• Title/Summary/Keyword: thickness shrinkage

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Effect of Heat Treatment Temperature and Coating Thickness on Conversion Lens for White LED (백색 LED용 색변환 렌즈의 열처리 온도 및 코팅 두께에 따른 영향)

  • Lee, Hyo-Sung;Hwang, Jong Hee;Lim, Tae-Young;Kim, Jin-Ho;Jung, Hyun-Suk;Lee, Mi Jai
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.533-538
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    • 2014
  • Today, silicon and epoxy resin are used as materials of conversion lenses for white LEDs on the basis of their good bonding and transparency in LED packages. But these materials give rise to long-term performance problems such as reaction with water, yellowing transition, and shrinkage by heat. These problems are major factors underlying performance deterioration of LEDs. In this study, in order to address these problems, we fabricated a conversion lenses using glass, which has good chemical durability and is stable to heat. The fabricated conversion lenses were applied to a remote phosphor type. In this experiment, the conversion lens for white LED was coated on a glass substrate by a screen printing method using paste. The thickness of the coated conversion lens was controlled during 2 or 3 iterations of coating. The conversion lens fabricated under high heat treatment temperature and with a thin coating showed higher luminance efficiency and CCT closer to white light than fabricated lenses under low heat treatment temperature or a thick coating. The conversion lens with $32{\mu}m$ coating thickness showed the best optical properties: the measured values of the CCT, CRI, and luminance efficiency were 4468 K, 68, and 142.22 lm/w in 20 wt% glass frit, 80 wt% phosphor with sintering at $800^{\circ}C$.

Taper phenomenon of UV-laser punching process on zero-shrinkage substrate (무수축 기판 상에 UV 레이저 가공에 의한 Taper 현상)

  • Ahn, Ik-Jun;Yeo, Dong-Hun;Shin, Hyo-Soon;Shim, Kwang Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.285-289
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    • 2015
  • With the miniaturization with both high functionality and high integrity of the probe cards, the highly precise laser punching on the zero-shrinkage high strength substrate has attracted more attention recently. Taper occurrence during laser-punching on green sheets appears as a problem in process. The size (diameter) difference between the entrance hole and the exit hole in tapered holes appeared to be inversely proportional to the hole size itself. To suppress taper occurrence, two-stage punching was adopted as the size of second hole was varied from $70{\mu}m$ to $79{\mu}m$ when punching $80{\mu}m$ via holes on the substrate with thickness of $380{\mu}m$. The minimal taper ratio of 11.9 % appeared with second hole size between 70 to $79{\mu}m$ before sintering. Taper ratio reduced to 7 % after zero-shrinkage sintering. The size difference between first hole and second hole appeared minimal when the size of second hole was 95~97 % to that of first hole.

Changes of Physical and Mechanical Properties of Firefighter Protective Clothing After Radiant Heat Exposure (노출시간과 열강도에 따른 복사열 노출후의 소방보호복의 물리적 특성과 역학적 특성변화)

  • ;N.Pan;G.Sun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.6
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    • pp.853-863
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    • 1999
  • the change of physical properties (thickness, weight, air permeability) and mechanical properties(abrasion resistance breaking load and displacement) of samples were determined after heat exposure by a RPP tester. The effect of exposure time and heat flux intensity on the changes and the relationship between physical properties and mechanical properties were investigated. FR treated cotton Kevlar/PBI and Nomex with different structureal characteristics were chosen for specimens. The changes of physical properties and mechanical properties were calculated based on their initial values before heat exposure. The longer exposure time and the high heat flux intensity the more changes of those properties. Heat flux intensity was more effective on the changes, The showed to be affected by an interplay of shrinkage and pyrolysis products loss. The changes of thickness and abrasion resistance showed to be higher for plain weave fabric and those of air permeabiliyt and breaking load and displacement for twill weave fabric. While FR treated cotton which have high RPP value experienced serious and detrimental changes after heat exposure Kevlar/PBI which has low RPP value showed no high changes. In conclusion it could be confirmed that when total performance of a protective clothing is estimated retention capability of physical and mechanical properties after heat exposure as well as RPP value must be considered.

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Flexural Cnaracteristics of Polymer Concrete Sandwich Constructions (폴리머 콘크리트 샌드위치 구조재의 휨특성)

  • 연규석
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.31 no.2
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    • pp.125-134
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    • 1989
  • This study was conducted to investigate the flexural behaviour of sandwich constructions with cement concrete core and polymer concrete facings. Six different cross-sectional shapes using epoxy based polymer concrete facings were investigated. Some of the results from the static tests are given including the load-deflection responses, load-strain relationships, ultimate moment, and mode of failure. From the. results the following conclusions can be made. 1. The various strengths of polymer concrete were very high compared to the strengths for portland cement concrete, while modulus of elasticity assumed an aspect of contrast. 2. The thickness of core and facing exerted a great influence on the deflection and ultimate strenght of polymer concrete sandwich constructions. 3. The variation shape of deflection and strain depend on loading were a very close approximation to the straight line. The ultimate strain of polymer concrete at the end of tensile side were ranged from 625x10-6 to 766x10-6 and these values increased in proportion to the decrease of thickness of core and facings. 4. The ultimate moments of polymer sandwich constructions were 3 to 4 times that of cement concrete constructions which was transformed same section. It should he noted that polymer concrete have an effect on the reinforcement of weak constructions. 5. Further tests are neede to investigate the shear strain of constructions, and thermal expansion, shrinkage and creep of cement and polymer concrete which were composite materials of sandwich constructions.

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Extended Unmixing-Mixing Scheme for Prediction of 3D Behavior of Porous Composites (다공성 복합재료의 삼차원 거동 예측을 위한 분리-혼합 기법의 확장)

  • Choi, Hoi Kil;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.2
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    • pp.91-97
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    • 2013
  • Pyrolysis and surface recession of charring composites are progressed primarily in the thickness direction. The unmixing-mixing scheme is applied to describe the in-plane and through-thickness behaviors of porous composites. The extended unmixing-mixing equations are based on transverse isotropy of unidirectionally fiber-reinforced composites. The strain components of gas pressure in pores, thermal expansion, and chemical shrinkage are included in the constitutive model. By analyzing micromechanical representative volume elements of porous composites, the validity of the derived equations are examined.

The Change of the Physical Properties of PET Fabrics Treated in NaOH/Quarternary Ammonium Salt Compound Solution (PET직물의 NaOH/4급암모늄염 혼합액에 의한 물성변화)

  • 오수민;조승식
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.3
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    • pp.287-297
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    • 1994
  • The purpose of this study is to investigate the Improvement of fiber surface, tenacity & elogation, fabric counts, thickness, handle, moisture regain, static voltage, handle, dyeability when polyester fabrics are treated with NaOH solution adding quartemary ammonium salt (Benzyl dimetyl dodecyl ammonium chloride . BDMDAC) The results are as follows. I. In regard to the method of processing VET, when the PET fabrics are alkaline-hydrolyzed adding BDMDAC, the weight loss of PET fabrics increased remarkably to the increse of BDMDAC concentration than when they are treated only in NaOH solution. When PET fabrics are alkaline-hydrolyzed the amount of BDMDAC as the catalyst is proper lg/1 II. The change in physical & chemical properties of alkaline-hydrolyzed PET fabrirs. 1. As the amount of the weight loss on PET fabrics increased, the void space of the PET yale increased but tenacity & elongation and thickness decreased. 2. The fabric counts of PET increased due to shrinkage by alkaline-hydrolydzing. 3. As the amount of of the weight loss on PET fabrics increased. NUMERI, FUKURAMI, increaseed and KOSHI decreased and Total hand value(T.H.V) in all cases increaseed. When the weight Ioss is 30.9% T.H.V. is best. 4. Moisture regain of PET fabrics a little increased by alkaline-hydrolyzing treatment. As the weight loss increased, static voltage is decreased. 5. The last dye absorption is different according to the degree of the Affinity. In regard to the difference of dye color, the dyestuff of low molecular weight dyed for deep color.

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EFFECT OF FILM THICKNESS OF RESIN CEMENT ON BONDING EFFICIENCY IN INDIRECT COMPOSITE RESTORATION (레진 시멘트의 film thickness가 간접 복합 레진 수복물의 접착 효율에 미치는 영향에 관한 연구)

  • Lee, Sang-Hyuck;Choi, Gi-Woon;Choi, Kyung-Kyu
    • Restorative Dentistry and Endodontics
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    • v.35 no.2
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    • pp.69-79
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    • 2010
  • The purpose of this study was to evaluate the effect of film thickness of various resin cements on bonding efficiency in indirect composite restoration by measurement of microtensile bond strength, polymerization shrinkage, flexural strength and modulus, fractographic FE-SEM analysis. Experimental groups were divided according to film thickness (< $50\;{\mu}m$-control, $50\;{\mu}m$-T50, $100\;{\mu}m$-T100, $150\;{\mu}m$-T150) using composite- based resin cements (Variolink II, Duo-Link) and adhesive-based resin cements (Panavia F, Rely X Unicem). The data was analyzed using ANOVA and Duncan's multiple comparison test (p < 0.05). The results were as follows ; 1. Variolink II showed higher microtensile bond strength than that of adhesive-based resin cements in all film thickness (p < 0.05) but Duo-Link did not show significant difference except control group (p > 0.05). 2. Microtensile bond strength of composite-based resin cements were decreased significantly according to increasing film thickness (p < 0.05) but adhesive-based resin cements did not show significant difference among film thickness (p > 0.05). 3. Panavia F showed significantly lower polymerization shrinkage than other resin cements (p < 0.05). 4. Composite-based resin cements showed significantly higher flexural strength and modulus than adhesive-based resin cements (p < 0.05). 5. FE-SEM examination showed uniform adhesive layer and well developed resin tags in composite-based resin cements but unclear adhesive layer and poorly developed resin tags in adhesive-based resin cements. In debonded surface examination, composite-based resin cements showed mixed failures but adhesive-based resin cements showed adhesive failures.

Study on the Thickness Effect of the Separator for Lithium Secondary Batteries (리튬이차전지용 분리막의 두께에 따른 특성 연구)

  • Kim, Sang Woo;Seok, Ji-Hoo;Kim, Byung-Hyun Daniel;Cho, Hee-Min;Cho, Kuk Young
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.7-12
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    • 2014
  • There is increasing demand on the reducing the weight and the volume of the major components in lithium secondary battery to improve energy density. Separator not only provides pathway for lithium ion movement but also prevents direct contact between anode and cathode. Herein we fabricated polyethylene separator by varying biaxial stretching ratio to obtain membrane thickness of 16, 12, and $9{\mu}m$. Mechanical and thermal properties of the separator with different thickness were investigated. Also rate capability and charge-discharge cycle property up to 500 cycles were studied using coin type full-cell with $LiCoO_2$ and graphite as a cathode and an anode, respectively. All the cells using separator with different thickness demonstrated excellent capacity retention after 500cycles (around 80%). Considering the rate capability, cell using separator with thickness of $9{\mu}m$ showed best performance. Interestingly, separator thickness of $9{\mu}m$ was more resistant to heat contraction compared to that of $16{\mu}m$ separator.

PECVD를 이용한 비정질 실리콘 박막의 Adhesion 개선에 관한 연구

  • Han, Yeong-Jae;Choe, Yeong-Cheol;Kim, Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.316.2-316.2
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    • 2016
  • Device가 점점 Shrinkage 됨에 따라 미세 패터닝을 위하여 기존에 사용하던 박막은 Hardmask 로써 CD(Critical Dimension)가 제한적으로 이를 개선하기 위한 비정질 실리콘 (amorphous silicon)으로 대체하여 사용되는 Layer의 수가 증가하고 있다. 하지만 비정질 실리콘을 증착 시, 하부막에 따른 Adhesion 및 Hillocks과 같은 공정상에서 발생하는 문제들이 발생하게 되는데, 이는 소자의 특성을 떨어뜨리게 된다. 이러한 문제를 해결하고자 본 연구에서는 PECVD를 사용하여 비정질 실리콘 박막을 증착하였고, 그 특성을 분석하였으며, Adhesion 및 Hillock 개선을 위해 비정질 실리콘 박막 증착 전 처리를 최적화하여 특성을 개선하였다. 증착된 박막의 두께 및 굴절률은 Auto thickness measurement로 분석하였고, 표면 특성은 Field emission scanning electron microscopy(FE-SEM 그림 참고), 4 Point Bending TEST를 이용하여 분석을 수행하였다.

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A Study on the Washing Finishing Effects of Denim Fabrics (데님 직물의 워싱 가공 효과에 관한 연구)

  • Uh, Mi-Kyung;Suh, Mi-A
    • The Research Journal of the Costume Culture
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    • v.15 no.5
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    • pp.852-862
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    • 2007
  • This study was to investigate the physical properties and the external characteristics of denim fabrics(100% cotton non-spun denim, 98% cotton/2% polyurethane spun denim) such as tensile strength, thickness and weight, flex stiffness, surface color and shrinkage. The results of the study were as follows. After examining the change of external characteristics of before and after washing finishing for denim fabrics, denim with bio washing had increased pliability compared to denim without washing finishing but the pliability of the denim did not increase according to the intensity or frequency of washing. The luminance change according to washing finishing was high in the order of bio stone bleach washing, bio stone washing, bio washing and denim without washing finishing and the surface color became brighter in accordance with the increase of intensity and frequency of washing finishing.

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