• 환경위생공학
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• 제20권1호
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• pp.40-54
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• 2005

This dissertation aims to develop adsorption tubes for measuring organic solvents in the working environment, by comparing and analyzing breakthrough condition and adsorption capacity with ACF. 1. In breakthrough characteristics, the raising velocity of breakthrough curve is increasing according to assault concentration, but $50\%$ breakthrough time is decreasing. As breakthrough curve of calculated data using this agrees with the one of experimental data both of them can be used on determining sampling time of adsorption tubes. It is predicted by theoretical that $10\%$ breakthrough time is increasing in the case of increasing filled adsorbent amount. 2. $10\%$ breakthrough time is regularly decreasing as much as assault concentration is increasing. As a result, we can predict the life of adsorbent within the range of the low concentration, and adsorption amount that ACF can sample during $10\%$ breakthrough time is increasing as much as assault concentration is increasing.

• 환경위생공학
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• 제11권3호
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• pp.13-19
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• 1996

Packed bed reactor containing immobilized microorganisms which degraded phenol without growth was used to remove phenol from the synthetic wastewater. The effects of temperature, retention time(reactor volume/flow rate) and phenol concentration on the removal efficiency of phenol were investigated. The effect of temperature in the range of 20-30$\circ $C was negligible while retention time and phenol concentration influenced the removal of phenol significantly. When retention time was in the range of 1-1.5 hour, the removal efficiency of phenol was affected not by phenol concentration but by retention time itself while it was influenced by phenol concentration above 1.5 hour of retention time. The beads after 720 hours operation were swelled by 40 % in diameter which could be prevented by crosslinking with glutaraldehyde at the expense of cell activity.

• Korean Chemical Engineering Research
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• 제57권5호
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• pp.652-665
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• 2019

Analytical solutions of the reactant concentration inside porous spherical catalytic particles were obtained from unsteady reaction-diffusion equation by applying eigenfunction expansion method. Various surface concentrations as exponentially decaying or oscillating function were considered as boundary conditions to solve the unsteady partial differential equation as a function of radial distance and time. Dirac delta function was also used for the instantaneous injection of the reactant as the surface boundary condition to calculate average reactant concentration inside the particles as a function of time by Laplace transform. Besides spherical morphology, other geometries of particles, such as cylinder or slab, were considered to obtain the solution of the reaction-diffusion equation, and the results were compared with the solution in spherical coordinate. The concentration inside the particles based on calculation was compared with the bulk concentration of the reactant molecules measured by photocatalytic decomposition as a function of time.

• 한국식품영양과학회지
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• 제19권2호
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• pp.121-126
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• 1990

Internal mass transfer during osmotic concentration of apples in sugar solutions was exami-ned as a function of concentration temperature and immersion time of those solutions using moisture loss sugar gain molality and rate parameter. Influence of osmotic concentration processes on browning reaction was also evaluated compared to control In creasin the concen-tration and temperature of sugar solutions increased moistrue loss sugar gain molality and rate parameter. Water loss was rapid early in the process and then levelled off, The same phenomena were occurred on sugar gain only in higher concentration(60$^{\circ}$ brix). IN lower concentration (30$^{\circ}$brix) sugar gain was gradually increased during whole process. Moisture loss during osmotic concentration using a sugar solution(60$^{\circ}$ brix 6$0^{\circ}C$) with 180min immer-sion time was 45.79% Effect of osmotic concentration befor air dried to 4% M.C(wet basis) on browning reaction was significant. Minimum browning reaction during air drying was carried out using a pretreatment such as osmotic concentration in sugar solution(60$^{\circ}$brix 45$^{\circ}C$) with 150min immersion time(O.D=0.01) compared to control(O.D=0.17)

• 한국대기환경학회지
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• 제28권6호
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• pp.666-674
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• 2012

The purpose of this study is to propose management strategies to lower the level of $PM_{10}$ concentration. First, this study analyzes the characteristics of particle sizes in three different areas, the residential, the roadside, and the industrial areas. Second, it has examined the size of particles which can influence on the increase of $PM_{10}$ concentration level. The distribution of particle size for $PM_{10}$ concentration was not different by regions. The highest portion in the observed $PM_{10}$ is near $0.3{\mu}m$. In addition, both near $2.5{\mu}m$ and near $5.0{\mu}m$ are found higher in portion. The fractions of $PM_{1.0}$ and $PM_{2.5}$ in $PM_{10}$ are 68.2% and 75.8% respectively. The fraction of $PM_{1.0}$ in $PM_{2.5}$ is 89.8%. The particle diameters contributed to the increase of $PM_{10}$ concentration are different by regions. In the residential area, the sizes of near $0.6{\mu}m$ and near $3.3{\mu}m$ particles are found to be the cause for the increase of $PM_{10}$ concentration level. However the particle sizes for the increase of $PM_{10}$ concentration level are $0.8{\mu}m$ and $0.5{\mu}m$ in roadside and industrial area respectively. Therefore, fine particles are found as the key factors to raise $PM_{10}$ concentration level in the two areas, while both fine and coarse particles are in the residential areas. When examined the $PM_{10}$ concentration level change, it was categorized by two different time zones, the high concentration level time and the lower concentration time. In high concentration time, the $PM_{10}$ concentration has increased in the morning in the residential and roadside areas. On the contrary, the level has increased in the evening in the industrial area. In low concentration time, the level of $PM_{10}$ concentration in the roadside area is significantly higher in the morning than the concentration level of other times. There is no significantly different concentration level found in the both residential and industrial areas throughout the day.

• 한국식생활문화학회지
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• 제27권2호
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• pp.211-224
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• 2012

Eggplant pickles were classified into three groups based on salt concentration (1, 3, 5%) and three groups based on drying time (30, 60 and 120 minutes), followed by storage at $5^{\circ}C$ for 28 days. Raw eggplant contains 94.82% water content. The increase in salt concentration and drying time caused a decrease in the moisture content. Compared to the 0.27% ash content of raw eggplant, the ash content of eggplant pickles increased noticeably with increasing salt concentration due to penetration into the eggplant pickles. pH values decreased significantly as the levels of salt concentration and dying time increased (p<0.05). In terms of storage time, pH values decreased from 21 days. The variation in salinity increased significantly as the concentration of salt increased. Compared to normal pickles salted at 5.39% salinity, eggplant pickles constituted 0.27~0.77% (1%), 0.40~1.14% (3%), and 0.47~11.20% (5%) 'low-salinity' eggplant pickles. Reducing-sugar content differed on the dates of 7, 14 and 21 in drying time and at 3% salinity. Hardness differed at 30, 60, and 120M on the 28th and 1, 5% salt concentration. Resilience differed according to drying time and from dates of 0 to 14th. The number of total microbes decreased at low salinity. In terms of storage time, the number of microbes tended to decrease after the 21st. In the consumer preference test, lightness of 5%-30M was the highest value.

• 한국수자원학회논문집
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• 제44권7호
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• pp.591-599
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• 2011

도달시간 산정식에서 강우강도는 고려되어야 할 매우 중요한 요소이지만 일반적으로 강우강도식의 복잡함 때문에 도달시간 산정에서 강우강도를 충분히 고려하지 못하고 있는 실정이다. 본 연구에서는 도달시간 계산의 정확성을 높이기 위하여 강우강도와 재현기간을 도달시간 산정식의 유도에 포함시켰다. 강우강도식으로는 Sherman형 식을 사용하였고, 건설교통부에서 발행한 확률강우량도에서 독취한 강우강도 값으로 수식의 지역상수를 추정하였다. 그리고 확률강우량을 간결하게 계산하기 위하여 Sherman형 식의 지역상수를 등치선도로 나타냈다. 기존의 연구에서는 일반형 강우강도식을 대입하여 반복계산으로 도달시간을 산정하였지만, 본 연구에서는 Sherman형 강우강도식을 도달시간 수식에 대입함으로써 반복계산이 필요 없는 간단한 도달시간 식이 유도되었다. 연구 결과로부터, 도달시간 계산에 강우강도의 영향을 반영하기 위하여 Sherman형 식의 사용을 추천한다. 그리고 재현기간과 우리나라에서 위치가 정해지면, 강우강도식의 지역상수를 간편하게 추정할 수 있고, 강우강도가 고려된 도달시간을 계산할 수 있다.

• 한국수자원학회논문집
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• 제46권2호
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• pp.155-169
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• 2013

본 연구에서는 유역 집중시간과 저류상수의 이론적 배경을 바탕으로 적절한 경험식의 형태를 제시하고 기존의 경험식의 형태와 비교 평가하였다. 추가로, 제시된 경험식의 형태를 이용하여 충주댐 유역의 집중시간 및 저류상수의 경험식을 유도하고, 유도된 경험식과 기존의 경험식들을 비교하였다. 그 결과를 정리하면 다음과 같다. (1) 유역의 집중시간에 대한 경험공식의 형태는 유로연장의 제곱에 비례하고 유로경사에 반비례하는 형태로 나타난다. (2) 저류상수는 집중시간에 비례하는 형태로 나타난다. (3) 기존 매개변수에 관한 경험식을 검토한 결과, 집중시간의 경우에는 Kirpich 공식, Kraven (I) 공식, Kraven (II) 공식, California DoT 공식, Kerby 공식, SCS 공식 및 Morgali and Linsley 공식 등이 이러한 이론적 배경을 잘 따르고 있는 것으로 나타난다. 저류상수의 경우, Clark 공식, Russell 공식, Sabol 공식 및 정성원 공식 등이 본 저류상수와 집중시간의 비례관계를 매우 잘 만족하는 것으로 나타난다. (4) 기존의 경험식을 충주댐 유역에 적용한 결과, 집중시간의 경험식 중 정성원 공식, 윤태훈 등 공식, Kraven (I) 공식 및 Kraven (II) 공식은 추정한 집중시간과 비교적 유사한 결과를 보였으나, Rziha 공식은 비정상적인 결과를 나타내는 것으로 나타났다. 저류상수의 경우에는 윤석영과 홍일표 공식, 정성원 공식, 이정식 등 공식 및 윤태훈 등 공식이 어느 정도 합리적인 결과를 보인 반면, Sabol 공식의 경우에는 비정상적인 결과가 유도되었다. 결론적으로 국내의 집중시간 및 저류상수에 대한 경험공식이 국내 유역의 특성을 잘 반영하는 것으로 나타났다.

• Membrane and Water Treatment
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• 제4권1호
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• pp.11-25
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• 2013

Emulsion liquid membrane (ELM) process suffers from emulsion instability problem. So far, emulsion produced by mechanical methods such as stirrer and homogenizer has big size and high emulsion breakage. This paper discussed the application of emulsion produced by sonicator to extract cadmium in a batch ELM system. The emulsions consist of N,N-Dioctyl-1-octanamine (trioctylamine/TOA), nitrogen trihydride (ammonia/NH4OH), sorbitan monooleate (Span 80), and kerosene as carrier, stripping solution, emulsifying agent, and organic diluent, respectively. Effects of comprehensive parameters on extraction efficiency of Cd(II) such as emulsification time, extraction time, stirring speed, surfactant concentration, initial feed phase concentration, carrier concentration, volume ratio of the emulsion to feed phase, and pH of initial feed phase were evaluated. The results showed that extraction efficiencies of Cd(II) greater than 98% could be obtained under the following conditions: 15 minutes of emulsification time, 4 wt.% of Span 80 concentration, 4 wt.% of TOA concentration, 15 minutes of extraction time, 250 rpm of stirring speed, 100 ppm of initial feed concentration, volume ratio of emulsion to feed phase of 1:5, and initial feed pH of 1.53.

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 2000년도 THE THIRD INTERNATIONAL CONFERENCE ON AGRICULTURAL MACHINERY ENGINEERING. V.III
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• pp.662-669
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• 2000

Based on the viscous flow characteristics of gas through capillary tube, a simple and low cost system was developed for controlling gas concentration for use in C.A experiments. The gas flow rate through capillary tube had a linear relationship with pressure, $(length)^{-1}$ and $(radius)^4$ of capillary tube, which agreed well with Hagen-Poiseuille's law. The developed system could control the gas concentration in storage chamber within ${\pm}0.3%$ deviation compared to the preset concentration. The required time for producing target gas concentration in storage chamber was exactly predicted by the model used in this study, and it required much longer time than the calculated time which divided the volume of chamber by flow rate. Therefore, for producing target gas concentration as quickly as possible, it needs to supply higher flow rate of gas during the initial stage of experiment when gas concentration in storage chamber has not reached at target value. It appeared that the developed system was very useful for C.A experiments. Because one could decide a desired flow rate by the prediction model, control flow rate freely and easily by changing pressure in the pressure-regulating chamber and the accuracy was high.