• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.05a
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• pp.414-416
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• 2009

In order to build a transient simulation program for a high thrust liquid rocket engine(LRE), a static performance simulation program for components were made. The components were the thrust chamber (combustion chamber and supersonic nozzle), centrifugal pump (impeller and volute casing), impulse turbine, and flow control devices (control valve and orifice). Simplified mathematical models based on classical thermodynamic and inviscid theories were used to remove complexity and enhance the utility of the program. We examined the results of each program qualitatively for validate each component modeling.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.5
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• pp.72-81
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• 2011

In order to understand the operation characteristics and major design parameters of a dual combustion ramjet engine, a fundamental analysis model based on gasdynamics and thermodynamic theories was established. The preliminary performance analysis was accomplished and the results clearly describe the intimate relationship between air inlets, gas generator, and supersonic combustor. The methodology presented provides a means for quantitatively determining the geometries of the gas generator and supersonic combustor and assessing the effects on performance of each of the engine components. Also the design results for a basic configuration were provided.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.6
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• pp.586-595
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• 2010

An analytical study based on physical understandings and aero-thermodynamic theories was conducted to observe the performance characteristics and to derive the essential design parameters of dual ramjet(dual-combustion/dual-mode) propulsion for wide Mach number. The performances and operating limitations of the engines with two types combustors, such as constant pressure- and constant area- combustor, over various flight Mach numbers was investigated. Finally, the transition Mach number from ramjet to scramjet was carried out to optimize performance load balancing of ramjet and scramjet.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.35 no.9
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• pp.805-815
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• 2007

In order to build a conceptual design program for a liquid rocket engine system, performance based sub-programs for each core component of the engine system were made. Parts included were the combustion chamber, supersonic nozzle, centrifugal pump, and impulsive turbine. Simple mathematical models based on classical thermodynamic and inviscid theories were adopted with proper tuning by empirical data. In Part I, aiming to validate each sub-program, we examined the results of each program qualitatively, and parametrically investigated the sensitivity due to the change in design parameters.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.11a
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• pp.35-38
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• 2007

Aiming at time-dependent performance prediction of Liquid Rocket Engine(LRE) system, Modular Program for Conceptual Design of LRE is reviewed, and a modeling and dynamic analysis of rocket engine system with reference to Rocket Engine Dynamic Simulator(REDS) is outlined. Component modeling is based on classical thermodynamic and inviscid theories, and were formulated mathematically in terms of essential parameters. Essential design parameters are addressed. The rocket engine is modeled as a system of pipes with various hydraulic elements, and then the operate characteristic of that elements are simulated by solving conservation equation sequentially.

• Macromolecular Research
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• v.16 no.5
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• pp.446-456
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• 2008

A recent theoretical approach based on the coupling of both the Flory-Huggins (FH) and the Association Equilibria thermodynamic (AET) theories was modified and adapted to study the miscibility properties of a multi-component system formed by two polymers (a proton-donor and a proton-acceptor) and a proton-acceptor solvent, named copolymer(A)/solvent(B)/polymer(C). Compatibility between polymers was mainly attained by hydrogen-bonding between the hydroxyl group on the phenol unit of the poly(styrene-co-vinyl phenol) (PSVPh) and the carbonyl group of the biodegradable and environmentally friendly poly(3-hydroxybutyrate) (PHB). However, the self-association of PSVPh and specific interactions between the PSVPh and the H-acceptor group (an ether oxygen atom) of the epichlorohydrin (ECH) solvent were also established in a lower extension, which competed with the polymer-polymer association. All the binary specific interactions and their dependence with the system composition as well as with the copolymer content were evaluated and quantified by means of two excess functions of the Gibbs tree energy, ${\Delta}g_{AB}$ and ${\Delta}g_{AC}$. Experimental results from fluorescence spectroscopy were consistent with the theoretical simulations derived with the model, which could also be applied and extended to predict the miscibility in solution of any polymer blend with specific interactions.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.318-325
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• 2011

In order to understand the operation characteristics and major design parameters of a dual combustion ramjet engine, a fundamental analysis model based on gasdynamics and thermodynamic theories was established. The preliminary performance analysis was accomplished and the results clearly describe the intimate relationship between air inlets, gas generator, and supersonic combustor. The methodology presented provides a means for quantitatively determining the geometries of the gas generator and supersonic combustor and assessing the effects on performance of each of the engine components. Also the design results for a basic configuration were provided.

• Clean Technology
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• v.30 no.3
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• pp.228-238
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• 2024

Electrolytes are one of the essential components of a lithium-ion battery. They determine the battery's lifespan and cell characteristics. The dielectric constant is a key thermophysical property for determining how much salt can be dissociated and solvated in a solution. Hence, fast and reliable dielectric constant measurement is essential when formulating an electrolyte solution. This work implemented an open-ended coaxial probe (OECP) station as a quick and reliable tool to measure the complex permittivity spectra of electrolyte solutions. The capability of the OECP station was tested by measuring the complex permittivity of propylene carbonate (PC), dimethyl carbonate (DMC), and their mixtures from 0.1 to 8 GHz at 288.15, 298.15, and 308.15 K. The obtained dielectric spectra were then interpreted based on dielectric relaxation models and thermodynamic theories. The measured static dielectric constant data agreed well with the data from previous studies. They were also correlated using the Wang-Anderko thermodynamic model, showing approximately a 1% deviation from the experimental data. In addition, the relaxation characteristics, including the relaxation time and the Cole-Davidson exponent, showed that the microstructure of the solution significantly changes at the propylene carbonate mole fraction of 0.4. These results and methodologies are expected to contribute to the further understanding of electrolyte solutions and ultimately lead to the optimization of electrolyte formulation for lithium-ion batteries.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.3
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• pp.245-251
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• 2014

Pyroprocess for treating spent nuclear fuels has been developed based on electrochemical principles. Process simulation is one of the important methods for process development and experimental data analysis and it is also a necessary approach for pyroprocessing. To date, process simulation of pyroprocessing has been focused on electrorefining and there have been not so many investigations on electrolytic reduction. Electrolytic reduction, unlike electrorefining, includes specific features of gas evolution and porous electrode and, thus, different equations should be considered for developing a model for the process. This study summarized required concepts and equations for electrolytic reduction model development from thermodynamic, mass transport, and reaction kinetics theories which are necessitated for analyzing an electrochemical cell. An electrolytic reduction cell was divided and equations for each section were listed and, then, boundary conditions for connecting the sections were indicated. It is expected that those equations would be used as a basis to develop a simulation model for the future and applied to determine parameters associated with experimental data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.2
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• pp.264-274
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• 1997

A numerical analysis on condensation and coagulation of the metallic species with fly ash particles pre-existing in an incinerator was performed. Waste was simplified as a mixture of methane, chlorine, and small amounts of Pb and Sn. Vapor-phase amounts of Pb- and Sn -compounds were first calculated assuming a thermodynamic equilibrium state. Then theories on vapor-to-particle conversion, vapor condensation onto the fly ash particles, and particle-particle interaction were examined and incorporated into equations of aerosol dynamics and vapor continuity. It was assumed that the particles followed a log-normal size distribution and thus a moment model was developed in order to predict the particle concentration and the particle size distribution simultaneously. Distributions of metallic vapor concentration (or vapor pressure) were also obtained. Temperature drop rate of combustion gas, fly ash concentration and its size were selected as parameters influencing the discharged amount of metallic species. In general, the coagulation between the newly formed metal particles and the fly ash particles was much greater than that between the metal particles themselves or between the fly ash particles themselves. It was also found that the amount of metallic species discharged into the atmosphere was increased due to coagulation. While most of PbO vapors produced from the combustion were eliminated due to combined effect of condensation and coagulation, the highly volatile species, PbCl$_{2}$ and SnCl$_{4}$ vapors tended to discharge into the atmosphere without experiencing either the condensation or the coagulation. For Sn vapors the tendency was between that of PbO vapors and that of PbCl$_{2}$ or SnCl$_{4}$. To restrain the discharged amount of hazardous metallic species, the coagulation should be restrained, the number concentration and the size of pre-existing fly ash particles should be increased, and the temperature drop rate of combustion gas should be kept low.