• Structural Engineering and Mechanics
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• v.76 no.1
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• pp.115-127
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• 2020

This study presents an analytical approach to investigate the thermodynamic behavior of functionally graded beam resting on elastic foundations. The formulation is based on a refined deformation theory taking into consideration the stretching effect and the type of elastic foundation. The displacement field used in the present refined theory contains undetermined integral forms and involves only three unknowns to derive. The mechanical characteristics of the beam are assumed to be varied across the thickness according to a simple exponential law distribution. The beam is supposed simply supported and therefore the Navier solution is used to derive analytical solution. Verification examples demonstrate that the developed theory is very accurate in describing the response of FG beams subjected to thermodynamic loading. Numerical results are carried out to show the effects of the thermodynamic loading on the response of FG beams resting on elastic foundation.

• Steel and Composite Structures
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• v.41 no.6
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• pp.873-886
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• 2021

In this paper, an analytical solution for thermodynamic response of functionally graded (FG) sandwich plates resting on variable elastic foundation is performed by using a quasi 3D shear deformation plate theory. The displacement field used in the present study contains undetermined integral terms and involves only four unknown functions with including stretching effect. The FG sandwich plate is considered to be subject to a time harmonic sinusoidal temperature field across its thickness with any combined boundary conditions. Equations of motion are derived from Hamilton's principle. The numerical results are compared with the existing results of quasi-3D shear deformation theories and an excellent agreement is observed. Several numerical examples for fundamental frequency, deflection, stress and variable elastic foundation parameter's analysis of FG sandwich plates are presented and discussed considering different material gradients, layer thickness ratios, thickness-to-length ratios and boundary conditions. The results of the present study reveal that the nature of the elastic foundation, the boundary conditions and the thermodynamic loading affect the response of the FG plate especially in the case of a thick plate.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.7
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• pp.735-743
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• 2015

The major component with a significant impact on the thermodynamic efficiency of the organic Rankine cycle is the turbine. Many difficulties occur in the turbine design of an organic Rankine cycle because the expansion process in an organic Rankine cycle is generally accompanied by a dramatic change in the working fluid properties. A precise preliminary design for a radial inflow turbine is hard to obtain using the classic method for selecting the loading and flow coefficients from the existing performance chart. Therefore, this study proposed a method to calculate the loading and flow coefficient based on the number of rotor vanes and thermodynamic design requirements. Preliminary design results using the proposed models were in fairly good agreement with the credible results using the commercial preliminary design software. Furthermore, a numerical analysis of the preliminary design results was carried out to verify the accuracy of the proposed preliminary design models, and most of the dependent variables, with the exception of the efficiency, were analyzed to meet the preliminary design conditions.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.132-132
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• 2006

Filler loading (fiber or particulate) usually increases the melt viscosity of polymers. In contrast, the addition of these fillers and fibrillation of thermotropic liquid crystalline polymer (LCP) jointly decreased the viscosity of polymer melts to lower than those of pure component polymers, filler-loaded or LCP-blended ones; and even decreased the viscosity with increasing filler loading. Termed as rheological hybrid effect, this phenomenon correlated well with the LCP fibrillation in these ternary systems. Research taking fillers of various shapes and sizes showed that the filler addition promoted the LCP fibrillation, depending upon thermodynamic and dynamic factors involved.

• KSBB Journal
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• v.10 no.4
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• pp.358-369
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• 1995

A mathematical model using local thermodynamic equilibrium isotherms for adsorption in encapsulated adsorbent is proposed in order to optimize the design parameters in situ bioproduct separation process. The model accurately follows the experimental data on the adsorption of berberine, secondary metabolite produced in Thaictrum rugosum plant cell culture. The adsorption rate on encapsulated adsorbent is compared with that on alginate-entrapped adsorbent. The result shows that the higher loading capacity in encapsulated adsorbent is mainly due to the increase in the maximum solid phase concentration. Based on the adsorption rate and loading capacity, the encapsulated adsorbent would be more useful than the entrapped adsorbent when used in situ bioproduct separation process. Design parameters in situ bioproduct separation process, such as the size of the capsule, membrane thickness, the ratio of capsule volume to bulk volume, the ratio of single capsule volume to total capsule volume and the adsorbent content in the capsule, are evaluated by using the model. The ratio of single capsule volume to total capsule volume is the most effective parameter for adsorption of berberine on encapsulated adsorbent.

• Advances in nano research
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• v.10 no.2
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• pp.175-189
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• 2021

In this article, frequency characteristics, and sensitivity analysis of a size-dependent laminated composite cylindrical nanoshell under bi-directional thermal loading using Nonlocal Strain-stress Gradient Theory (NSGT) are presented. The governing equations of the laminated composite cylindrical nanoshell in thermal environment are developed using Hamilton's principle. The thermodynamic equations of the laminated cylindrical nanoshell are obtained using First-order Shear Deformation Theory (FSDT) and Fourier-expansion based Generalized Differential Quadrature element Method (FGDQM) is implemented to solve these equations and obtain natural frequency and critical temperature of the presented model. The novelty of the current study is to consider the effects of bi-directional temperature loading and sensitivity parameter on the critical temperature and frequency characteristics of the laminated composite nanostructure. Apart from semi-numerical solution, a finite element model was presented using the finite element package to simulate the response of the laminated cylindrical shell. The results created from finite element simulation illustrates a close agreement with the semi-numerical method results. Finally, the influences of temperature difference, ply angle, length scale and nonlocal parameters on the critical temperature, sensitivity, and frequency of the laminated composite nanostructure are investigated, in details.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.127-134
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• 2020

The adsorption characteristics of the major tar compound, acenaphthene, derived from Taxus chinensis by the commercial adsorbent Sylopute were investigated using different parameters such as initial acenaphthene concentration, adsorption temperature, and contact time. Out of Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models, adsorption data were best described by Langmuir isotherm. The adsorption kinetics was evaluated by pseudo-first-order, pseudo-second-order and intraparticle diffusion models. The pseudo-second-order model was found to explain the adsorption kinetics most effectively. Thermodynamic parameters revealed the feasibility, nonspontaneity and exothermic nature of adsorption. In addition, the isosteric heat of adsorption was independent of surface loading indicating the Sylopute used as an energetically homogeneous surface.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.130-134
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• 2017

Organic aerosols dispersed in the atmosphere likely undergo phase separation. Such internally mixed particles are often described as comprising an organic phase and an aqueous phase separately. We studied the morphology of two liquid separated aerosols in the sub-microscale by using a simple thermodynamic model with Russian doll geometry. The morphology of particles can be easily predicted from the simple criteria on the surface tension and two algebraic equations (the volume constraint and Young equation). This result may give the potential explanation about the complex morphology of the organic airborne particles.

• Clean Technology
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• v.26 no.1
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• pp.30-38
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• 2020

The kinetic and thermodynamic parameters of Acid Red 66, adsorbed by granular activated carbon, were investigated on areas of initial concentration, contact time, and temperature. The adsorption equilibrium data were applied to Langmuir, Freundlich, Temkin, Redlich-Peterson, and Temkin isotherms. The agreement was found to be the highest in the Freundlich model. From the determined Freundlich separation factor (1/n = 0.125 ~ 0.232), the adsorption of Acid Red 66 by granular activated carbon could be employed as an effective treatment method. Temkin's constant related to adsorption heat (B_T = 2.147 ~ 2.562 J mol^-1) showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo-second order model with good agreement. The results of the intraparticle diffusion equation showed that the inclination of the second straight line representing the intraparticle diffusion was smaller than that of the first straight line representing the boundary layer diffusion. Therefore, it was confirmed that intraparticle diffusion was the rate-controlling step. From thermodynamic experiments, the activation energy was determined as 35.23 kJ mol^-1, indicating that the adsorption of Acid Red 66 was physical adsorption. The negative Gibbs free energy change (ΔG = -0.548 ~ -7.802 kJ mol^-1) and the positive enthalpy change (ΔH = +109.112 kJ mol^-1) indicated the spontaneous and endothermic nature of the adsorption process, respectively. The isosteric heat of adsorption increased with the increase of surface loading, indicating lateral interactions between the adsorbed dye molecules.

• Membrane Journal
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• v.17 no.3
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• pp.219-232
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• 2007

The polyethersulfone(PES)-titanium oxide($TiO_2$) hybrid membranes were prepared by immersion precipitation phase inversion method. The casting solution for the preparation of $PES-TiO_2$ hybrid membrane was provided by adding $TiO_2$ nano particles into the basis polymer solution of 14 wt% and 20 wt% PES/N-methyl-2-pyrrolidone(NMP). The $TiO_2$ loading [wt% ($TiO_2/NMP$)] in eating solution was varied from 0 to 60 wt%. Membrane performance and morphological change of the resulting $PES-TiO_2$ hybrid membranes were discussed in aspect of $TiO_2$ loading, by viscosity, coagulation value and light transmittance of the casting solution, measurement of tensile strength, pore size and contact angle, surface and cross sectional SEM images of the hybrid membrane, and ultrafiltration experiments using the hybrid membrane. According as increase of $TiO_2$ loading in the casting solution, viscosity is increased and coagulation value becomes lower, therefore the thermodynamic instability of the casting solution is increased. It is found that when $TiO_2$ loading is increased, 1) precipitation rate becomes faster while instantaneous demixing is maintained, 2) pure water flux, membrane pore size and compaction stability of the resulting membranes are increased, 3) tensile strength and contact angle are decreased. Dead-end ultrafiltration of bovine serum albumin(BSA) solution using the hybrid membrane shows that membrane performance(flux of BSA solution) enhanced up to 7 times compared with the results obtained using the pure PES membrane(not containing $TiO_2$ particle), due to the increase of hydrophilicity.