• 한국표면공학회지
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• 제52권2호
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• pp.96-102
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• 2019

Magnesium and its alloys are prone to be corroded, thus surface treatments improving corrosion resistance are always required for practical applications. As a surface treatment of magnesium alloys, plasma electrolytic oxidation (PEO), creating porous stable oxide layer by a high voltage discharge in electrolyte, enhances the corrosion resistance. However, due to superhydrophilicity of the porous oxide layer, which easily allow the penetration of corrosive media toward magnesium alloys substrate, post-treatments inhibiting the transfer of corrosive media in porous oxide layer are required. In this work, we employed a hydrophobizing method to enhance the corrosion resistance of PEO treated Mg alloy. Three types of hydrophobizing techniques were used for PEO layer. Thin Teflon coating with solvent evaporation, self-assembled monolayer (SAM) coating of octadecyltrichlorosilane (OTS) based on solution method and SAM coating of perfluorodecyltrichlorosilane (FDTS) based on vacuum method significantly enhances corrosion resistance of PEO treated Mg alloy with reducing the contact of water on the surface. In particular, the vacuum based FDTS coating on PEO layer shows the most effective hydrophobicity with the highest corrosion resistance.

• 한국표면공학회지
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• 제24권1호
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• pp.18-24
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• 1991

In the present work the adhesion failure of a hot-dip galvanized coating has been studied as a function gas composition temperature of strip and of atmospheric gas in furnace. The adhesion failure of the hot-dip galvani-zed coating is classified as three mechanisms : carbon deposition, oxide film formation and alloy layer formation. The adhesion failure due to oxide film formation decreased markedly by increasing the gases temperature of direct fired furnace(DFF) in order to improve the reducing ability of steel strip. Optimum conditions of operating and manufacturing facilities for improving the coating adherence are suggested by analyzing the interface between steel substrate and coating layer.

• 한국표면공학회지
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• 제36권2호
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• pp.116-121
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• 2003

Ti-Si-N coating layers were deposited onto WC-Co substrates by a hybrid system of arc ion plating (AIP) and sputtering techniques. The tribological behaviors of Ti-Si-N coating layers with various Si contents were investigated by the dry sliding wear experiments, which were conducted at three different sliding speeds, 0.1, 0.3, 0.5 m/s, against the steel and alumina balls. In the case of steel ball, the average friction coefficient slightly decreased with increasing the sliding speed regardless of Si content due to adhesive wear behavior between coating layer and steel ball. At constant sliding speed, the average friction coefficient decreased with increase of Si content. On the contrary, in the case of alumina ball, the average friction coefficient increased with increasing the sliding speed regardless of Si content, indicating that the abrasive wear behavior was more dominant when the coating layers slide against alumina ball. Through these experimental results, it was found that the tribological behaviors of Ti-Si-N coating layers were effected by factors such as Si content, sliding speed, and kinds of counterpart materials rather than the hardness of coating layer.

• 한국안광학회지
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• 제19권1호
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• pp.1-8
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• 2014

목적: 플라스틱 렌즈의 온도에 의한 영향을 조사하고자 열 충격을 주어 렌즈 재질과 코팅의 변화를 살펴보았다. 방법: 본 연구에서는 굴절률이 다른 3 가지의 렌즈(2 종류의 thiourethane계열 렌즈, 한 종류의 allyl diglycol carbonate, ADC 렌즈)를 5 시간 동안 고온(50, 80, 그리고 $100^{\circ}C$)에 노출시켰을 때 각각의 코팅(반사방지코팅, 하드 코팅, 그리고 수막방지코팅)의 변화를 측정하였다. 결과: 그 결과 고굴절률 렌즈들에서는 경도의 변화가 미미하였으나 중굴절률 렌즈는 고온의 열에 노출될수록 경도가 점차 감소하여 하드코팅이 손상됨을 확인하였다. 모든 렌즈의 광투과율이 $80^{\circ}C$ 이상의 열 충격 시 큰 감소가 나타나 멀티코팅 층이 파괴됨을 유추할 수 있었다. 렌즈에 열 충격이 가해질수록 표면 접촉각이 작아져 $80^{\circ}C$ 이상 가열 시 수막발수코팅이 손상되기 시작함을 보였다. 결론: 굴절률이 다른 3가지 렌즈 모두에서 $80^{\circ}C$ 이상의 열 충격을 받았을 때 발수코팅을 포함한 멀티코팅이 손상되었고 고분자 재료 소재에 따라 기계적, 물리적 특성 변화정도가 다르게 나타났다.

• 한국정밀공학회지
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• 제13권11호
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• pp.32-37
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• 1996

Using the are ion plating(AIP) process, TiN coating was deposited onto high speed steel substrates. The effects of coating thickness, titanisum interlayer and shield on wear resisting capability of the coated tools were investigated. In order to promote good adhesion between the substrate and the TiN coating a thin Ti interlayer was deposited. A shield was set up also between Ti target and high speed steel substrates to prevent molten droplets from reaching the substrate. Three series of varying thickness of TiN coated layer were prepared with or without the Ti interlayer, and with or without the shield. The tools with the Ti layer and the shield showed longer tool lifes than those of other series of tools and the commercially available TiN coated HSS tools, by up to 70%.

• 한국분말재료학회지
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• 제27권3호
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• pp.210-218
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• 2020

A T-800 (Co-Mo-Cr) coating material is fabricated using Co-Mo-Cr powder feedstock and laser cladding. The microstructure and melted Al erosion properties of the laser-cladded T-800 coating material are investigated. The Al erosion properties of the HVOF-sprayed MoB-CoCr and bulk T-800 material are also examined and compared with the laser-cladded T-800 coating material. Co and lave phases (Co₂MoCr and Co₃Mo₂Si) are detected in both the laser-cladded T-800 coating and the bulk T-800 materials. However, the sizes of the lave phases are measured as 7.9 ㎛ and 60.6 ㎛ for the laser-cladded and bulk T-800 materials, respectively. After the Al erosion tests, the erosion layer thicknesses of the three materials are measured as 91.50 ㎛ (HVOF MoB-CoCr coating), 204.83 ㎛ (laser cladded T-800), and 226.33 ㎛ (bulk T-800). In the HVOF MoB-CoCr coating material, coarse cracks and delamination of the coating layer are observed. On the other hand, no cracks or local delamination of the coating layer are detected in the laser T-800 material even after the Al erosion test. Based on the above results, the authors discuss the appropriate material and process that could replace conventional bulk T-800 materials used as molten Al pots.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.153-154
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• 2002

Wear map of silver coatings on AISI 52100 has been constructed to delineate the wear transition behavior with the change in operating conditions in various environments. Three main regimes were clearly identified: (i) elastic/plastic deformation of silver coating without failure. (ii) mild wear regime after initial failure of silver coating and (iii) severe wear regime. In the mild wear regime, the contact surfaces were covered with transfer layers of agglomerated wear particles. The transfer layer acted as a protective layer and resulted in low friction even after the initial failure of the coated films, whose characteristics were strongly dependent on both the operating and environmental conditions. Also, the existence of the critical sliding speed, above which no transfer layer was able to form, was discussed in the work.

• 한국임상수의학회지
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• 제13권2호
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• pp.184-194
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• 1996

A comparative study of three absorbable suture materials of chromic catgut, Dexon II (a polyglycolic acid suture with a polycaprolate coating system) and Coated Vicryl (a polyglactin 910 suture with a glycolide-lactide-calcium stearate coating system) was undertaken in terms of tensile strength, breaking elongation, appearances of the suture materials in the subcutaneous layer of rats and of tissue reaction in the intramuscular layer of rats. The initial tensile strength of chromic catgut and the tensile strength after 21 days were about 1.55 kg and 0.19 kg, respectively. Those of Dexon II were about 2.01 kg and 0. 20 kg, respectively. Those of Coated Vicryl were about 2.39 kg and 0.48 kg, respectively. Coated Vicryl showed the highest tensile strength among the three materials during the whole period. On the other hand, Dexon II showed the highest breaking elongation among the three materials during the first week. But the breaking elongation of Dexon II rapidly continuously decreased during the whole period. The appearances of the suture materials in the subcutaneous layer of rats showed that chromic catgut was the fastest among the three materials, whereas it formed comparatively much connective tissue. The intramuscular absorption rate and tissue reaction of Dexon II were similar to those of Coated Vicryl. The intramuscular absorption rate of these was fairly late when compared with chromic catgut. And the tissue reaction appearance of these showed the formation of a granuloma with foreign body giant cells, macrothages and epitheloid cells by the 28th day in the experimental period.

• Journal of Welding and Joining
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• 제33권1호
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• pp.49-53
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• 2015

An experimental study was conducted to investigate the effect of carbon nanotubes on the zinc corrosion resistance of sealing layer formed on the Tungsten Carbide spray coating. Using the nanotubes, a sealing agent in the form of solid-liquid suspensions was made and applied to the surface of spray coating. A series of experiments, consisted of three stages such as preparation of test piece, molten-pot immersion test, and evaluation of micro structure, were undertaken to demonstrate complicated interaction existing between zinc ions and sealing layer containing the nanotubes. Experimental results showed newly developed sealing layer were less susceptible to corrosion and thus coated layer was well protected even in the case of 10 days exposure. Comparison of the micro structure after molten pot test also indicated that carbon nanotubes still remained in the matrix and organized more reliable frame work constituted with boron nitride and chromium compound. It was revealed that carbon nanotubes in the sealing layer played positive role to enhance zinc corrosion resistance in the perspective of both fibrous structure and inherent chemical stability.

• 한국해양공학회지
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• 제15권4호
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• pp.60-65
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• 2001

Thermal spray coating is formed by a process in which melted particles flying with high speed towards substrate, then crash and spread on the substrate surface cooled and solidified in a very short time, Stacking of the particles makes coating. In this study, the exfoliation of $Al_2$O$_3$ and Ni-4.5wt.%Al thermally sprayed coating which were deposited by an atmospheric plasma spray apparatus are investigated using an AE method. A tensile test is conducted on notch specimens in a stress range below the elastic limit of substrate. The wave forms of AE generated from the three coating specimens can be classified by FFT analysis into two types which low frequency(type I waveform is considered to corresponds exfoliation of coating layers and type II waveform corresponds the plastic deformation of notch tip or the resultant fracture of coating. The fracture of the coating layers can estimate by AE event and amplitude, because AE features increase when the deformation generates.