• Journal of Korean Society for Atmospheric Environment
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• v.23 no.2
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• pp.191-202
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• 2007

We developed an in-situ analyzer to understand the HONO levels in indoor environments. The in-situ measurement system utilizes a diffusion scrubber and luminol chemiluminescence to measure the HONO concentration with time resolution of 4-minute. Concentrations of NO, $NO_{2}$, and HONO were determined at an indoor air of an apartment for 9 days using the developed in-situ analyzer. Indoor HONO concentrations were highly elevated when a gas range was operated. Enhancements of the indoor NO, $NO_{2}$, and HONO concentrations during combustion indicate that the observed indoor HONO was formed by direct emission. In addition to the direct emission, the indoor HONO was partially generated from heterogeneous reactions of $NO_{2}$ on indoor surfaces, which was supported by strong relationships between peak NO, $NO_{2}$, and HONO concentrations, high HONO/$NO_{2}$ ratio and a weak correlation between NO and HONO concentrations. Additionally, three combustion experiments during the whole measurement period were performed to investigate the effects of unvented and vented gas burning on the HONO, NO, and $NO_{2}$ concentrations and their decay. The decay rate of the HONO concentration was significantly less than the NO and $NO_{2}$ decay rates for all the experiments, indicating that the lifetimes of trace nitrogen species in indoor environment varied in the order approximately HONO>$NO_{2}$>NO.

• The Journal of the Korea Contents Association
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• v.19 no.3
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• pp.485-493
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• 2019

With the development of remote sensing technology, it becomes possible to measure the trace gas concentration by satellites, so the ministry of environment is executing 152.5 billion-won to develop the geostationary orbital environment monitoring satellite and ground segment. A variety of contents for the application to utilize environmental satellite has been sought to increase the benefits. This study is for the improvement the accuracy of emission inventories, to correct emission amount with top-down method using the satellite observing data instead of bottom-up method. Two methodologies to estimate $NO_2$ emission were analyzed, one is ignoring $NO_2$ transportation effect(method-1), and the other is considering transportation effect(method-2) with source-receptor relationship equation, and the results were compared. The methodology of this study can be applicable all components which are observed from satellites.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.802-806
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• 2004

For the protection of the local air quality and the global atmosphere, the emissions of trace species including nitric oxides (NO and NO$_2$) from gas turbines are regulated by local governments and by the International Civil Aviation Organization. In-situ measurements of such species are needed not only for the development of advanced low-emission combustion concepts but also for providing emissions data required for the sound assessment of the effects of the emissions on environment. We have been developing a laser absorption system that has a capability of simultaneous determination of NO and NO$_2$concentrations in the exhaust jets from aero gas turbines. A diode laser operating near 1.8 micrometer is used for the detection of NO while a separated visible tunable diode laser operating near 676 nanometers is used for NO$_2$. The sensitivities at elevated temperature conditions were determined for simulated gas mixtures heated up to 500K in a heated cell of a straight 0.5 m optical path. Sensitivity limits estimated as were 30 ppmv-m and 3.7 ppmv-m for NO and NO$_2$, respectively, at a typical exhaust gas temperature of 800K. Experiments using the simulated exhaust flows have proven that $CO_2$ and $H_2O$ vapor - both major combustion products - do not show any interference in the NO or NO$_2$ measurements. The measurement system has been applied to the NO/NO$_2$ measurements in NO and NO$_2$ doped real combustion gas jets issuing from a rectangular nozzle having 0.4 m optical path. The lower detection limits of the system were considerably decreased by using a multipass optical cell. A pair of off-axis parabola mirrors successfully suppressed the beam steering in the combustion gas jets by centralizing the fluctuating beam in sensor area of the detectors.

• The Bulletin of The Korean Astronomical Society
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• v.45 no.1
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• pp.63.2-63.2
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• 2020

FLASH is a blind neutral hydrogen (HI) absorption line survey, eventually targeting about 100,000 background radio continuum sources in the entire southern sky using the full 36-antenna of the Australian Square Kilometre Array Pathfinder (ASKAP). Our primary goal is to search for associated and intervening HI absorption lines in the intermediate redshift range 0.4 < z < 1.0. The survey aims to understand the evolution of HI gas in galaxies as well as various physical mechanisms in active galactic nuclei, such as accretion and feedback processes. In this poster, we give an overview of the FLASH survey and present the preliminary results from our first 100-hrs of pilot observations. The latest survey data covers 1,000 square degrees and is ideal for validating observation and data processing in the continuous 300MHz-width low frequency ASKAP band (700-1000MHz). One of the crucial objectives of the pilot survey is to establish the analysis methodology that will be applied to upcoming large absorption surveys in the future. We discuss our data quality validation and present some detections of associated/intervening HI absorption lines. These absorption lines allow us to trace the cold gas properties of active and normal galaxies at higher redshifts where the HI emission line is too weak to be detectable.

• Journal of Korean Society of Transportation
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• v.31 no.6
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• pp.90-105
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• 2013

There are lots of variations on speed, acceleration and engine power during vehicle driving. It is well known that Green House Gas emissions by these dynamic driving properties are not precisely estimated by the average speed based emission estimation model which has been currently used in Korea. MOVES are selected as an appropriate transferable model among Micro-level emission estimation models. Based on MOVES, a novel emission estimation model can be used in Korea is developed. In this model, MOVES concept of emission estimation method and the MOVES method of estimating the Micro-level emission rate map is adopted. The results from the proposed model were compared with those from the average speed based emission model. The comparison results show the estimated base emission maps are good to be applied in Korea, but needed to be adjusted to consider the vehicle size differences between the two countries. Therefore, the factors for calibrating vehicle size difference were calculated and applied to acquired the micro-level emission maps for the Korean standard vehicle types.

• Analytical Science and Technology
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• v.9 no.1
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• pp.26-34
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• 1996

A method to determine the trace amount of Se and Bi in the scalp hair using the hydride generation inductively coupled plasma atomic emmission spectrometry was studied. The optimum operation conditions of ICP for hydride generation are 0.6~0.8L/min for the carrier gas flow rate, and 6mm above the induction coil for the observation height. Hydrochloric acid concentrations for the optimum hydride generation conditions were greater than 1.5M when 2.5% $NaBH_4$ and NaOH were used, and greater than 0.5M when 2.5% $NaBH_4$ and 0.1% NaOH were used. Severe interference effects are observed from transition metals such as Cu and Ni, and they could be circumvented by the coprecipitation with lanthanum hydroxide.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.5
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• pp.584-593
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• 2008

The surface $O_3,\;CO,\;NO_x,\;and\;SO_2$ were measured at Gosan in Jeju Island from May 2004 to April 2005. Over this period, the mean concentrations $({\pm}s.d.)$ of each gas was 40.06 $({\pm}16.01)$ ppbv for $O_3,\;264.92({\pm}115.73)ppbv\;for\;CO,\;1.98({\pm}2.73)ppbv\;for\;SO)_2,\;and\;4.64 ({\pm}3.24) ppbv\;for\;NO_x$. The monthly variations and the diurnal variations of these gases show that the Gosan site is situated in a relatively clean region. However, there were episodic simultaneous peaks in CO and $SO_2$, especially in winter and early spring. Using cluster analysis with air mass back- ward trajectory analysis, we suggest that these episodes are due to the influence of transportation of polluted air mass from polluted regions. In the cluster, which was under the dominant influence of clean maritime air mass, low levels of $O_3,\;CO,\;and\;SO_2$ were observed. The levels of these species were elevated in the other two clusters which had the air mass influenced by polluted continental regions. In addition, ratios of the chemical species such as $CO/NO_x,\;SO_2/NO_x,\;and\;CO/SO_2$ revealed the somewhat different characteristics of emission sources influencing each cluster. The differences in concentration of trace gases among clusters with different origin and transport pathways imply that Gosan is under the effect of pollution transported from other regions.

• Applied Chemistry for Engineering
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• v.28 no.5
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• pp.501-505
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• 2017

Due to the rapid urbanization and increased population, there is an increase in airtight nature of buildings which causes serious indoor air pollution. Among several indoor air pollutants, volatile organic compounds (VOCs) emitted from paint are of major concern. Therefore, there is an urge for the development of environmental friendly paint products. In this wok, a natural wall paint (NWP) was prepared by utilizing a natural clay material "sericite" as a main component. A small chamber test was carried out to identify the toxic substances release from NWP and the results were compared with two eco-friendly commercial paints. The total VOCs were detected in trace level inside the test chamber and their concentrations were below the recommended indoor air quality standards. Toluene was not detected for NWP, whereas formaldehyde was observed in trace level. The toxicity index results were compared with two commercial paints and found that NWP exhibited less harmful gas emission. Based on certification rating of building materials, NWP can be classified as the first grade of building materials. Due to the above advantages, the use of sericite as a major component in NWP will be a useful technique to maintain the indoor air quality.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.151-154
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• 2008

Information on the area and spatial distribution of crop fields is needed for biomass production, arrangement of water resources, trace gas emission estimates, and food security. The present study aims to monitor crops status during the growing season by estimating its aboveground biomass and leaf area index (LAI) from field reflectance taken with a hand-held radiometer. Field reflectance values were collected over specific spectral bandwidths using a handheld radiometer(LI-1800). A methodology is described to use spectral reflectance as indicators of the vegetative status in crop cultures. Two vegetation indices were derived from these spectral measurements. In this paper, first we analyze each spectral reflectance characteristics of vegetation in the order of growth stage. Vegetation indices (NDVI, GNDVI) were calculated from crop reflectance. And assess the nature of relationships between LAI and VI, as measured by the in situ NDVI and GNDVI. Among the two VI, NDVI showed predictive ability across a wider range of LAI than did GNDVI. Specific objectives were to determine the relative accuracy of these two vegetation indices for predicting LAI. The results of this study indicated that the NDVI and GNDVI could potentially be applied to monitor crop agriculture on a timely and frequent basis.

• Asian Pacific Journal of Cancer Prevention
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• v.14 no.4
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• pp.2461-2476
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• 2013

To assess environmental contamination with carcinogens, carbonaceous compounds, water-soluble ionic species and trace gaseous species were identified and quantified every three hours for three days st three different atmospheric layer at the heart of chiang-Mai, bangkok and hat-Yai from December 2006 to February 2007. A DRI model 2001 Themal/Optical Carbon Analyzer with the IMPROVE thermal/optical reflectance (TOR) protocol was used to quantify the organic carbon(OC) and elemental carbon content in $PM_{10}$. Diurnal and vertical variability was also carefully investigated. In general, OC and EC contenttration shoeed the highest values at the monitoring period o 21.00-00.00 as consequences of human activities at night bazaar coupled with reduction of mixing layer, decreased wind speed and termination of photolysis nighttime. Morning peaks of carboaceous compounds were observed during the sampling period of 06:00 -09:00, emphasizing the main contribution of traffic emission in the three cities. The estimation of incremental lifetime partculate matter exposure (ILPE) raises concern of high risk of carbonaceous accumulation over workers and residents living close to the observatory sites. The average values of incremental lifrtime particulate matter exposure (ILPE) of total carbon at Baiyoke Suit Hotel and Baiyoke Sky Hotel are approsimately ten time shigher then those air sample collected at prince of songkla University Hat-Yai campus corpse incinerator and fish-can maufacturing factory but only slightly higher than those of rice straw burnig in Songkla province. This indicates a high risk of developing lung cancer and other respiratory diseases across workers and residents living in high buildings located in Pratunam area. Using knowledge of carbonaceous fractions in $PM_{10}$, one can estimate the gas-particle partitioning of polycyclic aromatic hydrocarbons (PAHs). Dachs-Eisenreich model highlights the crucial role of adsorption in gas-particle partitioning of low molecular weight PAHs, whereas both absorption and adsorption tend to account for gas-particle partitioning of high molecular weight PAHs in urban residential zones of Thailand. Interestingly, the absorption mode alone plays a minor role in gas-partcle partitiining of PAHs in Chiang-Mai, Bangkok and hat-Yai.