• 대한화학회지
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• 제37권3호
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• pp.335-343
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• 1993

나프탈렌, ${\alpha}$- 또는 ${\beta}$-메틸 나프탈렌 그리고 1,2- 1,3- 또는 2,6-디메틸나프탈렌과 클로라닐의 전하이동 착물의 흡수 극대 파장은 염화에틸렌, 염화메틸렌, 클로로포름 용매에서 그리고 10, 15, 20, 25$^{\circ}C$ 온도에서 자외선 분광광도법으로 측정하였다. 이 전하이동착물은 1:1 분자비로 결합하였으며 흡수극대 파장은 용매의 극성과 온도에 따라 변하였고, 형성상수(K$_f$)는 용매의 극성 그리고 온도가 증가함에 감소하였다. 이와같이 온도 및 용매가 형성상수에 미치는 효과를 열역학적 고찰로써 논의하였으며, 또한 전자주개들의 전자 및 입체 효과가 형성상수에 미치는 영향도 논의하였다.

• Membrane and Water Treatment
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• 제3권2호
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• pp.123-131
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• 2012

This study investigated the extraction and stripping performance of PIMs consisting of PVC and Aliquat 336. Extraction and stripping of three representative heavy metals - namely $Cd^{2+}$, $Cu^{2+}$, and $Zn^{2+}$ - by the synthesized membranes were evaluated as a function of sodium chloride concentration and under different stripping solutions (0.01 M $HNO_3$, Milli-Q water, 0.01 M HCl and 0.01 M NaOH), respectively. Results reported here indicate that the formation of negatively charged metal chloride complex species was responsible for the extraction of the target metal to PIMs. Experimental results and thermodynamic modeling of the speciation of chloro metal complexes further confirm that the extraction selectivity between $Cd^{2+}$, $Cu^{2+}$ and $Zn^{2+}$ can be controlled by regulating the chloride concentration of the feed solution. An acidic solution without any chloride was the most effective stripping solution, followed by Milli-Q water, and a diluted hydrochloric acid solution. On the other hand, the stripping of metals from PIMs did not occur when a basic stripping solution was used.

• 한국환경과학회지
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• 제3권2호
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• pp.89-100
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• 1994

It is very important to assess accurately the terms which are included in the heat budget equation of soil surface because they are used in the UM and miso-scale circulation modeling as well as in the micrometeorological studies. Each terms in the heat budget equation change according to the soil moisture content. So, it is necessary to specify clearly the relations between soil moisture content and these terms. Special experiment with micrometeorological measurements was executed to study these relations at Environmental Research Center of Tsukuba University, Japan. The results are as follow: 1. The soil moisture contents of 1 cm and 4 cm depth are oscillated with one day Period in drying process and the amplitude of variation of 1 cm depth is greater than that of 4 cm. 2. Increase in soil moisture contents due to precipitation result in decrease of albedo with step function. 3. Sensible heat is in reverse proportion to the soil moisture content and latent heat is in direct proportion to it. Latent heat is more sensitive than sensible heat according to the soil moisture variation. Net long wave radiation have high correlation with soil moisture. 4. Comparing with the radiative term with the flux term in wetting process due to precipitation, the energy transfer of the aero and thermodynamic flux is greater than that of the radiative heat flux.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
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• pp.88-93
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• 2002

$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ and $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}:Co^{2+}$ + single crystals were grown by CTR method. The grown single crystals have defect chalcopyrite structure with lattice constant a= 5.5966A. c= 10.8042${{\AA}}$ for the pure. a= 5.6543${{\AA}}$. c= 10.8205${{\AA}}$ for the Co-doped single crystal. respectively. The optical energy band gap was given as indirect band gap. The optical energy band gap was decreased according to add of Co-impurity. Temperature dependence of optical energy band gap was fitted well to the Varshni equation. From this relation. we can deduced the entropy. enthalpy and heat capacity. Also. we can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

• 전기학회논문지P
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• 제52권2호
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• pp.68-73
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• 2003

$Zn_4SnSe_6$ and $Zn_4SnSe_6:Co^{2+}$ single crystals were grown by the chemical transport reaction(CTR) method. They were crystallized in the monoclinic structure. These temperature dependence of the optical energy gap were closely investigated over the temperature range 10[K]~300[K]. The direct energy gaps of $Zn_4SnSe_6$ and $Zn_4SnSe_6$:$Co^{2+}$ single crystals were given by 2.146[eV] and 2.042[eV] at 300[K]. The temperature dependence of the optical energy gap is well presented by the Varshni equation.

• Bulletin of the Korean Chemical Society
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• 제5권1호
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• pp.44-49
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• 1984

The ionic association constant (K) of N-methyl pyridinium iodide (NMPI) ion in several ethanol-water mixtures were determined by the combination of UV spectroscopy and conductance measurements using the Shedlovsky function as a correction factor. The measurement of electrical conductance and UV absorption were performed in 95, 90, 80 and 60 volume percentages of ethanol in the solvent mixture at 15, 25, 35 and 45 $({\pm}0.1)^{\circ}C$. The ion size parameter $(r_A+_D-)$ and the dipole moment $({\mu}_A+_D-)$ of NMPI ion were obtained from he linear plots of ln K vs. (1/D) and (D-1)/(2D+1), respectively. These ${\mu}_A+_D-$ values were in good agreement with the values of transition moment calculated from the equation, ${\mu}_{nm}=6.5168{\times}10^{-2}{\times}({\varepsilon}_{max}{\frac{\bar{\nu}_{\frac{1}{2}}}{\bar{\nu}_{max}})^{\frac{1}{2}}$ (Debye) which we have derived. The thermodynamic parameters indicate (1) that the water dipoles have an ordered rearrangement around the dipolar NMPI ions rather than the configuration existing in bulk free waters; and (2) that the equilibrium state between NMPI ion and its component ions are controlled by entropy.

• Bulletin of the Korean Chemical Society
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• 제12권2호
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• pp.199-206
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• 1991

A statistical thermodynamic theory of thermotropic main-chain polymeric liquid crystalline melts is developed within the framework of the lattice model by a generalization of the well-known procedure of Flory and DiMarzio. According to the results of Vasilenko et al., the theory of orientational ordering in melts of polymers containing rigid and flexible segments in the main chain is taken into account. When the ordering of flexible segments in the nematic melt is correlated with that of rigid mesogenic groups, the former is assumed to be given as a function of the ordering of rigid mesogenic cores. A free energy density that includes short-range packing contributions is formulated. The properties of the liquid-crystalline transiton are investigated for various cases of the system. The results calculated in this paper show not only the order-parameter values but also the first-order phase transition phenomena that are similar to those observed experimentally for the thermotropic liquid-crystalline polymers and show the transitional entropy terms which actually increase upon orientational ordering. In the orientational ordering values, it is shown that mesogenic groups, flexible segments, and gauche energy (temperature) may be quite substantial. Finally, by using the flexibility term, we predict the highly anisotropic mesophase which was shown by Vasilenko et al.

• 대한화학회지
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• 제33권2호
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• pp.156-163
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• 1989

사염화탄소 용액중에서 thiopropionamide(TPA)와 N,N-dimethylalkylamides(DMF, DMA, DMP)간의 수소결합에 관한 열역학적 상수를 구하기 위하여 TPA의 근적외선 영역의 흡수띠 중에서 $ν_a+amide II$조합띠를 사용하여 5${\sim}$55$^{\circ}C$ 범위에서 실험하였다. TPA 단위체와 수소결합을 하고 있는 TPA의 혼합 흡수띠를 Lorentzian-Gaussian product function을 사용하여 개개의 띠로 분리하였다. 컴퓨터로 분해하여 얻은 개개의 흡수띠의 면적을 사용하여 단위체 및 1 : 1 복합체의 농도를 계산하였고 이로부터 평형상수를 구하였다. 열역학적 상수들은 온도의존 흡수띠를 분석하여 구하였다. TPA와 DMF, DMA 및 DMP간의 1 : 1 복합체의 ${\Delta}$$H^{\circ}$는 각각 -12.5, -13.5, -14.1kJ/mol이었고.${\Delta}$$S^{\circ}$는 각각 -15.2, -17.9, -22.3kJ/mol${\cdot}$deg이었다.

• 대한기계학회논문집B
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• 제38권7호
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• pp.625-638
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• 2014

본 연구에서는 천연가스 유량 측정에 사용되는 임계유동함수(CFF)를 AGA8-dc 상태방정식으로 계산할 때 CFF 계산값의 불확도를 평가하였다. CFF 계산에 사용되는 엔탈피, 엔트로피, 음속 식은 불확도 분석이 가능하도록 무차원 헬름홀츠 자유에너지(Helmholtz free energy, HFE)와 이의 편도함수로 표현하였고, HFE의 불확도를 추정하였다. 압축인자의 불확도에 의해 유발되는 종속 변수의 불확도를 반영하기 위해 AGA8-dc 압축인자 식을 해당 불확도만큼 편차가 생기는 형태로 변형하였고, 각 불확도 요인별로 불확도 기여도 평가 모델을 만들었으며, 이를 CFF 계산 프로그램에 적용하였다. 그 결과 CFF의 불확도는 압력 10, 50, 100 bar 에서 각각 0.025, 0.055, 0.112 % 정도로 평가 되었고 압력에 비례하여 증가하는 것을 확인하였다. 또한 본 결과를 기존 CFF 국제비교시험결과(1999년)에 적용한 결과 각 기관별 CFF 값의 차이를 적절히 설명하는 것도 알 수 있었다.

• 대한기계학회논문집B
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• 제37권12호
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• pp.1167-1173
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• 2013

본 연구에서는 천연가스 유량 측정에서 2차 표준으로 사용되는 소닉노즐 뱅크 -12개 노즐 패키지로 구성-의 임계유동함수 계산 시간을 1초 이하로 단축하고자 하였다. 이를 위해 AGA 8-dc 상태방정식을 적용한 헬름홀츠 자유에너지를 유도하고 이로부터 적분 항이 없는 열역학 상태량 식을 도출하여 CFF 계산에 적용하였다. 그 결과 CFF 계산 시간이 기존 6.7초/12개에서 0.6초/12개로 크게 감소하는 것을 확인할 수 있었고 이 계산 시간은 가스 성분 수와 거의 무관함도 알 수 있었다. 또한 본 계산 결과의 정확도를 확인하기 위해 기존 CFF 국제비교연구의 결과와 비교한 결과 차이가 없음도 확인하였다.