• Title/Summary/Keyword: trace metals

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Trace Metals Characterization of Respirable Dust during Yellow Sand Phenomena in Seoul Area (서울지역의 황사발생시 호흡성 분진 중 미량원소의 특성 평가)

  • 신은상;선우영
    • Journal of environmental and Sanitary engineering
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    • v.17 no.1
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    • pp.41-51
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    • 2002
  • This research was carried out using Anderson air sampler which were set up on the roof of the Engineering College of Konkuk University at Hwayang-Dong, Kwangjin-Gu, Seoul from Aug. 1992 to foul. 1999. The results are as follows: The major component of yellow sand is soil particles based upon the observation that particles ranging from $3.3~7.0{\mu}m$ occupy 36~63%. It is certain that the increase of fine particles of respirable dust during yellow sand phenomenon in Seoul area affects the human body. The trace metals from natural sources like Al, Ca, Fe, K, Na, and Si show larger mass median diameter(MMD) values during yellow sand phenomenon than in normal situations while the values of MMD for Mn and Pb rarely changes. Noticeably, the changes in value of MMD of water soluble elements like ${NO_3}^{-}$ and ${SO_4}^{2}$ are 2.3 and 6.6 times higher during the yellow sand phenomenon compared to normal situations, respectively. This fact is regarded as decisive evidence showing that ${NO_3}^{-}$ and ${SO_4}^{2}$ in the air are attached to yellow sand and move together.

Geochemical Characteristics of Surface Sediments and an Evaluation of Trace Metal Pollution in Gomso Bay, Korea, 2011 (2011년 곰소만 표층퇴적물의 지화학적 특성 및 중금속 오염도 평가)

  • Kim, Chung-sook;Kim, Hyung Chul;Lee, Won Chan;Hong, Sokjin;Hwang, Dong-Woon;Cho, Yoon-Sik;Kim, Jin ho;Kim, Sunyoung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.5
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    • pp.567-575
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    • 2017
  • To understand the geochemical characteristics of Gomso Bay, which features extensive Manila clam, we measured various geochemical parameters, organic matter, and trace metals (Cu, Cd, Pb, Zn, Cr, Hg, As and Fe) of intertidal and subtidal surface sediments in 2011. The surface sediments consisted of sedimentary facies including gravel (0.21%), sand (61.1%), silt (32.1%), and clay (6.5%). The chemical oxygen demand (COD) and acid volatile sulfide (AVS) values in most areas were below sediment quality criteria (COD, $20mg/g{\cdot}dry$; AVS, $0.2mg/g{\cdot}dry$). Trace metals in the surface sediments were below pollution thresholds, except for As (morderately polluted). Sediment quality was evaluated using the trace metal pollution load index (PLI) and ecological risk index (ERI), which showed that sediments were generally not polluted and at low risk; however, values along the outer bay were higher. We expect these results will be valuable for sustainable aquaculture prodution and environmental management in Gomso Bay.

Simultaneous Determination of Trace Metals in Infant Formula by AAS Method (AAS법에 의한 유아용 분유중 미량 금속의 동시정량에 관한 연구)

  • Park Kyung-Lyeoull
    • Journal of environmental and Sanitary engineering
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    • v.3 no.2 s.5
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    • pp.99-106
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    • 1988
  • In order to analyze trace metals by Atomic absorption spectrophotometer in infant formula milk powder, Wet digestion method using nitric acid, perchloric acid mainly and D.D.T.C.-M.I.B.K. extraction method were done. The r-value of calibration curve were more than 0.999 in Cu, Mn, Zn. Recovery test showed high recovery rate of $97-104\%$. The results were as follows: Averages of total samples were Cu $1.92\pm1.24 ppm,\;Mn\;1.18\pm1.01ppm,\;Zn\;22.43\pm8.88ppm.$ Averages of Common Infant formula were Cu1.96\pm1.26ppm,\;Mn\;1.0\pm0.57ppm,\;Zn\;21.52\pm9.72ppm.$ Averages of follow-up infant formula were Cu$1.89\pm1.26ppm,\;Mn\;1.36\pm1.31ppm,\;Zn\;23.34\pm8.7 ppm$.

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Comparison of Trace Element, Metal, and Metalloid Contents in North and South Korean Plants

  • Park, Jeong-Soo;Chung, Ha-Sook;Lee, Eun-Ju
    • Journal of Environmental Science International
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    • v.23 no.6
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    • pp.995-1001
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    • 2014
  • When relations improve between North and South Korea, there will be demand for North Korean edible plants because of the low labor cost and similar environmental conditions. However, there is no reliable information about trace elements, metals, and metalloids in edible plants from North Korea. Selenium (Se) and germanium (Ge) have positive effects on basic human health and are therapeutical in diverse illnesses. Metal and metalloid (Cd, Pb) poisoning, on the other hand, can cause many health problems. Plants collected from North Korea had higher selenium content than those from South Korea. Although none of the collected species exceeded the permissible levels of cadmium and lead, their content in plants was significantly higher in North Korea than in South Korea. The high metal contents in plants collected from North Korea may be associated with the soil physicochemical properties as well as the accumulated amounts of elements in the soil.

Studies on the Contents of Trace Metals in Crude Drugs (시판생약(市販生藥)의 미량금속(微量金屬) 함량(含量)에 관(關)한 연구(硏究))

  • Park, Chae-Joo;Yang, Ki-Sook
    • Korean Journal of Pharmacognosy
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    • v.8 no.2
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    • pp.61-68
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    • 1977
  • The content of micro inorganic compounds in the 145 kinds of crude drugs on market was determined with Model 207 Atomic Absorption Spectrophotometer and Model 306 Flameless A.A. Content of Fe, Cu, Ni, Mn, Cd, Cr, Sn, and Pb was examined and the results revealed that the crude drugs which are using as a hematics and emmenagogues contained high content of iron, and those which are using as a antiinflammatory and emmenagogues contained high content of copper. Aromatic stomachics contain manganese and zinc, and diuretics and antiinaflammatory agents do tin. High content of Ni was found in tonics, but chronium and cadmium were not detected in crude drugs. There were no differences of content of trace metals in the various site of plants used.

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A Study on Co-precipitation of Indium Hydroxide (In(OH)3) for the Recovery and Determination of Trace Heavy Metals (인듐 수산화물(In(OH)3)의 공동침전을 이용한 미량의 중금속 회수 및 분석방법 연구)

  • Kwon, Seul-woo;Son, Seong-Hun;Lee, Man Seung;Nam, Sang-Ho
    • Resources Recycling
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    • v.26 no.4
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    • pp.50-55
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    • 2017
  • Determination of trace elements in a sample including complicated matrix is very difficult due to the interference by the matrix. Therefore, if the trace elements can be separated from the complex sample matrix and determined, the interference effects can be reduced, and it is very helpful for the overall analysis. In this study, the analytes of trace elements were separated from the sample matrix by co-precipitation with trace elements using indium hydroxide ($In(OH)_3$), then detected by inductively coupled plasma-atomic emission spectrometer (ICP-AES). Above all, the optimal conditions for the co-precipitation of elements with indium hydroxide were experimentally established. At last, salt was analyzed by the developed analytical method. No heavy metals were not found in Shinan Jeungdo salt, but trace amounts of several heavy metals except for cadmium were found in Cheonnam Yongkwang salt.

Environmental Assessment of Vitrified Mine Tailing Aggregate Using Various Leaching Methods (고농도 중금속 함유 광미를 이용한 유리화 처리 골재의 장기 용출특성에 따른 환경안전성 평가)

  • Lee, Sang-Woo;Chun, Sa-Ho;Lee, Ki-Kang;Lee, Sanghoon
    • Journal of Environmental Impact Assessment
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    • v.16 no.1
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    • pp.35-43
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    • 2007
  • Vitrified aggregates obtained by using mine tailings were evaluated using various leaching methods to assess their environmental safety. The leaching tests in this study include continuous batch leaching, Dutch availability leaching, pH-stat and tank diffusion test as well as TCLP (Toxicity Characteristic Leaching Procedure), which is commonly adopted. Vitrification technique has successfully been applied treating some solid wastes containing high level of heavy metals, such as EAF (Electric Arc Furnace) dust and mine tailings. The potentially most leachable element among trace metals was As and theoretically about 7% of total concentrations in the aggregate can be released under extreme condition. Zinc was leached about 4% and the other trace metals including Cd, Cr and Pb were hardly released from the vitrified mine tailing aggregate.

Exposure of Selected Chuncheon Residents to Trace Metals and Inorganic Anions in Drinking Water (춘천지역 일부 주민들의 먹는물 중 미량금속 및 무기 음이온에 대한 노출)

  • Kim, He-Kap;Song, Jin-A;Song, Byeong-Yeol
    • Environmental Analysis Health and Toxicology
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    • v.24 no.4
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    • pp.293-301
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    • 2009
  • This study was conducted to investigate the distribution of the concentrations of selected trace metals and inorganic anions in five types of drinking water samples (mineral spring water, well water, small community water, municipal tap water, and commercial mineral water) collected from Chuncheon, Gangwon-do in 2007. Forty four samples were analyzed for five metals and five anions using an atomic absorption spectrometer and an ion chromatograph, respectively. Arsenic (As) and nitrate (${NO_3}^-$) concentrations in some groundwater samples did not meet the future (10 ${\mu}g/L$) and current (44 mg/L) Korean drinking water standards, respectively. On the other hand, any municipal tap water samples, the sources of which were lake surface water, satisfied the Korean standards. Human health risk assessment results showed that arsenic in all types of water, especially groundwater including commercial mineral water, may pose both noncarcinogenic and carcinogenic effects on the residents. It is concluded that groundwater is not safe drinking water any longer and that a national survey and follow-up measures need to be taken.

Pollution Level of Heavy Metals of Asian Dust in Daejeon Area, 2008 (2008년 대전지역에서 발생한 황사의 중금속 오염도)

  • Lee, Pyeong-Koo;Bae, Beob-Geun
    • Journal of Soil and Groundwater Environment
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    • v.19 no.1
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    • pp.8-25
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    • 2014
  • The aims of this study were to determine concentrations of selected metals in Asian and non-Asian dust collected in Daejeon, Korea between February 2008 and December 2008 and to estimate the pollution level. The geochemical analyses of Asian dust (AD) and Non Asian dust (NAD) show that the mean concentrations of As, Cd, Cu, Pb, Zn, Zr, Sb, Mo and S reached levels up to 16, 209, 31, 43, 81, 28, 31, 122 and 302 times higher, respectively, than those in uncontaminated Chinese desert soils. These results indicate that both AD and NAD serve as an atmospheric repository for trace and heavymetal accumulation. The the enrichment factor (EF) and pollution index (PI) show that AD and NAD were severely contaminated by S, Mo, Zr, Cd, Pb, Zn, Sb, Cu, and As. All indices for these metals showed either strong or notably high level of pollution relative to Chinese desert soil, principally due to the severe atmospheric pollution derived from anthropogenic activities in heavily industrial Chinese cities. Therefore, Mo, Cd, Zr, As, Cu, Sb, Pb, and Zn are the ones most strongly affected by anthropogenic inputs such as airborne pollutants.

Temporal and Spatial Variation and Removal Efficiency of Heavy Metals in the Stream Water Affected by Leachate from the Jiknaegol Tailings Impoundment of the Yeonhwa II Mine (제2연화광산 직내골 광미장 침출수에 오염된 하천수계의 시.공간적 수질변화 및 중금속 제거효율)

  • Lee, Pyeong-Koo;Kang, Min-Ju;Choi, Sang-Hoon
    • Journal of Soil and Groundwater Environment
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    • v.16 no.1
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    • pp.19-31
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    • 2011
  • This study had been carried out to investigate spatial and temporal variations of the concentrations of trace metals for contaminated surface water in creek affected by leachate from the tailings impoundment of the Yeonhwa II mine for about 2 years. It was also to ascertain the metal removal efficiency for potentially deleterious metals by the artificial and natural attenuation processes such as retention ponds and hydrologic mixing of uncontaminated tributaries. The concentrations of As, Pb, Cd, and Cu for leachate in the rainy season were not detected. On the other hand, the concentrations of Zn, Fe, Mn, Al, and $SO_4^{2-}$ in the rainy season for leachate were 2-66 times higher than those in the dry season, due to the oxidation of the sulfide minerals and the dissolution of the secondary minerals. The concentrations of Zn and Cd for leachate and surface water of the upper creek in the rainy season exceeded the criteria of River Water Quality and Drinking Water Quality but in the dry season, those of analyzed all the metals (As, Pb, Cd, Cu, Zn, Cd, Fe, Mn, and Al) for surface water sampled at the study area were below the criteria of River Water Quality and Drinking Water Quality. In regard of the attenuation efficiency for the concentrations of metals, Fe, Mn, Al, Zn, Cd, As, and Cu were removed highly at retention ponds, while the removal efficiency for major cations and sulfate ($SO_4^{2-}$) were related to mixing of the uncontaminated tributaries. Therefore, the major attenuation processes of the metal and sulfate contents in creek affected by leachate from a tailing dump were precipitation (accompanied by metal co-precipitation and sorption), water dilution, and neutralization.