commonly observed under blast and impact loadings of concrete structures was able to be realistically captured by the coupled formulation.