• Journal of applied mathematics & informatics
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• 제26권3_4호
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• pp.519-530
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• 2008

This paper studies the multi-domain coupled system of one dimensional Arctic temperature field and establishes identification model about the thermodynamic parameters of sea ice (heat storage capacity, density and conductivity) by the so-called output least-square estimate according to the temperature data acquired by a monitor buoy installed in the Arctic ocean. By the optimal control theory, the existence and dependability of weak solution and the identifiability of identification model have been given. Moreover, necessary optimality condition is proposed. Furthermore, the optimal algorithm for the identification model is constructed. By using the optimal thermodynamic parameters of Arctic sea ice, the numerical simulation is implemented, and the numerical results of temperature distribution of Arctic sea ice are demonstrated.

• 대한조선학회논문집
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• 제29권4호
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• pp.179-192
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• 1992

연속해 손상역학 분야의 열역학적 정식화 과정에 따라 연성재료의 탄소성-손상 구성방정식을 유도하였다. 이때, 재료 내부의 비가역적인 열역학적 상태변화를 표현하는 소성변형, 손상진전 등의 물리적현상을 내부상태변수로 간주하였다. 이 새로운 구성방정식 모형을 실제 문제에 적용함으로써 연성재료의 탄소성 거동 뿐만 아니라 재료의 자체가 손상을 입어 약화되는 과정 까지도 합리적으로 예측 가능함을 확인할 수 있었다.

• 한국환경과학회지
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• 제27권3호
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• pp.167-177
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• 2018

The removal characteristics of As and Se ions from aqueous solution by hexadecyl trimethyl ammonium bromide (HTMAB) modified anthracite (HTMAB-AT) were investigated under various conditions of contact time, pH and temperature. When the pH is 6, the zeta potential value of anthracite (AT) is -24 mV and on the other hand, the zeta potential value of the HTMAB-AT is +44 mV. It can be seen that the overall increase of about 60 mV. Increasing the (+) potential value indicates that the surface of the adsorbent had a stronger positive charge, so adsorption for the anion metal was increased. The isotherm data was well described by Langmuir and Temkin isotherm model. The maximum adsorption capacity was found to be 7.81 and 6.89 mg/g for As and Se ions from the Langmuir isotherm model at 298 K, respectively. The kinetic data was tested using pseudo first and pseudo second order models. The results indicated that adsorption fitted well with the pseudo second order kinetic model. The mechanism of the adsorption process showed that adsorption was dependent on intra particle diffusion model according to two step diffusion. The thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, and ${\Delta}S^{\circ}$) were also determined using the equilibrium constant value obtained at different temperatures. The thermodynamic parameters indicated that the adsorption process was physisorption, and also an endothermic and spontaneous process.

• 한국주조공학회지
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• 제25권1호
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• pp.36-39
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• 2005

The thermodynamic analysis of deoxidation in molten coppyr by Fe has been made. Equilibrium oxygen solubility saturated with FeO in Cu-Fe-O system has been derived without and with consideration of the solute interaction between Fe and O. The derived relationship of oxygen contents with Fe has been compared with the experimental results done by Kulkarni and the minimum oxygen solubility could be predicted by a simple first order interaction method, Wagner model.

• 대기
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• 제25권2호
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• pp.249-260
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• 2015

The changes in thermodynamic and dynamic aspects on near (2025~2049) and long-term (2075~2099) future climate changes between the historical run (1979~2005) and the Representative Concentration Pathway (RCP) 4.5 run with 20 coupled models which employed in the phase five of Coupled Model Inter-comparison Project (CMIP5) over East Asia (EA) and the Korean Peninsula are investigated as an extended study for Moon et al. (2014) study noted that the 20 models' multi-model ensemble (MME) and best five models' multi-model ensemble (B5MME) have a different increasing trend of precipitation during the boreal winter and summer, in spite of a similar increasing trend of surface air temperature, especially over the Korean Peninsula. Comparing the MME and B5MME, the dynamic factor (the convergence of mean moisture by anomalous wind) and the thermodynamic factor (the convergence of anomalous moisture by mean wind) in terms of moisture flux convergence are analyzed. As a result, the dynamic factor causes the lower increasing trend of precipitation in B5MME than the MME during the boreal winter and summer over EA. However, over the Korean Peninsula, the dynamic factor causes the lower increasing trend of precipitation in B5MME than the MME during the boreal winter, whereas the thermodynamic factor causes the higher increasing trend of precipitation in B5MME than the MME during the boreal summer. Therefore, it can be noted that the difference between MME and B5MME on the change in precipitation is affected by dynamic (thermodynamic) factor during the boreal winter (summer) over the Korean Peninsula.

• Structural Engineering and Mechanics
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• 제81권2호
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• pp.205-217
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• 2022

The thermodynamic properties of shaft lining concrete (SLC) are important evidence for the design and construction, and the spatial variability of concrete materials can directly affect the stochastic thermal analysis of the concrete structures. In this work, an array of field experiments of the concrete materials are carried out, and the statistical characteristics of thermophysical parameters of SLC are obtained. The coefficient of variation (COV) and scale of fluctuation (SOF) of uncertain thermophysical parameters are estimated. A three-dimensional (3-D) stochastic thermal model of concrete materials with heat conduction and hydration heat is proposed, and the uncertain thermodynamic properties of SLC are computed by the self-compiled program. Model validation with the experimental and numerical temperatures is also presented. According to the relationship between autocorrelation functions distance (ACD) and SOF for the five theoretical autocorrelation functions (ACFs), the effects of the ACF, COV and ACD of concrete materials on the uncertain thermodynamic properties of SLC are analyzed. The results show that the spatial variability of concrete materials is subsistent. The average temperatures and standard deviation (SD) of inner SLC are the lowest while the outer SLC is the highest. The effects of five 3-D ACFs of concrete materials on uncertain thermodynamic properties of SLC are insignificant. The larger the COV of concrete materials is, the larger the SD of SLC will be. On the contrary, the longer the ACD of concrete materials is, the smaller the SD of SLC will be. The SD of temperature of SLC increases first and then decreases. This study can provide a reliable reference for the thermodynamic properties of SLC considering spatial variability of concrete materials.

• 대한화학회지
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• 제58권3호
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• pp.251-257
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• 2014

Poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기 중, 증류수 용액에서 실행하였다. Eyring-Halsey 모델의 이론적인 응력완화식에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 비결정성 영역에서의 유동단위의 고찰을 위하여 유동 파라메타와 결정크기로부터 섬유고분자 물질의 자체확산, 홀 부피, 점성, 열역학파라메타 등을 계산하였다. 이들 시료의 유동 파라메타는 유동 단위의 홀부피, 자체확산, 유동 열역학 파라메타와 직접적인 연관을 갖는 것으로 규명되었다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권6호
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• pp.265-270
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• 2002

The determination of DNA hybridization reaction can apply the molecular biology research, clinic diagnostics, bioengineering, environment monitoring, food science and application area. So, the improvement of DNA hybridization detection method is very important for the determination of this hybridization reaction. Several molecular biological techniques require accurate predictions of matched versus mismatched hybridization thermodynamics, such as PCR, sequencing by hybridization, gene diagnostics and antisense oligonucleotide probes. In addition, recent developments of oligonucleotide chip arrays as means for biochemical assays and DNA sequencing requires accurate knowledge of hybridization thermodynamics and population ratios at matched and mismatched target sites. In this study, we report the characteristics of the probe and matched, mismatched target oligonucleotide hybridization reaction using thermodynamic method. Thermodynamic of 5 oligonucleotides with central and terminal mismatch sequences were obtained by measured UV-absorbance as a function of temperature. The data show that the nearest-neighbor base-pair model is adequate for predicting thermodynamics of oligonucleotides with average deviations for $\Delta$H$^{0}$ , $\Delta$S$^{0}$ , $\Delta$G$_{37}$ $^{0}$ and T$_{m}$, respectively.>$^{0}$ and T$_{m}$, respectively.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 2009년도 한국우주과학회보 제18권2호
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• pp.24.4-25
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• 2009

We have investigated the radiational fields through a hydrodynamical stellar model atmosphere. Stellar convection zone is the extremely turbulent region composed of partly ionized compressible gases in high temperature. Moreover, super-adiabatic layers are the transition region in energy transport from convection to radiation. Therefore, opacities and thermodynamic properties due to interaction of matter and radiational fields vary significantly with depth. In order to describe radiational fields accurately, the Opacity Distribution Function (ODF) and the Accelerated Lambda Iteration (ALI) have been applied to hydrodynamic medium. As the first result of our radiative transfer, we present time-dependant variation of radiational fields and thermodynamic structures. Our non-gray transfer model has been compared with the conventional Eddington Approximation. Detailed information of radiational fields and thermodynamic properties will provide deeper insight of physical processes inside stellar atmospheres.

• Bulletin of the Korean Chemical Society
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• 제18권5호
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• pp.501-509
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• 1997

In recent papers[Bull. Kor. Chem. Soc. 1996, 17, 735; ibid 1997, 18, 478] we reported results of molecular dynamics (MD) simulations for the thermodynamic, structural, and dynamic properties of liquid normal alkanes, from n-butane to n-heptadecane, using three different models. Two of the three classes of models are collapsed atomic models while the third class is an atomistically detailed model. In the present paper we present results of MD simulations for the corresponding properties of liquid branched-chain alkanes using the same models. The thermodynamic property reflects that the intermolecular interactions become weaker as the shape of the molecule tends to approach that of a sphere and the surface area decreases with branching. Not like observed in the straight-chain alkanes, the structural properties of model Ⅲ from the site-site radial distribution function, the distribution functions of the average end-to-end distance and the root-mean-squared radii of gyration are not much different from those of models Ⅰ and Ⅱ. The branching effect on the self diffusion of liquid alkanes is well predicted from our MD simulation results but not on the viscosity and thermal conductivity.