• Journal of the Korean Society of Tobacco Science
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• v.27 no.1 s.53
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• pp.40-50
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• 2005

The influence of tobacco additives on the composition of the combustion products in mainstream smoke is discussed. The effect of additives on the chemical composition of smoke have been further evaluated in order to discover additives that would alter the chemical composition of smoke. Tobacco was uniformly treated at a 1-5$\%$ level with 8 classes of additives. Group M treated with alkali metal salt and group S, F, O give lower tar, nicotine and CO values than the control. Group AN treated with natural antioxidant gives higher tar and CO values than the control. The increases are most probably due to the high transfer rate of the ingredients to smoke. M3 and P1 reduced above the $50\%$ of TSNA from the smoke. M4 and P1 reduced above the $50\%$ of HCN from the smoke. These results suggest that tobacco additives alter pyrolysis or combustion product distribution and provide fundamental data to lead the development of a RRP(reduced risk product).

• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2717-2722
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• 2014

The reaction mechanism between azacyclopropenylidene and epoxypropane has been systematically investigated employing the second-order M${\o}$ller-Plesset perturbation theory (MP2) method to better understand the reactivity of azacyclopropenylidene with four-membered ring compound epoxypropane. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. It was found that for the first step of this reaction, azacyclopropenylidene can insert into epoxypropane at its C-O or C-C bond to form spiro intermediate IM. It is easier for the azacyclopropenylidene to insert into the C-O bond than the C-C bond. Through the ring-opened step at the C-C bond of azacyclopropenylidene fragment, IM can transfer to product P1, which is named as pathway (1). On the other hand, through the H-transferred step and subsequent ring-opened step at the C-N bond of azacyclopropenylidene fragment, IM can convert to product P2, which is named as pathway (2). From the thermodynamics viewpoint, the P2 characterized by an allene is the dominating product. From the kinetic viewpoint, the pathway (1) of formation to P1 is primary.

• Bulletin of the Korean Chemical Society
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• v.23 no.2
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• pp.267-270
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• 2002

Photodissociations of o-, m-, and p-iodotoluene radical cations were investigated by using Fourier-transform ion cyclotron resonance (FT-ICR) spectrometry. Iodotoluene radical cations were prepared in an ICR cell by a photoionization charge-transfer method. The time-resolved one-photon dissociation spectra were obtained at 532 nm and the identities of $C_7H_7^+$ products were determined by examining their bimolecular reactivities toward toluene-$d_8$. The two-photon dissociation spectra were also recorded in the wavelength range 615-670 nm. The laser power dependence, the temporal variation, and the identities of $C_7H_7^+$ were examined at 640 nm. The mechanism of unimolecular dissociation of iodotoluene radical cations is elucidated: the lowest barrier rearrangement channel leads exclusively to the formation of the benzyl cation, whereas the direct C-I cleavage channel yields the tolyl cations that rearrange to both benzyl and tropylium cations with dissimilar branching ratios among o-, m-, and p-isomers. With a two-photon energy of 3.87 eV at 640 nm, the direct C-I cleavage channel results in the product branching ratio, [tropylium cation]/[benzyl cation], in descending order, 0.16 for meta >0.09 for ortho >0.05 for para.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.16 no.3
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• pp.9-15
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• 2017

This study represents basic research for the development of submerged pump technology applicable to transfer and storage of a cryogenic liquids. Its purpose is to secure baseline design data by applying reverse engineering to the process of developing a submerged cryogenic pump. The two-stage model included in the ARTICK Series LNG Submerged Pump produced by Vanzetti of Italy was selected for analysis for development of a localized product, and was disassembled for reverse engineering. The pump was disassembled after analyzing its processing/assembly characteristics such as shrinkage of fittings. In addition, the materials used in manufacturing of the main components were analyzed, and the ingredients were confirmed. As a result, a design drawing for each component required for product development was secured via foundational design, and a test product was manufactured by maximizing the application of appropriate domestic technologies.

• The Journal of Information Systems
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• v.27 no.1
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• pp.111-131
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• 2018

Purpose This study empirically investigated the impact of information technology(IT) capability on the co-innovation with suppliers and the effects of the co-innovation with suppliers on the product and process innovations in manufacturing firms. We demonstrated that IT promotes innovations trough the sharing of knowledge with suppliers. Design/methodology/approach The empirical data were collected through post-survey. 97 valid survey data were finally collected. With a multiple-regression analysis, we confirmed the influence relationships among critical variables. Findings In the empirical results, it was found that IT integration positively and significantly influences the amount of inter-organizational information exchange with suppliers. The results showed that the inter-organizational information flow with suppliers has a positive and significant impact on the inter-organizational learning with suppliers. It was also observed that the inter-organizational learning with suppliers facilitates and promotes the co-innovation with suppliers. From these results, it is concluded that the co-innovation with suppliers is activated through the knowledge transfer or sharing caused by an inter-organizational information flow or learning. Finally, the positive effects of the co-innovation with suppliers on the product and process innovations were empirically confirmed. Thus, it is suggested that IT capability influences innovations through the co-innovation with suppliers caused by an inter-organizational information flow.

• The KIPS Transactions:PartA
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• v.13A no.4 s.101
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• pp.317-322
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• 2006

The development of RFID system is increasing rapidly by applying to variety fields recently. Especially, RFID system is used to the focus technology of the supply chain management in distribution field of the supplier. In distribution field, We have to grasp products quickly and correctly, but this has a problem to make an inventory of products in real-time because of products transfer. In this paper, to solve this problems. We grasp the state of inventory in real-time by using EPC-IS network becoming the organizational standard of RFID network. also, We offer an authentation of product service to grasp counterfeits and stolen goods in real-time. Therefore, in this paper, We show to be able to process an authentation of product service and inventory of products in distribution field in real-time.

• Progress in Superconductivity and Cryogenics
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• v.23 no.1
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• pp.7-11
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• 2021

Cryogenic vessels are special equipment that requires periodic evaluation of their thermal insulation performance. At the current standard, the test is considered as the loss product or heat leakage of cryogenic vessel, which takes over 72 h to evaluate; consequently, a large amount of working medium is discharged to the environment in the process. However, hydrogen is flammable and explosive, and the discharged gas may be dangerous. If liquid hydrogen is replaced with liquid nitrogen before testing, the operation then becomes complicated, and the loss product or heat leakage cannot respond to the thermal insulation performance of cryogenic vessels for liquid hydrogen. Therefore, a novel method is proposed to evaluate the heat leakage of cryogenic vessels for liquid hydrogen in self-pressurization. In contrast to the current testing methods, the method proposed in this study does not require discharge or exchange of working medium in all test processes. The proposed method is based on one-dimensional heat transfer analysis of cryogenic vessels, which is verified by experiment. When this method is used to predict the heat leakage, the comparison with the experimental data of the standard method shows that the maximum error of heat leakage is less than 5.0%.

• Design & Manufacturing
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• v.13 no.1
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• pp.25-30
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• 2019

This paper presents the design strategy for the optimal RTM molds of Carbon Fiber Reinforced Plastic (CFRP) by carbon fiber draping and resin flow simulation. First, the mold shape and molding condition were determined considering the undercut and die face of the product in the draping simulation, which made the preliminary shape of the product by compressing the carbon fiber. After that, the diffusion behavior during the injection of resin in the mold was predicted by the resin flow simulation. Finally, the optimal mold shape was designed by selecting the locations of resin injection port and vent based on total results of simulations. In this paper, the mold of automotive side mirror case was selected as the representative product. Also, the actual mold was manufactured based on the simulation design to confirm the practicality of it. This study is expected to contribute to the industry as a technology to improve the reliability and productivity of CFRP producted by RTM process.

• Toxicological Research
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• v.17
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• pp.173-183
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• 2001

Although there are still many technical difficulties to be overcome, recent advances in the molecular and cellular biology of gene transfer have made it likely that gene therapy will soon start to play an increasing role in clinical practice. However. safety issues are raised from vector system. It is not clear whether it is safe to incorporate genes into nuclear DNA. Little is known about the antigenicity of gene product which the immune system is encountering. In this review, some safety-related topics are introduced and discussed.

• 한국전산유체공학회:학술대회논문집
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• 2010.05a
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• pp.444-445
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• 2010

Predictive modeling schemes have been developed to characterize the heat Transfer and thermo-mechanical behavior for the plasma display panel (PDP) in operation. The inverse approach was adopted to predict the accurate temperature distribution and deformation in PDP. The predictive models were validated with the measurements from real panel. The developed models could be utilized to predict and/or improve the product quality of PDP.