• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.11a
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• pp.7-12
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• 2004

Desalination system of revers osmosis(RO) membrane has been proven to be the most economical not only for the desalination of water containing salts, but also for the concentration of solute. RO membranes were traditionally made of inorganic polymers such. as cellulose acetate(CA), Polyamide(PA). To retain more minerals in deep ocean water, a new hybrid membrane composed of tourmaline film as organic material onto inorganic layer of CA polymer in asymmetric structure was developed for RO membrane process. The performance tests were carried out in the permeability of pure water and the rejection of NaCl solution to evaluate the adaptability for DOW desalination. The results of these basic tests show possibility to apply the new hybrid RO membrane for the desalination with function control.

• Journal of the Mineralogical Society of Korea
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• v.3 no.1
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• pp.44-57
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• 1990

Mineralogy of clay(Napseok) deposits in Yangsan area has been studied by the methods of field investigation and laboratory works including the polarizing microscopy, X-ray diffraction, infrared spectroscopy, thermal analysis, chemical analysis by electron micro-probe and atomic absorption spectrophotometer, and electron microscopy(SEM and TEM). The Napseok ores in both the Cheonbulsan and Yongcheon deposits consist mainly of sericite, pyrophyllite and quartz, with more or less tourmaline. The high temperature minerals such as corundum and dumortierite are found in the Cheonbulsan deposit, but not in the Yongcheon deposits. Dickite, nacrite, and halloysite are found in the Yongcheon deposit, but not in the Cheonbulsan deposit. The Napseok ores of the Yukwang deposit consist of sericite posits in the Yangsan area. Occurrence, chemistry and structural features of important minerals are described. Mineralogical data of sericite such as intensity raios and chemistry also support that the Napseok deposits of both the Chenobulsan and Yongcheon mines were formed at the higher temperature than those of the Yukwang mine. Presence of sericite-dickite-pyrophyllite ores in the Yongcheon deposit also suggests the lower temperautre than in the Cheonbulsan deposit.

• Economic and Environmental Geology
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• v.28 no.1
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• pp.43-51
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• 1995

The Jangsan Quartzite is a basal unit of the Cambro-Odovician sequence, in Socheon-Myeon, Bonghwa-Gun, Gyeongsangbug-Do, South Korea, was petrologically and geochemically investigated. The quartzite consists mainly of quartz and muscovite, assosiated with tourmaline and graphite. The quartzite shows white and/or gray color and various green color in hand specimens. The white and gray colored rocks have very low vanadium contents, but a dark green colored rock contains 8960 ppm vanadium. The muscovites in the quartzite show colorless and green color, of which green ones range from pale blue green to pale green. The dark green colored muscovites have above 8 wt. % vanadium and pale green ones have 1-3 wt. % vanadium. Vanadium contents in moscovite increase with decreasing $Al^{v1}$ contents. It suggests that vanadium substitutes for octahedral aluminium in moscovite. In general, it tends to large volumes of muscovite (up to 14 modal %) in deep green colored rocks, and high vanadium contents in their muscovites. Most of the moscovite flakes occur along the quartz boundaries and some are enclosed by quartz grain. The moscovite grains intergrowth each other in the former. The mouscovite aggragates are divided into two types on the basis of their intergrowth(cut) times. Two cut times and one cut time are named T type and D type, respectively. The T type is mainly distributed at western part (near of the Chunyang granite), whereas the D type is distributed from middle to estern part(near the Janggunbong) of the formation. The boundary is consistent with metamorphic isograd between andalusite and sillimanite zone by Ahn et. al. (1993).

• Economic and Environmental Geology
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• v.15 no.4
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• pp.221-233
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• 1982

Ssangjeon tungsten ore deposits is a complex pegmatite deposits embedded along the contact between pre-Cambrian Buncheon granite gneiss and amphibolite. This pegmatite vein developed 2 km along the strike and thickness varies from 10m to 40m. Mineral constituent of the normal pegmatite are quartz, microcline, plagioclase, muscovite, biotite, tourmaline and garnet. The vein paragenesis is complicated by repeated deposition of quartz but three distinct depositional stage can be recognized. Quartz A stage is the stage of the earliest milky white quartz deposition as a rock forming mineral of normal pegmatite. Quartz B stage is the stage of gray to dark gray quartz replace earlier formed normal pegmatite minerals. Quartz C stage is the stage of latest white translucent massive quartz replace quartz A and B. Tungsten ore minerals and other sulfide minerals were precipitated during quartz B stage. Ore minerals are ferberite and scheelite. Minor amount of molybdenite, arsenopyrite, pyrrhotite, pyrite, chalcopyrite, sphalerite, galena, pentlandite, bismuthinite, native bismuth and marcasite accompanied. Fluid inclusion in quartz A and B are gaseous inclusions and liquid inclusions are contained in quartz C as a primary inclusions. Salinity of inclusions in quartz A and B ranges from 4.5 to 9.5 wt. % and from 5.1 to 6.0 wt. % equivalent NaCl respectively. Homogenization temperature of quartz A; quartz B and quartz C ranges from 415 to $465^{\circ}C$, from 397 to $441^{\circ}C$ and from 278 to $357^{\circ}C$. $CO_2$ content of the ore fluid increased at the ends of quartz B stage.

• Economic and Environmental Geology
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• v.19 no.1
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• pp.35-55
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• 1986

The area of this study is located in the Sang dong district, Youngwol Gun, Kangwon Do, where the Ogcheon fold belt comes into contact with the Ryongnam massif. The area is covered by the Precambrian metasedimentary rocks of Yulri Group in the south from the line of Ungyosan-Maebongsan-Jansan-Taebaegsan Mountains and by the Cambro-Ordovician sedimentary rocks of Choseon Supergroup in the north. The Choseon Supergroup unconformably overlies the Yulri group. Several granitic intrusives occur in the Precambrian and Cambro-Ordovician terrain. The purpose of this study is to clarify the geochronology, mineralogical composition, geochemical characteristics, petrogenesis and tectonic settings of the Precambrian granitic rocks, and to evaluate the P.T. conditions of granitic intrusions. The K/Ar ages obtained from the muscovite of Nonggeori Granite, Naedeogri granite and pegmatite intruded into the Yulri Group are Early Proterozoic ($1805{\pm}18Ma$ to $1642{\pm}23Ma$), and those from the migmatitic pegmatite are Late Carboniferous ($305{\pm}4Ma$), respectively. The Precambrian granitic rocks are characterized by the presence of muscovite, tourmaline and grey feldspar with faint lineation of mafic minerals. In terms of mineralogical and chemical composition, the granitic rocks are felsic, calc-alkalic, peraluminous and S-type (ilmenite-series). The geochemical characteristics of major and trace elements indicate that the granitic rocks belong to syn-collision setting at the compressional plate margin. They were formed by progressive melting of relatively homogeneous crustal materials under 1~3kb and $670^{\circ}{\sim}720^{\circ}C$ in aqueous fluid conditions, and the Naedeogri granite was more fractionated than the Nonggeori granite. During the Taebaeg disturbance, Nonggeori granite, Naedeogri granite and pegmatite were intruded and emplaced into the Yulri Group. Migmatitic pegmatite occurring in the southwestern area, however, gave much younger muscovite age than the pegmatite intruded into the Yulri Group in rest of the area did, that might be due to the regional metamorphism of the Post-Choseon disturbance. The Geodo granitic mass and the Imog granite were intruded during the Bulgugsa disturbance.

• Economic and Environmental Geology
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• v.7 no.3
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• pp.87-100
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• 1974

This paper deals with grain size analysis, heavy mineral analysis and trace element analysis of the recent sediments of Han River basin between Cheongpyong, Gyeonggi province and Seoul. For each location the samples are taken at river shoreline, river berm and river dune. The size analysis discloses that the mean values range from $-1.37{\phi}$ to $-1.60{\phi}$, sorting values range from 0.25 to 1.84, skewness values range from -0.44 to 0.51 and kurtosis values range from -0.1 to 1.75. Based on the textural parameters, the dune sand can be distinguished from the shoreline-berm sand. The content of heavy minerals of each sample ranges from 0.04 to 4.7%. The principal heavy minerals are ilmenite, magnetite, leucoxene, garnet, amphibole, pyroxene, kyanite, zircon, monazite, tourmaline, epidote, limonite, and minor minerals are apatite, sillimanite, andalusite and olivine. In general, dune sand samples contain more heavy minerals than the samples of shoreline or berm sand. This suggests that the heavy mineral concentration is affected by wind action more than by any other causes. The content of ilmenite and leucoxene decreases, whereas the content of zircon and epidote increases as it approaches the downstream region. The differences result from the variance of geological occurrences. The emission spectrochemical analysis and colorimetry analysis revealed that the content of Ni and V in the heavy minerals of the study area are higher than those of other stream sediments in Korea. On the other hand the content of Cu, Ph, Zn, Mo, W, P, Mn, Cr, Ag and Sn are lower in the study area. It has been observed also that the contents of all the elements except for Bi are higher in this area than the samples of marine sediments of Yellow Sea.

• Journal of the Mineralogical Society of Korea
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• v.21 no.4
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• pp.365-372
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• 2008

Because stellerite, belonging to the zeolite group, is much less common mineral than any other minerals in Korea, little mineralogical study has been done so far. Stellerite occurs on open surfaces of fractured zones in the Yucheon Granite associated with flowery tourmaline, Chongdo, Gyeongsangbuk-do. Stellerite with $3{\sim}4\;mm$ length and $1{\sim}2\;mm$ width is characterized by an equigranular and euhedral form. Flat and elongated columnar crystals show well developed (010) face. Stellerite shows an intensive alteration process, possibly due to weathering or devitrification, as evidenced by microtextural analysis of Scanning Electron Microscope (SEM). Water loss occurs at $161^{\circ}C$ while dehydroxylation occurs at $467^{\circ}C$ causing decomposition of the structure afterward. From its textural observation, it is concluded that stellerite formed rapidly at small undercooling, precipitated from residual melt during the late stage with relatively constant chemistry.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.15 no.5
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• pp.182-187
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• 2005

The FT-IR absorption spectrum by the lattice vibrations of ruby and garnet obtained from FT-IR shows quite different characteristics. By the UV-VIS spectroscopy it was found that the ruby has two transmission bands in red and blue region, while garnet has only one transmission band in red region. The color filter to distinguish ruby from garnet was developed and named HWANG JI HO filter. Through the HWANG JI HO filter, ruby was shown in blue color and garnet was shown in dark red color because of the only the blue region transmittance of the filter. Other red stones, such as spinel, tourmaline were shown in dark red color like as garnet. The ruby could be recognized easily from the red stone.

• Economic and Environmental Geology
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• v.18 no.2
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• pp.107-124
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• 1985

More than fifty copper veins are emplaced around late Cretaceous granitoid stock in Haman-Gunbuk district, southernmost part of Korea. These veins cut both late Cretaceous granitoids and hornfels of Jindong formation which is intruded by the granitoids. The paragenesis of veins is nearly the same, consisting of (1) an early vein stage in which most iron oxide minerals, tourmaline and other silitcate minerals were deposited, (2) a calcite and quartz with base·metal sulfide stage and (3) late vein lets of barren calcite stage. Fluid inclusion studies reveal highly systematic trends of salinity and temperature during mineralization. Ore fluids of early vein stage were complex NaCl-KCl rich brines. Salinities of polyphase inclusions in quartz and scapolite in thie stage reached up to 72 wt.% and gradually decreased to 10.5wt. % in closing stage. Homogenization temperatures of inclusions in the beginning of this stage were up to $490^{\circ}C$ and then declined steadly to $290^{\circ}C$ in the late stage. Salinities of fluid inclusions in quartz and calcite of base·metal sulfide stage were 37.4~5.7wt. % and homogenization temperatures range from $373^{\circ}C$ to $170^{\circ}C$. Intermittent boiling of early vein fluid is indicated by fluid inclusions in quartz. Potassic alteration of granodiorite adjacent to early vein seems to be related to early saline vein fluid. Fluid inclusion data of base-metal sulfide stage of this area reveal nearly the same range as those of Koseong copper mining district about 30km apart from this area.

• The Journal of the Petrological Society of Korea
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• v.3 no.1
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• pp.49-75
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• 1994

The Hognjesa granitic rocks can be subdivided into biotite granitic gneiss and microcline- perthite granitic gneiss according to their mineralogy and textures, which change gradationally each other. They consist mainly of biotite, muscovite, chlorite, microcline, plagioclase, perthite and quartz accompanied with sillimanite, garnet, and tourmaline in places. The replacement and/or alteration phenomena and relationships of coexisting minerals suggest that the granitic gneisses might be formed by regional metamorphism of upper amphibolite facies and granitization by partial melting accompanied to the regional metamorphism, and again at later effected by regional metamorphism of epidote-amphibolite or greenschist facies. The biotite, muscovite and chlorite formed during these metamorphism, show nearly similar chemical compositions, respectively, regardless to the rock phases and stages of formation. They show relatively stable chemical equilibrium between coexisting pairs. The granitization which formed granitic gneisses may be seemed to occur regionally by partial melting accompanied to the first regional metamorphism.