• Microbiology and Biotechnology Letters
• /
• v.41 no.2
• /
• pp.215-220
• /
• 2013

Biofilters for the removal of methane using tobermolite, perlite and polyurethane as packing materials have been undergoing recent development. The effects of these packing materials on methane oxidation activity were evaluated in this study. Mixed methanotrophs (consortia A, B, C and D) from wetland and landfill soils were used as the inoculum sources. The influences of packing materials, consisting of tobermolite, perlite, and polyurethane, on the methane oxidation rate and methanotrophic bio-mass, were estimated. When perlite was added into the methanotrophic cultures, the methane oxidation rate was more than twice that of the control (without packing materials), and the methanotrophic biomass increased more than 10 fold. The ratio of methanotrophic bacteria to total bacteria under with tobermolite packing material was higher than the control and the other packing materials, indicating that tobermolite can serve as a specific packing material where dominance of methanotrophs is desired. Therefore, perlite and tobermolite provide habitats which increase the activity of methanotrophic bacteria, and these packing materials are promising for use in methane oxidation processes.

• Journal of Korean Society of Water and Wastewater
• /
• v.27 no.6
• /
• pp.751-759
• /
• 2013

This study is carried out to get the basic design parameters for phospate removal facilites from wastewater by Tobermolite. The phosphate removal by the apatite formation on the surface was affected by several important factors, temperature, ions present in wastewater stream, contact time, recirculation rate, and etc. In case of the temperature, with the increase of temperature, the apatite formation was accelerated. When temperature increased from $15^{\circ}C$ to $35^{\circ}C$, removal efficiency of phosphate increased from 83 % to 93 %. An increase of calcium and fluoride ion content increase the apatite formation, however, bicarbonate and magnesium ion inhibited the crystallization of apatite. As expected, when the recirculation rate was increased from 1 Q to 3 Q, at EBCT (Empty Bed Contact Time) 60min enhanced removal efficiency was observed. The more the recirculation rate increased, the more the removal efficiency increased. According to the results of column experiment using an actual wastewater with low and high phosphate concentration (5 mg/L and 50 mg/L-P), the removal efficiency was 77 % at EBCT of 45 min, and 80 % at 60 min. It was suggested that optimum EBCT was 45 min.

• Microbiology and Biotechnology Letters
• /
• v.41 no.2
• /
• pp.221-227
• /
• 2013

The methane oxidation characteristics at the top and bottom layers in up-flow biofilters were investigated. Two biofilters were packed with perlite and tobermolite (biofilter A: respectively top and bottom; biofilter B: respectively bottom and top) and then compared. The methane oxidation rate was analyzed with the packed bed of the biofilter layers. The bacterial population in the biofilter was characterized using quantitative real-time PCR. For the methane oxidation rate of the biofilter A column, the perlite top part ($845.16{\pm}64.78{\mu}mol{\cdot}VS^{-1}{\cdot}h^{-1}$) gave a relatively higher value than the tobermolite bottom part ($381.85{\pm}42.00{\mu}mol{\cdot}VS^{-1}{\cdot}h^{-1}$). For the methane oxidation rate of the biofilter B column, the tobermolite top part ($601.25{\pm}37.78{\mu}mol{\cdot}VS^{-1}{\cdot}h^{-1}$) provided a relatively higher value than the perlite bottom part ($411.07{\pm}53.02{\mu}mol{\cdot}VS^{-1}{\cdot}h^{-1}$). The pmoA gene copy numbers, responsible for methanotrophs, in the top layer of biofilter A (1.27E+13 pmoA gene copy number/mg-VSS) was higher than in the bottom layer (3.33E+13 pmoA gene copy number/mg-VSS). However, the population of methanotrophs in biofilter B was not significantly different between the top and bottom layers. These results suggest that although the methane oxidation rates of perlite and tobermolite in the top parts of biofilter A and B were high, methanotroph populations were higher in the bottom parts of both biofilters, with a rapid decline in methane concentrations within the biofilters.

• Journal of the Korean Ceramic Society
• /
• v.32 no.8
• /
• pp.893-900
• /
• 1995

The porous wollastonite ceramics were fabricated after firing calcium silicates, obtained using natural resources and by-products of power plants by hydrothermal synthesis, without organic fibers or asbestos for reinforcement agent. A specimen from diatomite as a SiO2 staring raw material had the highest strength owing to normal grain growth and good densification from homogeneous sperhcial C-S-H hydrates. A specimen from SiO2 sol as a SiO2 starting raw material showed tobermolite, but fly ash and mixed system did xonotlite after hydrothermal synthesis. The specimen from fly ash showed the lowest firing shirikage and strength changes in the firing range from 50$0^{\circ}C$ to 120$0^{\circ}C$. The other phases in all specimens changed to wollastonite phase after firing at 100$0^{\circ}C$. Also the average pore size was distributed from 0.2${\mu}{\textrm}{m}$ to 2${\mu}{\textrm}{m}$.

• Journal of The Korean Digital Architecture Interior Association
• /
• v.12 no.4
• /
• pp.87-95
• /
• 2012

Autoclaved lightweight concrete (ALC), also known as autoclaved aerated concrete (AAC), is a lightweight, precast building material that simultaneously provides structure, insulation. ALC is a unique building material. Because of its cellular nature, it is lightweight, self-insulating, as well as sound and fireproof. ALC products include blocks, wall panels, floor and roof panels, and lintels. Recently, the use of ALC has became increasingly popular. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures and chemical reactants. Admixtures make use of meta kaolin and silica fume, chemical reactants make use of sodium silicate and sodium hydroxide. From the test result, the ALC using admixtures and chemical reactants have a good fundamental properties compared with plain ALC. These good fundamental properties is caused by the admixtures and chemical reactants of ALC by the reason of the micro filling effect and chemical binding of C-S-H gel, tobermolite and quartz.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.13 no.6 s.58
• /
• pp.135-147
• /
• 2009

In order to develop the ultra high strength concrete over 400Mpa at 28 day, Low-heat portland cement, ferro-silicon, silica-fume and steel fiber were mixed and tested under the special autoclave curing conditions. Considering the influence of Ultra high strength concrete. normal concrete is used as a comparison with low water-cement ratio possible Low-heat portland cement. Additionally, as a substitution of aggregates, we analyzed the compressive strength of Ferro Silicon by making the states of mixed and curing conditions differently. In addition, SEM films testified the development of C-S-H hydrates of Type III & Type IV, and tobermolite, zonolite due to the high temperature, high pressure of autoclave curing. Fineness of aggregate, filler and reactive materials in concrete caused 420Mpa compressive strength at 28day successfully.