• Title/Summary/Keyword: total deposition

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An optimized condition for corrosion protection of Type 304 Films prepared by unbalanced magnetron sputtering in 3.5% NaCl solution

  • Yoo, Ji-Hong;Ahn, Seung-Ho;Kim, Jung-Gu;Lee, Sang-Yul
    • Journal of Surface Science and Engineering
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    • v.34 no.5
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    • pp.465-474
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    • 2001
  • Type 304SS coatings were performed at 200$\square$ onto AISI 1045 carbon steel substrate using unbalanced magnetron sputtering (UBMS) with an austenitic AISI 304 stainless steel (SS) target of 100mm diameter. The total deposition pressure in the active Ar gas was 2$\times$10$^{-3}$ Torr. Coatings were done at various target power densities and bias voltages. Chemical compositions of metallic elements of the coatings were measured by energy dispersive X-rays spectroscopy (EDS). The structure and the morphology of Type 304SS coatings were investigated by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). Corrosion properties of the coated specimens were examined using electrochemical polarization measurements and electrochemical impedance spectroscopy in a deaerated 3.5% NaCl solution. The porosity rate was obtained from a comparison of the dc polarization resistance of the uncoated and coated substrates. Scratch adhesion testing was used to compare the critical loads for different coatings. XRD results showed that the sputtered films exhibit a ferritic b.c.c. $\alpha$-phase. Potentiodynamic polarization curves indicated that all samples had much higher corrosion potential and better corrosion resistance than the bare steel substrate. The corrosion performance increased with increasing power density and the adhesion was enhanced at the bias voltage of -50V. An improvement in the corrosion resistance can be obtained with a better coating adhesion. Finally, an optimized deposition condition for corrosion protection was found as $40W/cm^2$ and -50V.

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Application of Remote Sensing and GIS technology for monitoring coastal changes in estuary area of the Red river system, Vietnam

  • Lan, Pham Thi;Son, Tong Si;Gunasekara, Kavinda;Nhan, Nguyen Thi;Hien, La Phu
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.31 no.6_2
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    • pp.529-538
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    • 2013
  • Coastline is the most dynamic part of seascape since its shape is affected by various factors. Coastal zone is an area with immense geological, geomorphological and ecological interest. Monitoring coastal change is very important for safe navigation, coastal resource management. This paper shows a result of monitoring coastal morphological changes using Remote Sensing and GIS. Study was carried out to obtain intensity of erosion, deposition and sand bar movement in the Red River Delta. Satellite images of ALOS/AVNIR-2 and Landsat were used for the monitoring of coastal morphological changes over the period of 1975 to 2009. Band rationing and threshold technique was used for the coastline extraction. Tidal levels at the time of image acquisition varied from -0.89m to 2.87m. Therefore, coastline from another image at a different tidal level in the same year was considered to get the corrected coastline by interpolation technique. A series of points were generated along the coastal line from 1975 image and were established as reference points to see the change in later periods. The changes were measured in Euclidean distances from these reference points. Positive values represented deposition to the sea and negative values are erosion. The result showed that the Red river delta area expanded to the sea 3500m in Red river mouth, and 2873m in Thai Binh river mouth from 1975 to 2009. The erosion process occurred continuously from 1975 up to now with the average magnitude 23.77m/year from 1975 to 1989 and 7.85m/year from 2001 to 2009 in Giao Thuy area. From 1975 to 2009, total 1095.2ha of settlement area was eroded by sea. On the other hand, land expanded to the sea in 4786.24ha of mangrove and 1673.98ha of aquaculture.

PIII&D (Plasma immersion ion implantation & deposition) 기술을 이용하여 제조된 NbN 박막이 인공관절용 UHMWPE 소재의 마모에 미치는 영향 평가

  • Park, Won-Ung;Kim, Eun-Gyeom;Mun, Seon-U;Kim, Gyeong-Hun;Im, Sang-Ho;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.228-228
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    • 2012
  • 인공관절은 노인성 질환이나 자가 면역질환, 신체적인 외상 등으로 인하여 발생하는 관절의 손상 부위를 대체하기 위하여 고안된 관절의 인공 대용물이다. 인공 관절 중 인공 고관절의 경우 관절 운동을 하는 라이너(Liner)와 헤드(Head) 부분이 마모에 관여하여 인공관절의 수명에 영향을 미치게 되는데, 헤드 소재로서는 Co-Cr-Mo 합금이, 라이너 소재로서는 고분자 소재인 UHMWPE (Ultra High Molecular Weight Polyethylene)가 주로 사용되고 있다. 이러한 MOP (Metal-On-Polymer) 구조의 인공관절의 경우, 충격흡수의 장점이 있는 반면, 관절 운동시 발생하는 UHMWPE의 wear debris에 의한 골용해로 인하여 관절이 느슨해지는 문제점이 발생하여 재시술을 필요로 하게 된다. 또한 메탈 헤드의 마모로 인한 금속이온의 용출은 세포 독성의 문제를 야기하여 인공관절의 수명을 낮추는 또 하나의 요인이 되고 있다. 이러한 문제점들을 해결 하기 위하여, 본 연구에서는 PIII&D (Plasma Immersion Ion Implantation & Deposition)공정을 이용하여 Co-Cr-Mo 합금 소재 위에 niobium nitride (NbN) 박막을 증착하여 상대재인 UHMWPE의 마모를 줄이고자 하는 연구를 진행하였다. 마모량의 감소를 위하여, 박막을 증착하기 전에 Co-Cr-Mo 합금 위에 질소를 이온주입 하는 pre-ion implantation 공정을 도입하였으며, Co-Cr-Mo 합금과 NbN박막 사이의 접착력을 증가시키기 위하여 박막의 증착 초기에 이온주입과 증착을 동시에 수행하는 dynamic ion mixing공정을 수행하였다. 실험 결과 pre-ion implantation 공정을 도입한 경우 현재 상용화 되어있는 Co-Cr-Mo 합금에 비하여 마모량을 2배 이상 감소시키는 것을 확인 할 수 있었으며, dynamic ion mixing 공정을 도입한 경우 장시간의 마모 시험에서도 UHMWPE의 마모량을 2배 가까이 줄일 수 있었다.

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Effect of Chemical Vapor Deposition Condition on the Growth of SiC Thin Films (화학기상증착조건이 SiC 박막의 성장에 미치는 영향)

  • Bang, Wook;Kim, Hyeong-Joon
    • Korean Journal of Crystallography
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    • v.3 no.2
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    • pp.98-110
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    • 1992
  • B-SiC thin films were fabricated on Si(100) substrate under 1 atom by fVD. The effects of deposition conditions on the growth and the properties especially crystallinity and prefer ential alignment of these thin films were investigated. SiH4 and CH4 were used as source gases and H2 as Carrier gas. Th9 growth Of B-SiC thin films with changing parameters such as the growth temperature, the ratio of source gases (SiH4/CH4 ) and the total amount of source gases. The grown thin films were characterized by using SEM, a -step, XRD, Raman Spectro- scopy and TEM. Chemical conversion process improved the quality of thin films due to the formation of SiC buffer layer. The crystallinity of SiC thin films was improved when the growth temperature was higher than l150t and the amount of CH4 exceeded that of SiH4. The better crystallinity, the better alignment to the crystalline direction of substates. TEM analyses of the good quality thin films showed that the grain size was bigger at the surface than at the interface and the defect density is not depend on the ratio of the source gases.

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Image Evaluation and Association Analysis of the Cardiovascular Disease of the Degree of Pancreatic Steatosis in Ultrasonography

  • Cho, Jin-Young;Ye, Soo-Young;Ko, Seong-Jin
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.6
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    • pp.375-379
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    • 2016
  • Increasing fat tissue of obese people, increases the rate of cardiovascular disease, diabetes, metabolic syndromes and dyslipidemia. An increase in the focal tissue of pancreas is a known risk factor of these diseases. Although there exists sufficient research on the diagnosis and treatment of pancreatic cancer, studies have been done on fatty pancreas. In this study, based on ultrasound imaging and using a texture characteristic of GLCM, fatty pancreas was divided into three categories: mild, moderate and severe. We compared and analyzed the three groups was by Pancreatic ultrasonography and body characteristics, serological tests, pressure and the degree of arteriosclerosis, against normal control group. The following parameters of control and test groups were measured: WC (waist circumference),BMI (body mass index), TC (total cholesterol), TG (triglyceride), HDL-C (High-density lipoprotein cholesterol) and LDL-C (Low-density lipoprotein cholesterol), SBP (systolic blood pressure), BST (Blood Sugar Test) and aortic PWV (pulse wave velocity). We observed the values correspondingly increasing fat deposition. However, ABI (Ankle Brachial pressure index) stenosis and HDL-C levels decreased with increasing fat deposit (p <0.05); a drop in these parameters are known to be harmful to the human body. The difference in texture characteristics between normal control group and pancreatic fatty group (mild, moderate, and severe) was statistically confirmed. Ultrasound imaging of pancreatic steatosis categorized the disease as mild, moderate and severe based on the characteristic texture. In conclusion, we observed on increase in metabolic syndrome, dyslipidemia, and arteriosclerosis, proportional to the degree of pancreatic fat deposition. The escalation of these diseases was confirmed and was directly related with predictors of cardiovascular diseases.

Bone apposition on implants coated with calcium phosphate by ion beam assisted deposition in oversized drilled sockets: a histologic and histometric analysis in dogs

  • Kim, Min-Soo;Jung, Ui-Won;Kim, Sungtae;Lee, Jung-Seok;Lee, In-Seop;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.43 no.1
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    • pp.18-23
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    • 2013
  • Purpose: The purpose of this study was to evaluate the osseointegration of calcium phosphate (CaP)-coated implants by ion beam assisted deposition with a lack of primary stability. Methods: A total of 20 CaP-coated implants were bilaterally placed in the mandible of five dogs. In the rotational implant group, the implants were inserted in oversized drilled sockets without mechanical engagement, while the conventional surgical protocol was followed in the control group. Each group was allowed to heal for 4 and 8 weeks. The bone-to-implant contact (BIC, %) was measured by a histometric analysis. Results: All of the implants were well-maintained and healing was uneventful. In the histologic observation, all of the implants tested were successfully osseointegrated with a high level of BIC at both observation intervals. There was no significant difference in BIC among any of the groups. Conclusions: Within the limitation of this study, successful osseointegration of CaP-coated implants could be achieved in unfavorable conditions without primary stability.

Geochemical Study of Black Shale in Uhangri Formation, Haenam Area (해남지역(海南地域)에 분포(分布)된 우항리층내(牛項里層內) 흑색(黑色)셰일의 유기지화학적(有機地化學的) 연구(硏究))

  • Lee, Dai Sung;Yun, Hyun Soo
    • Economic and Environmental Geology
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    • v.12 no.4
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    • pp.207-221
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    • 1979
  • The studied area occupies the southern part of Haenam peninsula located in the southwestern corner of Korea. The stratigraphic sequences of the area are grouped into following three units in ascending order. (1) Late Cretaceous sedimentary rocks of Uhangri Formation which consist of the alternative beds of black shales and tuffaceous sediments, Hwangsan acidic fine grained tuffs and Jindo rhyolite flows. (2) Late Cretaceous biotite granite and acidic porphyries which intruded the Late Cretaceous sedimentary rocks. (3) Tertiary(?) pitchstone. The study purposes to delineate any of geochemical aspects on the deposition of the sequences, the average amounts of organic materials and the effect to the maturation of hydrocarbonization which has been occured by the intrusives. Sixty nine black shale samples were collected from Uhangri Formation in the northern and southern coasts of the peninsula. Organic carbons, total extracted organic matters and hydrocarbons were mainly determined by the Soxhlet extraction method, together with C-H-N elemental analyses. Based on the field and laboratory studies, the following interpretations have been obtained. (1) The paleohydrostatic condition of the sedimentation which took place was relatively calm and stable to delineate a lacustrine environment. (2) The amounts of organic material were more or less constant throughout the period of the deposition of the sediments. (3) The degree of hydrocarbonization of the Uhangri Formation in the northern coast was taken place higher than that in the southern coast due to the differences of thermal effect by the biotite granite which is assumed to be as a heat source in the area. Among the northern coast, some black shales in Uhangri and Mogsam areas which had been under the most moderate temperature environment snow symptomatic oily material, whereas, those in Sinseongri area do not, which were presumably to be intensive thermal alteration by the later acidic porphyries.

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Paleomagnetic Study on the Tertiary Rocks in Pohang Area (포항일원에 분포하는 제3기 암류에 대한 고지자기 연구)

  • Min, Kyung Duck;Kim, Won Kyun;Lee, Dae Ha;Lee, Youn Soo;Kim, In Su;Lee, Young-Hoon
    • Economic and Environmental Geology
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    • v.27 no.1
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    • pp.49-63
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    • 1994
  • Paleomagnetic study of Tertiary rocks in Pohang area has been carried out to determine the characteristic directon of natural remanent magnetization, the position of paleomagnetic pole, the stratigraphic correlation, and the tectonic movement. A total of 196 specimens was collected from 5 sites in the Pohang Basin, 19 sites in the Janggi Basin, and 10 sites in the Eoil Basin, respectively. The mean declination and inclination of 4 sites (3 sites in the Yonil Group and 1 site in the Yonil Basalt) are $-3.2^{\circ}$ and $54.3^{\circ}$, and yield the paleomagnetic pole position $86.9^{\circ}N$ and $7.7^{\circ}E$. These are the characteristic direction and pole position of Miocene Epoch by comparison with contemporary Eurasian and Chinese data. The characteristic direction and pole position of remaining 30 sites are $47.6^{\circ}$ and $57.5^{\circ}$, and $52.3^{\circ}N$ and $201.5^{\circ}E$, respectively. These show clockwise rotation of $50.8^{\circ}$ with respect to the Miocene ones resulted by a tectonic movement before the deposition of the Hakjeon Formation of the Yonil Group about 15~16 Ma in the study area. The mechanism of the clockwise rotation is considered to be the dextral movement of the Yangsan Fault presumably caused by the opening of the East Sea. The Yonil Basalt is reclassified into pre- and post-deposition of the Yonil Group, i.e. the former is early Miocene and the latter late Miocene.

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Effects of Si cluster incorporation on properties of microcrystalline silicon thin films

  • Kim, Yeonwon;Yang, Jeonghyeon;Kang, Jun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.181-181
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    • 2016
  • Hydrogenated microcrystalline silicon (${\mu}c-Si:H$) films have attracted much attention as materials of the bottom-cells in Si thin film tandem photovoltaics due to their low bandgap and excellent stability against light soaking. However, in PECVD, the source gas $SiH_4$ must be highly diluted by $H_2$, which eventually results in low deposition rate. Moreover, it is known that high-rate ${\mu}c-Si:H$ growth is usually accompanied by a large number of dangling-bond (DB) defects in the resulting films, which act as recombination centers for photoexcited carriers, leading to a deterioration in the device performance. During film deposition, Si nanoparticles generated in $SiH_4$ discharges can be incorporated into films, and such incorporation may have effects on film properties depending on the size, structure, and volume fraction of nanoparticles incorporated into films. Here we report experimental results on the effects of nonoparticles incorporation at the different substrate temperature studied using a multi-hollow discharge plasma CVD method in which such incorporation can be significantly suppressed in upstream region by setting the gas flow velocity high enough to drive nanoparticles toward the downstream region. All experiments were performed with the multi-hollow discharge plasma CVD reactor at RT, 100, and $250^{\circ}C$, respectively. The gas flow rate ratio of $SiH_4$ to $H_2$ was 0.997. The total gas pressure P was kept at 2 Torr. The discharge frequency and power were 60 MHz, 180 W, respectively. Crystallinity Xc of resulting films was evaluated using Raman spectra. The defect densities of the films were measured with electron spin resonance (ESR). The defect density of fims deposited in the downstream region (with nonoparticles) is higher defect density than that in the upstream region (without nanoparticles) at low substrate temperature of RT and $100^{\circ}C$. This result indicates that nanoparticle incorporation can change considerably their film properties depending on the substrate temperature.

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Estimation of Mean Air Exchange Rate and Generation Rate of Nitrogen Dioxide Using Box Model in Residence (주택에서 Box Model을 이용한 평균 환기율 및 이산화질소 발생량 추정)

  • Bae, Hyeon Ju;Yang, Won Ho;Son, Bu Sun;Kim, Dae Won
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.645-653
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    • 2004
  • Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate these factors by application of multiple measurements. For the total duration of 30 days, daily indoor and outdoor $NO_2$ concentrations were measured in 30 houses in Brisbane, Australia, and for 21 days in 40 houses in Seoul, Korea, respectively. Using a box model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated, Sub-sequently, the ventilation and source strength were estimated. In Brisbane, the penetration factors were $0.59\pm0.14$ and they were unaffected by the presence of a gas range. During sampling period, geometric mean of natural ventilation was estimated to be $l.l0\pm1.5l$ ACH, assuming a residential $NO_2$ decay rate of 0.8 hr^{-1}$ in Brisbane. In Seoul, natural ventilation was $1.15\pm1.73$ ACH with residential $NO_2$ decay rate of 0.94 hr^{-1}$ Source strength of $NO_2$ in the houses with gas range $(12.7\pm9.8$ ppb/hr) were significantly higher than those in houses with an electric range $(2.8\pm2,6$ ppb/hr) in Brisbane. In Seoul, source strength in the houses with gas range were $l6.8\pm8.2$ ppb/hr. Conclusively, indoor air quality using box model by mass balance was effectively characterized.