• Title/Summary/Keyword: toxic pollutants.

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Biochemical and Molecular Characterization of Laccases from Wild Mushrooms

  • Ro, Hyeon-Su
    • 한국균학회소식:학술대회논문집
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    • 2014.05a
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    • pp.43-43
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    • 2014
  • White rot fungi have been useful source of enzymes for the degradation of environmental pollutants including polycyclic aromatic hydrocarbons (PAHs) and synthetic dyes. PAHs are widespread organic compounds present in fossil fuels and are routinely generated by incomplete fuel combustion. PAHs are some of the major toxic pollutants of water and soil environments. Synthetic dyes are major water-pollutants, which are toxic to organisms in water environments and interfere photosynthesis of water plants. Removal of PAHs and synthetic dyes has been of interests in the environmental science especially in the environmental microbiology. Mushrooms are fungal groups that function as primary degraders of wood polyphenolic lignin. The ligninolytic enzymes produced by mushroom, including manganese peroxidase, lignin peroxidase, and laccase, mediate the oxidative degradation of lignin. The catalytic power of these enzymes in the degradation of aromatic ring compounds has been sought for the degradation of various organic compounds. In this project, we have screened 60 wild mushroom strains for their degradation activity against two representative PAHs, naphthalene and anthracene, and five aromatic dyes, including alizarin red S, crystal violet, malachite green, methylene blue, rose bengal. The degradation of PAHs was measured by GC while the decolorization of dyes was measured by both UV spectrophotometer and HPLC. As results, 9 wild mushroom strains showed high activity in degradation of PAHs and textile dyes. We also describe the secretive enzyme activities, the transcription levels, and cloning of target genes. In conjunction with this, activities of degradative enzymes, including laccase, lignin peroxidase, and Mn peroxidase, were measured in the liquid medium in the presence of PAHs and dyes. Our results showed that the laccase activity was directed correlated with the degradation, indicating that the main enzyme acts on PAHs and dyes is the laccase. The laccase activity was further simulated by the addition of $Cu^{2+}$ ion. Detailed studies of the enzyme system should be sought for future applications.

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Toxic Assessment on Effluents of Argo/Industrial Wastewater Treatment Plants in Jeonnam using Chemical and Biological Method (전남 농공단지 폐수처리장 방류수의 화학적/생물학적 독성평가)

  • Lee, Moon-Hee;Choi, Ik-Chang;Han, Sang-Kuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.4
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    • pp.267-273
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    • 2008
  • The purpose of this study is to investigate the distributive property of organic pollutants in effluents of argo/industrial wastewater treatment plants in Jeonnam using simultaneous analysis method of 310 chemicals. The numerous organic pollutants were detected in four sampling sites and the major chemicals were pesticides, CH type chemicals such as polycyclic compounds, CHO type chemicals such as phthalates, and CHO(N) type chemical such as aromatic amines. Moreover, 17 kinds of endocrine disrupters which include diethylptbalate were detected in each sampling sites. TU (Toxic unit) indicated cytotoxicity of samples using XTT assay, it appeared highly at A point(27.2) and D point(24.4). Also, the results from the correlation between total concentration of pollutants and TU did not correspond to the results of chemical and biological analysis.

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Effects of Water Content and Temperature on Equilibrium Distribution of Organic Pollutants in Unsaturated Soil (토양내 유기독성물질의 평형분포에 미치는 토양수분과 온도의 영향)

  • Koo, Ja Kong;Shin, Hang Sik;Kim, Dong Ha
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.3
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    • pp.119-128
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    • 1988
  • The purpose of this research is to quantify the effects of water content(0.3~1.255%) and temperature ($4{\sim}40^{\circ}C$) on the equilibrium distribution of toxic organic pollutant in unsaturated soil. The priority pollutants, Dichloromethane and 1, 1, 1-Trichloroethane were selected as toxic organic pollutants and the Korean decomposed granite soil as the experimental soil media. Two models were developed on the basis of shapes of soil water distribution in unsaturated soil and compared; complete surface coating(model I) vs. spot clustering (model II). From the experiment, a large decrease in the values of effective partition coefficient ($K_{eff}$) was observed as the water content increased. As the temperature increased, the $K_{eff}$ values decreased, and this effect was magnified at lower water contents. The values of $K_{eff}$ were correlated better with the estimated values using model II. Thus it was experimentally proved that the soil water tends to enclose the soil grain partly at lower water contents.

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Synthesis and Characterization of Calcium Derivative Combined with High-Surface-Area Activated Carbon Composites for Fine Toxic Gas Removal

  • Areerob, Yonrapach;Nguyen, Dinh Cung Tien;Dowla, Biswas Md Rokon;Kim, Hyuk;Cha, Je-Woo;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.473-479
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    • 2018
  • Highly toxic gases such as hydrogen sulfide ($H_2S$), carbon dioxide ($CO_2$), and ammonia ($NH_3$) are generated by both nature and human activities and affect human health. In this research, activated carbon combined with $Ca(OH)_2$ and $CaCO_3$ (AC-CO and AC-CC, respectively) were fabricated and applied in absorbing toxic gases from air pollutants. Activated charcoal powder was compressed in the form of pellets and used in the designated conditions. The optimum operating conditions and material properties, such as adsorption capacity, effect of weight ratio of the mixture, and hardness, have been investigated after combining with the calcium derivative. The good performance exhibited in this study suggests that this material is expected to be an effective and economically viable adsorbent for $NH_3$, $CO_2$, and $H_2S$ removal from the air system.

The Various Factors which Should Be Considered in Classifying Toxic Substances in Water and Deriving Their Effluent Limits: Focusing on the Reduction of Risk (수질유해물질의 지정 및 배출허용기준 설정 시 고려해야 하는 복합적 요인에 대한 고찰: 위해성 저감을 중심으로)

  • Bae, Hyokwan;Chung, Yun-Chul;Yang, Hyungjae;Kim, Jaehoon;Lee, Hyun Dong;Jung, Jin-Young
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.766-775
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    • 2007
  • The use of toxic chemicals was extended as the industry in Korea has grown dramatically during the last three decades. However, list of toxic substances and limit concentrations in the water environment are not consistent within management of ambient water, drinking water and industrial effluent. This article suggests the systematic framework to classify toxic substances in the water environment and deriving their effluent limits. The most important factor for decision-making to classify toxic substances is whether their concentrations in the water environment are higher than the reference concentrations, estimated by considering human health risk and ecological risk. Using a risk-based reference concentration, the ambient water quality criterion, it is possible to derive the regulatory limit concentrations of toxic substances in drinking water and in industrial effluent. The goal concentrations in the effluent, which guarantee the human and ecological safety, should be determined with scientific investigation, balancing environmental benefit and economical effect, considering availability of treatment technology and identifying characteristics of wastewater from different industries.

Current Status and Research Trend of the Green Technology for Atmospheric Environment (대기환경 개선을 위한 녹색기술 현황과 연구동향)

  • Kim, Daekeun;Park, Sung-Kyu;Jeon, Eui Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.574-580
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    • 2013
  • Green technology encompasses a growing group of methods and materials, from techniques for generating energy and alternative resources to non-toxic cleaning products. Green technology is expected to solve current problems in atmospheric environment such as climate changes due to green house gases and hazardous air pollutants. This paper provides a review on the status of green technology and policy guidelines in Korea as well as the green technology for air pollutants. It presents the R&D projects and future direction in atmospheric environment, and the green technology in mobile source air pollution. Emerging green technology contributes to sustainable growth and development of atmospheric environmental industry for better air quality.

Concentrations of PCBs (Polychlorinated Biphenyls) in coastal sediments of Korea (국내 연안 퇴적물내 PCBs(Polychlorinated Biphenyls) 오염도 현황)

  • Kim, Gi-Whan;Lee, Yoon
    • Journal of environmental and Sanitary engineering
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    • v.11 no.3
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    • pp.9-12
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    • 1996
  • Polychlorinated biphenyl (PCBs) is one of major toxic pollutants in marine environments, This artificial chlorinated compound has been found in freshwater, seawater, soil, sediments and organismes living in various environments. Because of its toxicity and degradability, its uses in industrial processes have been banned after 1984 in Korea. Coastal area is an important environment for agriculture, industry, transportation, reduction of pollution loads through biogeochemical processes, cycling of nutrients and recreation. Input of pollutants from land and freshwater has been occurring through runoff, rivers and estuaries. Concentrations of PCBs were determined with GC-ECD. Concentrations of PCBs were in the range of 1.0 - 19.2 ng/g-dry weight of sediment(g-d.w.) at Ulsan, 4.5 -8,2 ng/g-d.w. at Onsan, 2.7 - 33.5 ng/g-d.w. at Masan and 4.0 - 60.7 ng/g-d.w. in Kwangyang, In Inchon area, PCBs were not detected in sediments. In sediments of Nakdong estuary, the distribution of PCBs' concentrations was 0.19 - 303 ng/g-d.w.

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Removal of Pollutants and Recovery of Toxic Heavy Metals from Wastewater Using Microporous Hollow Fiber Modules

  • Yun, Chang-Han
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.04a
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    • pp.25-27
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    • 1993
  • Multiphase equilibrium-based processes for separation and purification generally utilize dispersed systems in which one phase is dispersed in the other as bubbles or drops or thin films. Using microporous membranes, novel techniques have been developed such that multiphase processes can now be carried out in a nondispersive fashion for gas-liquid (Sirkar, 1992) and liquid-liquid (Prasad and Sirkar, 1992) contacting processes. Among such processes, only nondispersive solvent extraction of pollutants using microporous membranes will be of concern here. These processes employ immobilized immiscible phase interfaces at the pore mouths in a microporous membrane. Through such interfaces, solutes are extracted into the solvent as two immiscible phases flow on two sides of a microporous membrane. Many advantages of such a technique over conventional dispersion-based extractors have been summarized (Prasad and Sirkar, 1992).

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Washoff Characteristics of Nonpoint pollutants in Paved Areas (포장지역내 비점오염물질의 유출특성)

  • Gil, Kyung-Ik;Wee, Seung-Kyung;Lee, Sang-Soo;Park, Moo-Jong
    • 한국방재학회:학술대회논문집
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    • 2008.02a
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    • pp.779-782
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    • 2008
  • During the dry periods, many types of pollutant are accumulating on the paved surface by vehicle activities and accumulated various pollutants are inflowing to the near watershed areas for the rainfall periods. Also, the metals, toxic chemicals and sediments originated from bridges could be strongly influenced to the watershed areas during the runoff. The result shows that the EMC ranges for 95% confidence intervals in a bridge land use are $10.12\sim128.09mg/L$ for TSS, $6.07\sim21.15mg/L$ for BOD, $2.10\sim6.70mg/L$ for TN and $0.06\sim0.85mg/L$ for TP.

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Washoff Characteristics and Correlation of Nonpoint pollutants in a Bridge Storm Runoff (교량 강우유출수내 비점오염물질의 유출특성 및 상관성)

  • Wee, Seung-Kyung;Kim, Lee-Hyung;Jung, Yong-Jun;Gil, Kyung-Ikt
    • Journal of Korean Society on Water Environment
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    • v.24 no.3
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    • pp.378-382
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    • 2008
  • During the dry periods, many types of pollutants are being accumulated on the paved surface by vehicle activities and the accumulated various pollutants are inflowing into the near watershed areas for the rainfall periods. Particularly, bridges are the centralized region to be the surface runoff of the stromwater due to the high ratio of the impermeable area. Also, the metals, toxic chemicals and sediments originated from bridges could be strongly influenced to the watershed areas during the runoff. Therefore, the present study is achieved to provide washoff characteristics and correlation from the bridge during rainfall periods. The result shows that the EMC ranges for 95% confidence intervals in a bridge land use are 10.12~128.09 mg/L for TSS, 6.07~21.15 mg/L for BOD, 2.10~6.70 mg/L for TN and 0.06~0.85 mg/L for TP.