• Title/Summary/Keyword: time of concentration

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A study on breakthrough characteristics of activated carbon fiber by development of sorbent tube (ACF 흡착관 개발을 위한 파괴특성에 관한 연구)

  • Won Jung-Il;Kim Ki-Hwan
    • Journal of environmental and Sanitary engineering
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    • v.20 no.1 s.55
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    • pp.40-54
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    • 2005
  • This dissertation aims to develop adsorption tubes for measuring organic solvents in the working environment, by comparing and analyzing breakthrough condition and adsorption capacity with ACF. 1. In breakthrough characteristics, the raising velocity of breakthrough curve is increasing according to assault concentration, but $50\%$ breakthrough time is decreasing. As breakthrough curve of calculated data using this agrees with the one of experimental data both of them can be used on determining sampling time of adsorption tubes. It is predicted by theoretical that $10\%$ breakthrough time is increasing in the case of increasing filled adsorbent amount. 2. $10\%$ breakthrough time is regularly decreasing as much as assault concentration is increasing. As a result, we can predict the life of adsorbent within the range of the low concentration, and adsorption amount that ACF can sample during $10\%$ breakthrough time is increasing as much as assault concentration is increasing.

Characteristics of Phenol Degradation in Wastewater Treatment using Packed bed reactor (충진층 반응기를 이용한 폐수처리에서 페놀의 분해 특성)

  • 염승호;최석순
    • Journal of environmental and Sanitary engineering
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    • v.11 no.3
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    • pp.13-19
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    • 1996
  • Packed bed reactor containing immobilized microorganisms which degraded phenol without growth was used to remove phenol from the synthetic wastewater. The effects of temperature, retention time(reactor volume/flow rate) and phenol concentration on the removal efficiency of phenol were investigated. The effect of temperature in the range of 20-30$\circ $C was negligible while retention time and phenol concentration influenced the removal of phenol significantly. When retention time was in the range of 1-1.5 hour, the removal efficiency of phenol was affected not by phenol concentration but by retention time itself while it was influenced by phenol concentration above 1.5 hour of retention time. The beads after 720 hours operation were swelled by 40 % in diameter which could be prevented by crosslinking with glutaraldehyde at the expense of cell activity.

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Analytical Solutions of Unsteady Reaction-Diffusion Equation with Time-Dependent Boundary Conditions for Porous Particles

  • Cho, Young-Sang
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.652-665
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    • 2019
  • Analytical solutions of the reactant concentration inside porous spherical catalytic particles were obtained from unsteady reaction-diffusion equation by applying eigenfunction expansion method. Various surface concentrations as exponentially decaying or oscillating function were considered as boundary conditions to solve the unsteady partial differential equation as a function of radial distance and time. Dirac delta function was also used for the instantaneous injection of the reactant as the surface boundary condition to calculate average reactant concentration inside the particles as a function of time by Laplace transform. Besides spherical morphology, other geometries of particles, such as cylinder or slab, were considered to obtain the solution of the reaction-diffusion equation, and the results were compared with the solution in spherical coordinate. The concentration inside the particles based on calculation was compared with the bulk concentration of the reactant molecules measured by photocatalytic decomposition as a function of time.

Osmotic Concentration of Apples and Its Effect on Browning Reaction during Air Dehydration (사과의 삼투압농축과 열품건조시 갈색화 반응에 미치는 효과)

  • 김명환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.19 no.2
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    • pp.121-126
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    • 1990
  • Internal mass transfer during osmotic concentration of apples in sugar solutions was exami-ned as a function of concentration temperature and immersion time of those solutions using moisture loss sugar gain molality and rate parameter. Influence of osmotic concentration processes on browning reaction was also evaluated compared to control In creasin the concen-tration and temperature of sugar solutions increased moistrue loss sugar gain molality and rate parameter. Water loss was rapid early in the process and then levelled off, The same phenomena were occurred on sugar gain only in higher concentration(60$^{\circ}$ brix). IN lower concentration (30$^{\circ}$brix) sugar gain was gradually increased during whole process. Moisture loss during osmotic concentration using a sugar solution(60$^{\circ}$ brix 6$0^{\circ}C$) with 180min immer-sion time was 45.79% Effect of osmotic concentration befor air dried to 4% M.C(wet basis) on browning reaction was significant. Minimum browning reaction during air drying was carried out using a pretreatment such as osmotic concentration in sugar solution(60$^{\circ}$brix 45$^{\circ}C$) with 150min immersion time(O.D=0.01) compared to control(O.D=0.17)

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Regional Characteristics of Particle Size Distribution of PM10 (미세먼지 입경농도 분포의 지역별 특성)

  • Lee, Yong-Ki;Lee, Ki-Jong;Lee, Jae-Seong;Shin, Eun-Sang
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.6
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    • pp.666-674
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    • 2012
  • The purpose of this study is to propose management strategies to lower the level of $PM_{10}$ concentration. First, this study analyzes the characteristics of particle sizes in three different areas, the residential, the roadside, and the industrial areas. Second, it has examined the size of particles which can influence on the increase of $PM_{10}$ concentration level. The distribution of particle size for $PM_{10}$ concentration was not different by regions. The highest portion in the observed $PM_{10}$ is near $0.3{\mu}m$. In addition, both near $2.5{\mu}m$ and near $5.0{\mu}m$ are found higher in portion. The fractions of $PM_{1.0}$ and $PM_{2.5}$ in $PM_{10}$ are 68.2% and 75.8% respectively. The fraction of $PM_{1.0}$ in $PM_{2.5}$ is 89.8%. The particle diameters contributed to the increase of $PM_{10}$ concentration are different by regions. In the residential area, the sizes of near $0.6{\mu}m$ and near $3.3{\mu}m$ particles are found to be the cause for the increase of $PM_{10}$ concentration level. However the particle sizes for the increase of $PM_{10}$ concentration level are $0.8{\mu}m$ and $0.5{\mu}m$ in roadside and industrial area respectively. Therefore, fine particles are found as the key factors to raise $PM_{10}$ concentration level in the two areas, while both fine and coarse particles are in the residential areas. When examined the $PM_{10}$ concentration level change, it was categorized by two different time zones, the high concentration level time and the lower concentration time. In high concentration time, the $PM_{10}$ concentration has increased in the morning in the residential and roadside areas. On the contrary, the level has increased in the evening in the industrial area. In low concentration time, the level of $PM_{10}$ concentration in the roadside area is significantly higher in the morning than the concentration level of other times. There is no significantly different concentration level found in the both residential and industrial areas throughout the day.

Changes in Quality Characteristics of Eggplant Pickles by Salt Content and Drying Time during Storage (절임농도와 건조시간에 따른 가지장아찌의 저장 중 품질 특성 변화)

  • Choi, Sang-A;Cho, Mi-Sook
    • Journal of the Korean Society of Food Culture
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    • v.27 no.2
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    • pp.211-224
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    • 2012
  • Eggplant pickles were classified into three groups based on salt concentration (1, 3, 5%) and three groups based on drying time (30, 60 and 120 minutes), followed by storage at $5^{\circ}C$ for 28 days. Raw eggplant contains 94.82% water content. The increase in salt concentration and drying time caused a decrease in the moisture content. Compared to the 0.27% ash content of raw eggplant, the ash content of eggplant pickles increased noticeably with increasing salt concentration due to penetration into the eggplant pickles. pH values decreased significantly as the levels of salt concentration and dying time increased (p<0.05). In terms of storage time, pH values decreased from 21 days. The variation in salinity increased significantly as the concentration of salt increased. Compared to normal pickles salted at 5.39% salinity, eggplant pickles constituted 0.27~0.77% (1%), 0.40~1.14% (3%), and 0.47~11.20% (5%) 'low-salinity' eggplant pickles. Reducing-sugar content differed on the dates of 7, 14 and 21 in drying time and at 3% salinity. Hardness differed at 30, 60, and 120M on the 28th and 1, 5% salt concentration. Resilience differed according to drying time and from dates of 0 to 14th. The number of total microbes decreased at low salinity. In terms of storage time, the number of microbes tended to decrease after the 21st. In the consumer preference test, lightness of 5%-30M was the highest value.

The Time of Concentration Considering the Rainfall Intensity (강우강도를 고려한 도달시간 산정식)

  • Yoo, Dong-Hoon;Kim, Jong-Hee;Lee, Min-Ho;Lee, Sang-Ho
    • Journal of Korea Water Resources Association
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    • v.44 no.7
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    • pp.591-599
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    • 2011
  • The rainfall intensity is a very essential factor which must be considered for the estimation of the time of concentration. The rainfall intensity, however, is not fully considered for the estimation of the time of concentration due to the complexity of the equation of rainfall intensity. To increase accuracy of the time of concentration, the rainfall intensity and return period were included in the derivation of the time of concentration equations in this study. The equation of rainfall intensity is Sherman type and the regional coefficients were estimated from the rainfall intensity readings on the probability rainfall maps published by Ministry of Construction and Transportation. For simple calculation of rainfall intensities, the contour maps were drawn that expresses coefficients of the Sherman type equation. By substituting the Sherman type equation of rainfall intensity in the equation of the time of concentration, a relatively simple equation with no repeated calculation has been derived. From the study results, in order to include the influence of the rainfall intensity for the estimation of the time of concentration, it is highly recommended that the Sherman type equation of rainfall intensity be used. When one knows a location in Korea and a return period, he can estimate the coefficients of the rainfall intensity equation and calculate the time of concentration considering the rainfall intensity.

Theoretical Backgrounds of Basin Concentration Time and Storage Coefficient and Their Empirical Formula (유역 집중시간 및 저류상수의 이론적 배경과 경험식)

  • Lee, Jiho;Yoo, Chulsang;Sin, Jiye
    • Journal of Korea Water Resources Association
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    • v.46 no.2
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    • pp.155-169
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    • 2013
  • This study proposes proper forms of empirical formulas for the concentration time and storage coefficient based on their theoretical backgrounds and evaluates several existing empirical formulas by comparing them with the formula proposed in this study. Additionally, empirical formulas for the concentration time and storage coefficient of the Chungju Dam basin were derived using the forms proposed by considering their theoretical backgrounds, and compared with exiting empirical formulas. The results derived are summarized as follows. (1) The concentration time of a basin is proportional to the square of the main channel length, but inversely proportional to the channel slope, as the flood flow is generally turbulent. (2) The storage coefficient is proportional to the concentration time. (3) The comparison results with existing empirical formulas for the concentration time indicates that the empirical formulas like the Kirpich, Kraven (I), Kraven (II), California DoT, Kerby, SCS, and Morgali & Linsley are in line with the form proposed in this study. Among existing empirical formulas for the storage coefficient, the Clak, Russell, Sabol and Jung are found to be well matched to this study. (4) The application results to Chungju Dam basin indicates that among empirical formulas for the concentration time, the Jung, Yoon, Kraven (I), and Kraven (II) show relatively similar results to the observed in this study, but the Rziha shows abnormal results. Among the empirical formulas for the storage coefficient, the Yoon and Hong, Jung, Lee, and Yoon show somewhat reasonable results, but the Sabol shows abnormal results. In conclusion, the empirical formulas for the concentration time and storage coefficient developed in Korea are found to reflect the basin characteristics of Korea better.

Emulsion liquid membranes for cadmium removal: Studies of extraction efficiency

  • Ahmad, A.L.;Kusumastuti, Adhi;Derek, C.J.C.;Ooi, B.S.
    • Membrane and Water Treatment
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    • v.4 no.1
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    • pp.11-25
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    • 2013
  • Emulsion liquid membrane (ELM) process suffers from emulsion instability problem. So far, emulsion produced by mechanical methods such as stirrer and homogenizer has big size and high emulsion breakage. This paper discussed the application of emulsion produced by sonicator to extract cadmium in a batch ELM system. The emulsions consist of N,N-Dioctyl-1-octanamine (trioctylamine/TOA), nitrogen trihydride (ammonia/NH4OH), sorbitan monooleate (Span 80), and kerosene as carrier, stripping solution, emulsifying agent, and organic diluent, respectively. Effects of comprehensive parameters on extraction efficiency of Cd(II) such as emulsification time, extraction time, stirring speed, surfactant concentration, initial feed phase concentration, carrier concentration, volume ratio of the emulsion to feed phase, and pH of initial feed phase were evaluated. The results showed that extraction efficiencies of Cd(II) greater than 98% could be obtained under the following conditions: 15 minutes of emulsification time, 4 wt.% of Span 80 concentration, 4 wt.% of TOA concentration, 15 minutes of extraction time, 250 rpm of stirring speed, 100 ppm of initial feed concentration, volume ratio of emulsion to feed phase of 1:5, and initial feed pH of 1.53.

DEVELOPMENT OF A METHOD FOR CONTROLLING GAS CONCENTRATION FOR USE IN C.A EXPERIMENTS

  • Yun, H.S.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.662-669
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    • 2000
  • Based on the viscous flow characteristics of gas through capillary tube, a simple and low cost system was developed for controlling gas concentration for use in C.A experiments. The gas flow rate through capillary tube had a linear relationship with pressure, $(length)^{-1}$ and $(radius)^4$ of capillary tube, which agreed well with Hagen-Poiseuille's law. The developed system could control the gas concentration in storage chamber within ${\pm}0.3%$ deviation compared to the preset concentration. The required time for producing target gas concentration in storage chamber was exactly predicted by the model used in this study, and it required much longer time than the calculated time which divided the volume of chamber by flow rate. Therefore, for producing target gas concentration as quickly as possible, it needs to supply higher flow rate of gas during the initial stage of experiment when gas concentration in storage chamber has not reached at target value. It appeared that the developed system was very useful for C.A experiments. Because one could decide a desired flow rate by the prediction model, control flow rate freely and easily by changing pressure in the pressure-regulating chamber and the accuracy was high.

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