• Title/Summary/Keyword: thickness variation

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Fabrication of functional nanoparticles by layer-by-layer self-assembly method (LBL 법을 이용한 기능성 나노 입자 제조)

  • Kim, Jin-Ho;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Sae-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.6
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    • pp.305-310
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    • 2009
  • $TiO_2$ thin films consisting of positively charged poly (diallyldimethylammonium chloride) (PDDA) and negatively charged titanium (IV) bis (ammonium lactato) dihydroxide (TALH) were successfully fabricated on a poly (methyl methacrylate) (PMMA) by layer-by-layer (LBL) self-assembly method. By the measurement of quartz crystal microbalance (QCM), it was found that as the solution pH of TALH decreased, the deposition volume of TALH increased and the thickness of (PDDA/TALH) thin film coated on the surface of PMMA particles increased. The PMMA particles coated with the coating sequence of (PDDA/TALH)n showed the variation of color changes as a function of the number of bilayer. The number of bilayer (n) of (PDDA/TALH) thin films was 10 and 20, the values of $a^*$ and $b^*$ decreased from those of PMMA particles without coating films and the color changes was shifted to green and blue direction in the $a^*$, $b^*$ chromaticity diagram. And then, the number of n increased to 30 and 40, the values of $a^*$ and $b^*$ increased and the color changes was shifted to red and yellow direction, respectively. Finally the PMMA particles coated with $(PDDA/TALH)_{50}$ thin film showed a little same value of $a^*$ and $b^*$ with the PMMA particles without (PDDA/TALH) thin film.

Micro-silica Mixed Aqua-epoxy for Concrete Module Connection in Water : Part 1 - Material Development and Evaluation (해상 프리캐스트 콘크리트 부유체 모듈 가접합을 위한 마이크로 실리카 혼입 수중용 에폭시 접합 성능 검토 : Part 1 - 재료 개발 및 성능 검토)

  • Choi, Jin-Won;Kim, Young-Jun;You, Young-Jun;Kwon, Seung-Jun;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.27 no.1
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    • pp.21-28
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    • 2015
  • Recent studies on concrete floating structure development focused on connection system of concrete modules. Precast concrete modules are designed to be attached by prestressing in the water, exposing the structure to the loads from water and making the construction difficult. Therefore, a development of bond material became a key issue in successful connection of floating concrete modules. In this study, micro-silica mixed aqua epoxy (MSAE) is developed for the task. Existing primer aqua epoxy, originally used as a bond material for the retrofit of concrete structures using fiber reinforced polymers, is evaluated to find the optimum micro-silica added mix proportion. Micro-silica of 0~4 volume % was mixed in standard mixture of aqua epoxy. Then, the material property tests were performed to study the effect of micro-silica in aqua epoxy by controlling the epoxy silane proportion by 0, ${\pm}5$, ${\pm}10%$. The optimum mix design of MSAE was derived based on the test results. The MSAE was used to connect concrete module specimens with the epoxy thickness variation of 5, 10, and 20mm. Then, 3-point loading test was performed to verify the bond capacity of MSAE. The results show that MSAE improves the bond capacity of concrete module.

THE EFFECT OF FERMENTED FOODS ON THE COLOR AND HARDNESS CHANGE OF DENTURE BASE ACRYLIC RESINS (발효음식이 의치상레진의 색상 및 표면경도 변화에 미치는 영향)

  • Jeon, Yeol-Mae;Lim, Heon-Song;Shin, Soo-Yeon
    • The Journal of Korean Academy of Prosthodontics
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    • v.42 no.4
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    • pp.344-355
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    • 2004
  • Statement of problem: For a long time, many of denture base acrylic resins have been used for edentulous and partial edentulous patients because of easy manipulation and good mechanical properties, but its esthetic aspect has not been commented enough. Denture base acrylic resins also has caused esthetic problems due to discoloration or staining as in esthetic restoration. Many researches and reports have treated the problems and accomplished esthetic improvement. But these researches and reports dealt with general food colors or beverages, not with fermented foods. Purpose: This study is designed to assess what fermented foods, such as soy sauce, gochujang, and toenjang that many of Koreans have taken in, influence on the color and hardness variation of denture base acrylic resins. Materials and methods: For the procedure, twelve disks per 4 denture base acrylic resins were fabricated with a thickness of 2mm and 16mm in diameter. Each seven specimen were measured for discoloration with spectrophotometer, while the others, five specimen, for surface hardness change with Barcol hardness tester, over time. Each 12 specimen were immersed into the 4 beakers of fermented foods(soy sauces, gochujangs, toenjangs, deionized water), and $L^{*},a^{*}$, and $b^*$ values were measured for the color difference$({\Delta}E^*)$, on the 1st, 7th, and 28th day with spectrophotometer, with the measurement of surface hardness change. Each data observed was processed statistically. Results: The findings are as follows; Discoloration 1. All of denture base resins was not influenced by the kind of fermented foods, except for $QC20^{(R)}$ 2. Soy sauce and red pepper paste caused more change for denture base resins than deionized water and soy bean paste, except for Perform$^{(R)}$ 3. Most significant change was shown in Lucitone 199$^{(R)}$, whereas Perform$^{(R)}$ results in the least change for all immersed solution, with no statistical significance. Hardness change 1. Barcol hardness values in deposited specimens have been changed low degree, but with significant statistical change according to the kind of food and duration. 2. Lucitone$^{(R)}$ 199 as significantly lower Barcol hardness value than others do. Conclusion: Based on the above results, it suggests that the habitual intake of fermented foods is not helpful for the color stability of denture base acrylic resins because Soy sauce and red pepper paste mainly caused discoloration and surface hardness change. Particularly $Lucitone199^{(R)}$ shows specific discoloration and low surface hardness values. Therefore, it is recommended giving caution patients with denture of $Lucitone199^{(R)}$ especially against the habitual intake of fermented foods like soy sauce and red pepper paste.

An Experimental Study on the Failure of a Novel Composite Sandwich Structure (새로운 형상의 복합재 샌드위치 체결부 구조의 파손거동 연구)

  • Kwak, Byeong-Su;Kim, Hong-Il;Dong, Seung-Jin;Choi, Jin-Ho;Kweon, Jin-Hwe
    • Composites Research
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    • v.29 no.4
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    • pp.209-215
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    • 2016
  • The failure of composite sandwich structures with thickness and material variation was studied. The main body of the structure is sandwich plate made of the carbon composite face and Aluminum honeycomb core. It is connected with composite laminated flange without core through transition region of tapered sandwich panel with foam core. Tension and compression tests were conducted for the total of 6 panels, 3 for each. Test results showed that the panels under compression are vulnerable to the face failure along the material discontinuity line between two different cores. However the failure load of which panel does not show such failure can carry 16% more load and fails in honeycomb core and face debonding. For the tensile load, the extensive delamination failure was observed at the corner radius which connects the panel and the flange. The average failure load for compression is about 7 times the tensile failure load. Accordingly, these sandwich structures should be applied to the components that endure the compressive loadings.

A Study on the Paper Clothing -on the basis of handmade paper- (종이 의상에 관한 연구 - 수제지를 중심으로 -)

  • 이주실;김정혜
    • Journal of the Korean Society of Costume
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    • v.44
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    • pp.181-199
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    • 1999
  • The industry of modern clothing has deviated from the overflow of commercialism and the standardization and nowadays is going toward pursuing art, creativity, and high added value. This trend brings the return of the natural materials from the synthetic textiles and increases the value of old and handmade fabrics. Finally, the handmade-paper, which is a natural material, comes to be reconsidered as a new material for the clothing. Therefore, as the natural materials and the manufacture of handmade clothing are rising again, the qualitative improvement and globalization of clothing industry should be first realized through the developments of creative and various clothing materials and new expressing techniques. The above investigation and study have been synthesized and analyzed as follows: First, through the study on the origin of the paper clothing, its historical background and the process of its development, we've learned these two facts following : the paper clothing of the East in the past mostly had practiced meanings. On the other hand, in the West it had meanings which were raised the artist's emotions and beauty-consciousness to the artistic level by the various kinds of expressing methods. Second, handmade-paper was manufactured by the embedding method, which mixed mulberry pulp, gauze, corn, hair, sisal, silk and so on. It was found that handmade-paper had the affluent and proper texture as the clothing material and was be able to control the clarity through the variation of thickness. It was also confirmed that the creative and original texture with hand-worked molding beauty was obtained by the use of handmade-paper. Third, when the handmade-paper is used, the molding beauty of plane, relievo, and solid can be freely pursued, and various and effective molding conformation can be constructed by the effect of superposition and repetition. Also, because the maximum discretion from the various optional manufacturing methods is allowed, the molding beauty can be maximized when the clothes are manufactured with handmade-paper. Fourth, the gauze with strong drape was combined to overcome the stiffness and the tearing of the paper. As a result, the durability and the wearability of the paper were strengthened and thus the thus the applications as the clothing material were enlarged. In conclusion, in order to enhance the value, creativity, practicality, and artistic sense of the design for modern clothing, the clothes made of handmade-paper should be more studied. Moreover, for the generalization of paper clothes, the studies on the development of practical paper with paper with water resistance, post-treatment after dyeing, flexibility, and durability should be done. I really hope that this study will be the motive to provoke the possibility of handmade-paper as new clothing material in not only practical sense but also artistic sense.

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Tunnel Magnetoresistance with Top Layer Plasma Oxidation Time in Doubly Oxidized Barrier Process (이중 절연층 공정에서 상부절연층의 산화시간에 따른 터널자기저항 특성연구)

  • Lee, Ki-Yung;Song, Oh-Sung
    • Journal of the Korean Magnetics Society
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    • v.12 no.3
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    • pp.99-102
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    • 2002
  • We fabricated TMR devices which have doubly oxidized tunnel barrier using plasma oxidation method to form homogeneously oxidized AlO tunnel barrier. We sputtered 10 $\AA$-bottom Al layer and oxidized it with oxidation time of 10 sec. Subsequent sputtering of 13 $\AA$-Al was performed and the metallic layer was oxidized for 50, 80, and 120 sec., respectively. The electrical resistance changed from 500 Ω to 2000 Ω with increase of oxidation time, while variation of MR ratio was little spreading 27∼31 % which is larger than that of TMR device of ordinary single tunnel barrier. We calculated effective barrier height and width by measuring I-V curves, from which we found the barrier height was 1.3∼1.8 eV sufficient for tunnel barrier, and the barrier width (<15.0 $\AA$) was smaller than physical thickness. Our results may be caused by insufficient oxidation of Al precursor into A1$_2$O$_3$. However, doubly oxidized tunnel barriers were superior to conventional single tunnel barrier in uniformity and density. Our results imply that we were able to improve MR ratio and tune resistance by employing doubly oxidized tunnel barrier process.

Properties of Light-weight Expanded Bonded Leather Using Thermal Expandable Microspheres (열 팽창성 Microsphere를 적용한 경량 발포 재생피혁 특성 분석)

  • Shin, Eun-Chul;Kim, Won-Ju;Kim, Yeong-Woo
    • Journal of Adhesion and Interface
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    • v.21 no.3
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    • pp.81-85
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    • 2020
  • Shaving dust is a collagen fiber that is the leather waste occurred for thickness adjustment during the natural leather manufacturing process, and causes problems such as an environmental contamination because of a chromium (Cr) contained when it comes to reclaiming process. Various studies applying the shaving dust are currently being conducted in many countries across the world with an initiative by the EU. Of those applications, the bonded leather is being highlighted as a substitute for natural leather. Since the bonded leather, however, uses latex as a binder, accordingly it entails a high weight and a poor ventilation, which are deemed as disadvantages due to its dense internal tissues compared to other synthetic leathers. To address such disadvantages, this study employed the thermally expandable micro sphere to improve its air permeability and light weight by alleviating the internal structure. This is a study on the manufacturing of light bonded leather using the shaving dusts. In the study, the shaving dusts were forced to foam under 100~120℃ considering the heat resistance of collagen fiber after applying the thermally expandable micro sphere, and then the tendency was analyzed. In the analysis results, the most excellent foaming rate was exhibited when the shaving dusts were treated under 120℃ for 8 minutes and the variation of internal structure according to a foaming was observed through SEM analysis for the cross-section of the bonded leather.

Agronomic features and yield components of sago palms grown in the islands in Southeast Asia and Melanesia

  • Ehara, Hiroshi;Naito, Hitoshi;Mishima, Takashi;Toyoda, Yukio;Mizota, Chitoshi;Susanto, Slamet;Bintoro, M.H.;Pasolon, Yulius B.;Abbas, Barahima;Suwignyo, Rujito A.;Munandar, Munandar
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.360-360
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    • 2017
  • Morphological characteristics indicating agronomic features and yield components (trunk length, trunk diameter, thickness of bark, pith density, dry-matter percentage of pith and starch concentration in pith) of sago palms (Metroxylon sagu Rottbøll) were compared between the 27 populations grown in the islands in Southeast Asia (West Sumatra, South Sumatra, West Java, Southeast Sulawesi, Ternate, Halmahera and Seram in Indonesia) and the 20 populations grown in Melanesia (West Papua in Indonesia, East Sepik and New Ireland island in Papua New Guinea). The average starch yield calculated based on the yield components was $310kg\;plant^{-1}$ and $244kg\;plant^{-1}$ in the islands in Southeast and Melanesia, respectively. The variation of starch yield in Melanesia (CV: about 80%) was larger than that in the islands in Southeast Asia (CV: about 60%). The difference in starch yield in the islands in Southeast Asia was mainly attributed to the trunk diameter breast height and the dry-matter percentage of pith. In contrast, the differences in trunk length and dry-matter percentage of pith mainly accounted for the difference in starch yield in Melanesia. The sago palms in the islands in Southeast Asia had a comparatively thick and short trunk and those in Melanesia had a comparatively thinner and longer trunk. However, the average pith dry-matter yield was almost same level as $400kg\;plant^{-1}$ in both the islands in Southeast Asia and Melanesia. The difference in starch yield between the two areas was attributed to the difference in starch concentration in pith, 77% and 58% in the islands in Southeast Asia and Melanesia, respectively.

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Development of the pyramiding lines with strong culm genes derived from crosses among the SCM near isogenic lines in rice

  • Ookawa, Taiichiro;Kamahora, Eri;Ebitani, Takeshi;Yamaguchi, Takuya;Murata, Kazumasa;Iyama, Yukihide;Ozaki, Hidenobu;Adachi, Shunsuke;Hirasawa, Tadashi;Kanekatsu, Motoki
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.21-21
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    • 2017
  • Severe lodging has recurrently occurred at strong typhoon's hitting in recent climate change. The identification of quantitative trait loci (QTLs) and their responsible genes associated with a strong culm and their pyramiding are important for developing high-yielding varieties with a superior lodging resistance. To identify QTLs for lodging resistance, the tropical japonica line, Chugoku 117 and the improved indica variety, Habataki were selected as the donor parent, as these had thick and strong culms compared with the temperate japonica varieties in Japan such as Koshihikari. By using chromosome segment substitution lines (CSSLs) in which chromosome segments from the japonica variety were replaced to them from Habataki, we identified the QTLs for strong culm on chrs. 1 and 6, which were designated as STRONG CULM1 (SCM1) and STRONG CULM2 (SCM2), respectively. By using recombinant inbred lines (BILs) derived from a cross between Chugoku 117 and Koshihikari and introgression lines, we also identified the other QTLs for strong culm on chrs. 3 and 2, which were designated as STRONG CULM3 (SCM3) and STRONG CULM4 (SCM4), respectively. Candidate region of SCM1 includes Gn1 related to grain number. SCM2 was identical to APO1, a gene related to the control of panicle branch number, and SCM3 was identical to FC1, a strigolactone signaling associated gene, by performing fine mapping and positional cloning of these genes. To evaluate the effects of SCM1~SCM4 on lodging resistance, the Koshihiakri near isogenic line (NIL) with the introgressed SCM1 or SCM2 locus of Habataki (NIL-SCM1, NIL-SCM2) and the another Koshihikari NIL with the introgeressed SCM3 or SCM4 locus of Chugoku 117 (NIL-SCM3, NIL-SCM4) were developed. Then, we developed the pyramiding lines with double or triple combinations derived from step-by-step crosses among NIL-SCM1 NIL-SCM4. Triple pyramiding lines (NIL-SCM1+2+3, ~ NIL-SCM1+3+4) showed the largest culm diameter and the highest culm strength among the combinations and increased spikelet number due to the pleiotropic effects of these genes. Pyramiding of strong culm genes resulted in much increased culm thickness, culm strength and spikelet number due to their additive effect. SCM1 mainly contributed to enhance their pyramiding effect. These results in this study suggest the importance of identifying the combinations of superior alleles of strong culm genes among natural variation and pyramiding these genes for improving high-yielding varieties with a superior lodging resistance.

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Delineation of Geological Weak Zones in an Area of Small-scale Landslides Using Correlation between Electrical Resistivity, Bore, and Well-logging Data (전기비저항 및 시추·검층자료의 상관해석을 통한 소규모 산사태 지역의 지질 연약대 파악)

  • Lee, Sun-Joong;Kang, Yu-Gyeong;Lee, Cheol-Hee;Jeon, Su-In;Kim, Ji-Soo
    • The Journal of Engineering Geology
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    • v.30 no.1
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    • pp.31-42
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    • 2020
  • Electrical resistivity and downhole seismic surveys were conducted together with bore investigations and well-logging to examine subsurface structures in small-scale landslides at Sinjindo-ri, Geunheung-myeon, Taean-gun, Chungcheongnam-do, Republic of Korea in 2014. On the basis of the low N-values at depths of 5~7 m in borehole BH-2, downhole seismic and electrical dipole-dipole resistivity surveys were performed to delineate geological weak zones. The low-resistivity zones (<150 Ω·m) measure ~8 m in thickness and show a close depth correspondence to weathered soils consisting mainly of silty clays as identified from the bore investigations and well-logging data. Compared with weak zones in borehole BH-1, weak zones in BH-2 are characterized by lower densities (1.6~1.8 g/㎤) and resistivities (<150 Ω·m) and greater variation in Poisson's ratio. These observations can be explained by the presence of wet silty clays rich in weathered soil material that have resulted from heavy rainfall and rises in groundwater level. Downslope movements are probably caused by the sliding of wet clay that acts to reduce the strength of the weathered soil.