• 한국항공우주학회지
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• 제33권4호
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• pp.71-78
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• 2005

초임계 상태의 질소 유동 환경에서 헵탄 액적의 기화 특성을 수치적으로 연구하였다. 더불어 실기체 효과와 액적 내부 순환, 다양한 열역학적 물성치 및 고압 효과를 고려하였다. 또한 헵탄 액적 바로 근처에서의 저속 유동 문제를 풀기 위하여 예조건화 스킴을 적용한 시간 전진법을 수치 코드에 적용하였다. 주위 유동 속도와 주위 압력을 변화 시켜가면서 액적의 거동을 살펴보았다. 유동 속도 증가로 인한 레이놀즈수의 증가에 따라 액적의 변형이 활발히 이루어졌고, 동일한 레이놀즈수에 대해서는 압력이 높아질수록 액적의 변형이 약화되었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2007년도 제28회 춘계학술대회논문집
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• pp.309-312
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• 2007

액체 로켓의 추진제로 이용되는 극저온 유체는 발사체의 경량화를 위한 터보 펌프의 고속화로 인해 공동현상이 발생하게 된다. 그러나 극저온 유체는 등온 유체인 물과는 달리 낮은 액상/증기 밀도 비율을 가지며 온도에 민감한 잠열변화율을 갖게 된다. 이에 따라 극저온 유체에서 공동 현상이 발생하게 되면, 증발 냉각 현상이 발생하게 되어 공동 내부와 주 유체 사이의 온도 차이가 발생하게 된다. 따라서 이러한 극저온 유체의 특징을 반영해 주기 위해 기존의 경험적 공동 현상 모델을 수정하여 새로운 모델을 적용하였다. 또한 온도 변화에 따른 효과를 반영해 주기 에너지 방정식을 첨가 하였다.

• International Journal of Air-Conditioning and Refrigeration
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• 제6권
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• pp.36-44
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• 1998

R-410a and R-407c which have the best potential among R-22 alternatives were tested as drop-in refrigerants against a set of R-22 baseline tests. The performance evaluations were carried out in a psychometric calorimeter test facility using the residential spilt type air conditioner under the ARI rating conditions. Except the lubricant and hand-operated expansion valve, the other parts of the air conditioner were the same with the commercial system. Performance characteristics were measured; compressor power, capacity, VCR, mass flow rate and COP. The tests showed that R-407c can be directly charged into the current refrigeration system because its vapor pressure and other thermochemical properties are similar to those of R-22. However, it is required to change the volume flow rate of compressor in order to achieve the volumetric capacity of R-22. This results from its relatively small VCR and capacity. Meanwhile, R-410a has vapor pressure values too high to be substituted for the current system and this resulted relatively low COP of R-410a compared to that of R-22.

• 설비공학논문집
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• 제9권1호
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• pp.82-91
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• 1997

R-410a and R-407c witch have the best potential among the substances being considered as R-22 alternatives were tested as "drop in" refrigerants against a set R-22 baseline tests for comparison. The performance evaluations were carried out in a psychrometric calorimeter test facility using the residential split-type air conditioner under the ARI rating conditions. Other than the use of different lubricant and a hand-operated expansion valve, one of the commercial systems was selected for the experiment. Performance characteristics were measured; compressor power, capacity, VCR, mass flow rate and COP. The tests showed that R-407c can be directly applied to the existing refrigeration system because of its similar vapor pressure and other thermopysical properties with those of R-22. However, it required change to the volume flow rate of compressor in order to achieve the similar performance with R-22 because of its relatively small VCR and capacity. Meanwhile, R-410a has too high a vapor pressure to be applied to the existing system and this feature results in relatively low COP of the system compared to that of R-22. But this could be improved by changing compressor design considering R-410a's relatively high VCR and capacity compared to those of R-22.

• 대한화학회지
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• 제11권4호
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• pp.143-149
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• 1967

액체 구조에 관한 천이상태 이론을 벤젠과 사염화탄소의 이성분 액체 혼합물에 적용시켰다. 각 성분의 상태합으로부터 액체 혼합물계의 상태합을 구하고, 이것으로부터 전체압, 부분압, 몰부파, 혼합엔트로피 및 압축율 등의 열역학적 성질을 여러 온도에서 계산하였다. 계산 결과는 문헌에서 얻은 실험값과 근사적으로 일치함을 발견하였다.

• Macromolecular Research
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• 제16권5호
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• pp.446-456
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• 2008

A recent theoretical approach based on the coupling of both the Flory-Huggins (FH) and the Association Equilibria thermodynamic (AET) theories was modified and adapted to study the miscibility properties of a multi-component system formed by two polymers (a proton-donor and a proton-acceptor) and a proton-acceptor solvent, named copolymer(A)/solvent(B)/polymer(C). Compatibility between polymers was mainly attained by hydrogen-bonding between the hydroxyl group on the phenol unit of the poly(styrene-co-vinyl phenol) (PSVPh) and the carbonyl group of the biodegradable and environmentally friendly poly(3-hydroxybutyrate) (PHB). However, the self-association of PSVPh and specific interactions between the PSVPh and the H-acceptor group (an ether oxygen atom) of the epichlorohydrin (ECH) solvent were also established in a lower extension, which competed with the polymer-polymer association. All the binary specific interactions and their dependence with the system composition as well as with the copolymer content were evaluated and quantified by means of two excess functions of the Gibbs tree energy, ${\Delta}g_{AB}$ and ${\Delta}g_{AC}$. Experimental results from fluorescence spectroscopy were consistent with the theoretical simulations derived with the model, which could also be applied and extended to predict the miscibility in solution of any polymer blend with specific interactions.

• 한국화재소방학회논문지
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• 제17권1호
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• pp.26-32
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• 2003

Halon대체 소화제로 쓰이는 불활성 기체 중 Ar, $N_2$, $CO_2$의 단일 성분일 때의 물성(포화압력, 밀도, 점도)에 관한 실험식을 구하였다. 문헌에서 얻은 실험 값을 이용하여 다항식 등의 회귀분석에 의해서 실험식을 얻었다. 포화압력은 온도에 대하여 각각 2차와 3차의 실험식으로 표시하였다. 밀도는 Ar, $N_2$는 온도에 대한 1차 함수로 표시하였고, $CO_2$는 온도에 대하여 각각 2차와 3차의 실험식으로 표시하였다. 점도는 온도에 대한 지수함수로 표시하였다. 이들 실험식을 이용하여 단일 성분일 때의 상태를 알 수 있다.

• 한국표면공학회지
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• 제39권3호
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• pp.129-136
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• 2006

The high velocity oxy-fuel sprayed coatings of 38Ni-23Co-20Cr-11Al-3Y-5Ta, 25Ni-34Co-20Cr-11Al-3Y-2Re and 32Ni-34.5Co-22Cr-11Al-0.5Ir (in wt%) were oxidized at 1000 and $1100^{\circ}C$ in air in order to find the alloying effect of Ta, Re and Ir on the oxidation properties of the NiCoCrAlY-base coatings. The primary phase of the coatings was $Ni_3Al$. The oxides formed on the coatings consisted primarily of ${\alpha}-Al_2O_3$, together with some $CoCr_2O_4,\;CoAl_2O_4$, and $Al_5Y_3O_{12}$. Tantalum oxidized to $Ta_2O_5$ and $Ta_2O_{22}$. However, no oxides of Re and Ir were detected by XRD owing to their thermodynamic inertness and/or their small amount.

• 한국분말재료학회지
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• 제5권1호
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• pp.64-70
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• 1998

Milling media of steel and partially stabilized zirconia(PSZ) were used to produce $Mo_3$Si by mechanical alloying(MA) of Mo-25.0at%Si elemental powder mixture. The effect of milling medium materials on MA of the powder mixture have been investigated by XRD and DTA. The reaction rate and the end-product noticeably depended upon the milling medium material. The formation of $Mo_3$Si and $Mo_5Si_3$phases by PSZ ball-milling took place after 15 hr of MA and was characterized by a slow reaction rate as Mo, Si, $Mo_5Si_3$ and $Mo_3$Si coexisted for a long period of milling time. The formation of a new phase by steel ball-milling, however, did not take Place even after 96 hr of MA. DTA and annealing results showed that $Mo_5Si_3$ and $Mo_3$Si were formed after heating the ball-milled powder specimens to different temperatures. At low temperatures, Mo and Si were transformed into $Mo_5Si_3$. At high temperatures, the formation of $Mo_3$Si can be partially attributed to the reaction, 7Mo+Si+$Mo_5Si_3$-.4$Mo_3$Si . The formation of $Mo_3$Si and Mo5Si3 phases by mechanical alloying of the powder mixture and the relevant reaction rate appeared to depend upon the milling medium material as well as the thermodynamic properties of the end-products.

• 한국분말재료학회지
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• 제11권5호
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• pp.421-426
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• 2004

The microstructure and mechanical property of hot-pressed $Al_2O_3/Cu$ composites with a different temperature for atmosphere changing from H$_{2}$ to Ar have been studied. When atmosphere-changed from H$_{2}$ to Ar gas at 145$0^{\circ}C$, the hot-pressed composite was characterized by inhomogeneous microstructure and low fracture strength. On the contrary, when atmosphere-changed at low temperature of 110$0^{\circ}C$ the composite showed more homogeneous microstructure, higher fracture strength and smaller deviation in strength. Based on the thermodynamic consideration and microstructural analysis, it was interpreted that the Cu wetting behavior relating to the formation of CuAlO$_{2}$ is probably responsible for strong dependence of microstructure on atmosphere changing temperature. The reason for a strong sensitivity of fracture strength and especially of its deviation to atmosphere changing temperature was explained by the microstructural inhomogeneity and by the role of CuAlO$_{2}$ phase on the interfacial bonding strength.