• Title/Summary/Keyword: time reversibility

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Quantitative estimation of reversibility of the discharge process undergone by nickel hydroxide film cathodically deposited on pure nickel as a positive supercapacitor electrode using cyclic voltammetry and potential drop method

  • Pyun Su-Il;Moon Sung-Mo
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.8-13
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    • 1998
  • This work presents the way how to evaluate the degree of reversibility of the discharging process undergone by the nickel hydroxide film cathodically deposited on pure nickel as a positive electrode for electrochemical capacitor using the combined cyclic voltammetry and potential drop method, supplemented by galvanostatic discharge and open-circuit potential transient methods. The time interval necessary just to establish the current reversal of anodic to cathodic direction from the moment just after applying the potential inversion of anodic to cathodic direction, was obtained on cyclic voltammogram. The cathodic charge density passed upon dropping the applied potential, was calculated on potentiostatic current density-time curve. Both the time interval and the cathodic charge density in magnitude can be regarded as being measures of the degree of reversibility of the discharging process undergone by the positive active material for supercapacitor, i.e. , the longer the time interval is, the lower is the degree of reversibility and the greater the cathodic charge density is, the higher is the degree of reversibility. From the applied potential dependences of the time interval and cathodic charge density, discharge at $0.42 V_{SCE}$ was determined to be the most reversible.

Empirical modelling of chemically enhanced backwash during ultrafiltration process

  • Daramola, M.O.;Adeogun, A.G.
    • Membrane and Water Treatment
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    • v.2 no.4
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    • pp.225-237
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    • 2011
  • In this study, response of reversibility of membrane flux during chemically enhanced backwash (CEB) to changes in filtration time, filtration flux and coagulant concentration dosing during ultrafiltration (UF) process was investigated using a regression model. The model was developed via empirical modelling approach using response surface methodology. In developing the model, statistically designed UF experiments were conducted and the results compared with the model output. The results showed that the performance of CEB, evaluated in terms of the reversibility of the membrane flux, depends strongly on the changes in coagulant concentration dosage and the filtration flux. Also the response of the reversibility of membrane flux during CEB is independent of the filtration time. The variance ratio, VR << $F_{value}$ and $R^2$ = 0.98 obtained from the cross-validation experiments indicate perfect agreement of the model output with experimental results and also testify to the validity and suitability of the model to predict reversibility of the membrane flux during CEB in UF operation.

Some Basic and Asymptotic Properies in INMA(q) Processes

  • Park, You-Sang;Kim, Myung-Jin
    • Journal of the Korean Statistical Society
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    • v.26 no.2
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    • pp.155-170
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    • 1997
  • We propose an integer-valued MA(q) process with Poisson disturbance. Its various properties are discussed such as the joint distribution, time reversibility and regression. We derive the asymptotic distribution of autocovariance function and estimators of the parameters in the suggested model. We also consider the relationship between INMA(q) and M/D/.infty. processes.

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A Study in the Temporality in Digital Gameplay (디지털 게임 플레이의 시간성 연구)

  • Lee, Dong-Eun
    • Journal of Korea Game Society
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    • v.13 no.2
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    • pp.5-16
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    • 2013
  • The purpose of this study is how to occur the temporality in Digital Gameplay. There is two types of time in Gameplay. One is Irreversibility time that goes passed through a game world like a chronology order. Another is Reversibility time that returns and renews the time. The time's duality is caused by player's intervene and experience. And the polychronic temporality in gameplay makes the rhythm as replay and eternal cyclic time.

A quasistatic crack propagation model allowing for cohesive forces and crack reversibility

  • Philip, Peter
    • Interaction and multiscale mechanics
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    • v.2 no.1
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    • pp.31-44
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    • 2009
  • While the classical theory of Griffith is the foundation of modern understanding of brittle fracture, it has a number of significant shortcomings: Griffith theory does not predict crack initiation and path and it suffers from the presence of unphysical stress singularities. In 1998, Francfort and Marigo presented an energy functional minimization method, where the crack (or its absence) as well as its path are part of the problem's solution. The energy functionals act on spaces of functions of bounded variations, where the cracks are related to the discontinuity sets of such functions. The new model presented here uses modified energy functionals to account for molecular interactions in the vicinity of crack tips, resulting in Barenblatt cohesive forces, such that the model becomes free of stress singularities. This is done in a physically consistent way using recently published concepts of Sinclair. Here, for the consistency of the model, it becomes necessary to allow for crack reversibility and to consider local minimizers of the energy functionals. The latter is achieved by introducing different time scales. The model is solved in its global as well as in its local version for a simple one-dimensional example, showing that local minimization is necessary to yield a physically reasonable result.

A Laplacian Autoregressive Moving-Average Time Series Model

  • Son, Young-Sook
    • Journal of the Korean Statistical Society
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    • v.22 no.2
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    • pp.259-269
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    • 1993
  • A moving average model, LMA(q) and an autoregressive-moving average model, NLARMA(p, q), with Laplacian marginal distribution are constructed and their properties are discussed; Their autocorrelation structures are completely analogus to those of Gaussian process and they are partially time reversible in the third order moments. Finally, we study the mixing property of NLARMA process.

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Understanding the Effects of the Dispersion and Reflection of Lamb Waves on a Time Reversal Process (램파의 분산성과 파 반사가 시간반전과정에 미치는 영향의 이해)

  • Park, Hyun-Woo;Kim, Sung-Bum;Sohn, Hoon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.1
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    • pp.89-103
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    • 2009
  • This study investigates the applicability of the time reversal concept in modem acoustics to the Lamb waves, which have been widely studied for defect detection in plate-like structures. According to conventional time reversal acoustics, an input signal can be reconstructed at an excitation point if an output signal recorded at another point is reversed in the time domain and emitted back to the original source point. However, the application of a time reversal process(TRP) to Lamb wave propagations is complicated due to velocity and amplitude dispersion characteristics of Lamb waves and reflections from the boundaries of a structure. In this study, theoretical investigations are presented to better understand the time reversibility of Lamb waves. In particular, the effects of within-mode dispersion, multimode dispersion, amplitude dispersion, and reflections from boundaries on the TRP are theoretically formulated. Simple numerical case studies are conducted to validate the theoretical findings of this study.

Explicit integration algorithm for fully flexible unit cell simulation with recursive thermostat chains (순환적으로 결합되는 정온기들을 갖는 $N{\sigma}T$ 분자동역학 전산모사에 적용한 외연적 적분기법)

  • Jung, Kwang-Sub;Cho, Maeng-Hyo
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.512-517
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    • 2007
  • In the previous development of the recursive thermostat chained fully flexible cell molecular dynamics simulation, implicit time integration method such as generalized leapfrog integration is used. The implicit algorithm is very much complicated and not easy to show time reversibility because it is solved by the nonlinear iterative procedure. Thus we develop simple, explicit symplectic time integration formula for the recursive thermostat chained fully flexible unit cell simulation. Uniaxial tension test is performed to verify the present explicit algorithm. We check that the present simulation satisfies the ergodic hypothesis for various values of fictitious mass and coefficient of multiple thermostat system. The proposed method should be helpful to predict mechanical and thermal behavior of nano-scale structure.

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Mechanical evolution of radioactive waste repository and rock mass - A review on ANDRA's case - (방사성 폐기물 지층 처분장과 암반의 역학적 특성 변화 - ANDRA의 예 -)

  • Chung, So-Keul;Synn, Joong-Ho
    • Tunnel and Underground Space
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    • v.18 no.3
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    • pp.165-174
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    • 2008
  • Thermo-hydro-chemico-mechanical evolution of the radioactive waste repository and surrounding geological media is one of the key issues for the radioactive waste disposal. This article describes not only the basic context for the site selection but also a reasonable strategy for the repository related research based on the results of the French repository project carried out by ANDRA (National radioactive waste management agency). To have some alternatives for the determination of a preferable depth and geological media, it would be recommendable to establish a database system. The curing process of the fractures or microfissures in the EDZ (Excavation Disturbed Zone) during operation time has to be examined considering the evolution of the EDZ and the reversibility of the repository. It is prerequisite to carry out a feasibility study and to validate the design concept and design parameters in a properly constructed underground research laboratory (URL) in Korea.

Difference of Time Course of Functional Recovery after Revascularization According to Preoperative Reversibility of Perfusion Impairment in Ischemic Myocardial Dysfunction (허혈성 심근 기능장애에서 술전 관류결손의 가역성에 따른 재관류 시술 이후 심근 기능회복 양상의 시간적 차이)

  • Paeng, Jin-Chul;Lee, Dong-Soo;Kim, Ki-Bong;Kim, Yu-Kyeong;Yeo, Jeong-Seok;Chung, June-Key;Lee, Myung-Chul
    • The Korean Journal of Nuclear Medicine
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    • v.35 no.6
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    • pp.364-370
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    • 2001
  • Purpose: In the revascuarization of ischemic dysfunctional myocardium, stunned myocardium was reported to recover function earlier than hibernating myocardium. It was also suggested that stunning and hibernation could be discriminated by reversibility of perfusion impairment on myocardial SPECT. In this study, we investigated the time course of functional recover after CABG according to reversibility of perfusion impairment. Materials and Methods: In 92 patients with coronary artery disease, Tl-201 rest/dipyridamole stress Tc-99m-MIBI gated SPECT was performed before, 3 months after, and 17 months after CABG. Using a 20-segment model, segmental perfusion and systolic thickening were automatically quantified. Perfusion-impaired segments with abnormal thickening were classified by reversibility into reversible (REV) and irreversible (IRREV) groups. The proportions of function-recovered segments were compared between groups and also between 3 months and 17 months in each group. Results: A total of 129 segments were Included In the analysis, and 76 were REV and 53 were IRREV. At 3 months after CABG, 61 segments (80%) in REV group showed functional recovery while 28 segments (53%) in IRREV group did (p<0.001). However, at 17 months after CABG, 60 segments (79%) in REV group and 37 segments (70%) un IRREV group showed functional recovery (p=n.s.). When comparing 3 months and 17 months in each group, REV group showed no difference, while IRREV group showed significant further improvement (p<0.05). Conclusion: In viable myocardium with ischemic myocardial dysfunction, the segments with reversible perfusion impairment recover function earlier after revascularization than irreversible segments.

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