• 제목/요약/키워드: thermodynamic

검색결과 2,020건 처리시간 0.03초

Development of a three dimensional circulation model based on fractional step method

  • Abualtayef, Mazen;Kuroiwa, Masamitsu;Sief, Ahmed Khaled;Matsubara, Yuhei;Aly, Ahmed M.;Sayed, Ahmed A.;Sambe, Alioune Nar
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제2권1호
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    • pp.14-23
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    • 2010
  • A numerical model was developed for simulating a three-dimensional multilayer hydrodynamic and thermodynamic model in domains with irregular bottom topography. The model was designed for examining the interactions between flow and topography. The model was based on the three-dimensional Navier-Stokes equations and was solved using the fractional step method, which combines the finite difference method in the horizontal plane and the finite element method in the vertical plane. The numerical techniques were described and the model test and application were presented. For the model application to the northern part of Ariake Sea, the hydrodynamic and thermodynamic results were predicted. The numerically predicted amplitudes and phase angles were well consistent with the field observations.

Facile Evaluation of Thermodynamic Parameters for Reverse Thermochromism of Indolinobenzospiropyran-6-carboxylates in Aqueous Binary Solvents

  • Keum, Sam-Rok;Ma, So-Young;Lim, Hyun-Woo;Han, Tae-Hwi;Choi, Kyu-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제33권8호
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    • pp.2683-2688
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    • 2012
  • The position of the thermodynamic equilibrium for reverse thermochromic spiropyran 6-carboxylates (SP-COOHs) was easily determined in aqueous binary mixtures, such as water-methanol, water-acetonitrile and water-dimethyl sulfoxide. The existence of more than one type of interconvertible species of the ring-opened form of SP-COOH in aqueous binary solvents enables us to evaluate the molar extinction coefficients of the ring-opened species of SP-COOH and to obtain the thermodynamic parameters.

Sintering Phenomena and Thermodynamic Analysis in the SiC Whisker-Reinforced Mullite Matrix Ceramic Composites During RF Plasma Sintering

  • Park, Youngsoo;:Michael J. MeNallan
    • The Korean Journal of Ceramics
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    • 제2권4호
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    • pp.231-237
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    • 1996
  • Mullite ceramics can be sintered by rf plasma sintering to densities as high as 97% compared to the theoretical density of the mullite, while SiC whisker-reinforced mullite matrix ceramic composites were not sintered by plasma sintering. Decomposition of mullite occurs in a superficial regins at the outside surface of the specimen by volatilization of SiO at elevated temperature by plasma. SiC whiskers were destroyed, and the matrix was converted to alumina from SiC-whisker reinforced mullite matrix ceramic composites during the plasma sintering. Accelerated volatilization from the SiC whisker in the mullite prevents sintering. The volatile species are mainly SiC and CO gas species. The effects of plasma on mullite and SiC-whisker reinforced mullite matrix composites are interpreted by thermodynamic simulation of the volatile species in the plasma environment. The thermodynamic results show that the decomposition will not occur during hot pressing.

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열역학적 관점에 근거한 구름발생 실험의 문제점 분석 및 개선방안에 대한 고찰 (An Analysis of Problems Related to Cloud Making Experiments in School Science Textbooks and Development of an Experiment Based on the Thermodynamic Theories)

  • 박동조;백성혜;강성주
    • 한국과학교육학회지
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    • 제21권3호
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    • pp.547-557
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    • 2001
  • 이 연구에서는 5차 교육과정과 6차 교육과정의 중학교 과학 교과서에 제시된 구름발생 실험 내용을 실험 방법 및 실험 기구 등의 측면에서 비교 분석하였다. 그리고 열역학적 관점에서 문제점을 살펴보았으며 이러한 문제점을 개선하기 위한 실험을 개발하여 교과서 실험 결과와 비교함으로서 그 효과를 알아보았다.

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음용수의 염소살균부산물(DBPs)인 염화지방족화합물의 QSAR 독성예측치에 대한 열역학적 분자표현자의 역할(II) (Screening of QSAR Descriptors for Genotoxicily Prediction of Drinking Water Disinfection Byproducts (DBPs), Chlorinated Aliphatic Compounds-The Role of Thermodynamic factors)

  • 김재현;조진남
    • 한국환경성돌연변이발암원학회지
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    • 제21권2호
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    • pp.118-121
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    • 2001
  • The predictive screening of various molecular descriptors for predicting carcinogenic, mutagenic, teratogenic and alkylation activity of chlorinated disinfection byproducts (DBPs) has been investigated for the application of quantitative structure-activity relationships (QSAR). The toxicity index for 29 compounds were computed by the PASS program and active values were employed in this study. Studies show that different descriptors account for the model equation of each genotoxic endpoint and that thermodynamic descriptors significantly played a major role on prediction of endpoints of chlorinated aliphatic compounds.

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두 열적 단순계로 구성된 복합계의 열역학 (Thermodynamics of a composite system composed of two simple thermal systems)

  • 정평석;김수연
    • 대한기계학회논문집B
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    • 제21권2호
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    • pp.275-284
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    • 1997
  • Thermodynamic behavior of a composite system which is composed of two simple thermal subsystems with constant heat capacities is analyzed, and several thermodynamic phenomena are investigated. The changes of the states and the potential work of the composite system are shown as the interaction between the subsystems in the composite system. The potential work is defined as the possible maximum available work from the composite system, and it is a thermodynamic property of the composite system. The decrease of the potential work is the same as the available work output from the composite system in reversible processes. The dissipation of available work is directly connected to the generation of entropy. The concepts of exergy and internal energy can be explained as a special case of the potential work.

IDENTIFICATION OF THERMODYNAMIC PARAMETERS OF ARCTIC SEA ICE AND NUMERICAL SIMULATION

  • Xiw, Chao;Feng, Enmin;Li, Zhijun;Peng, Lu
    • Journal of applied mathematics & informatics
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    • 제26권3_4호
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    • pp.519-530
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    • 2008
  • This paper studies the multi-domain coupled system of one dimensional Arctic temperature field and establishes identification model about the thermodynamic parameters of sea ice (heat storage capacity, density and conductivity) by the so-called output least-square estimate according to the temperature data acquired by a monitor buoy installed in the Arctic ocean. By the optimal control theory, the existence and dependability of weak solution and the identifiability of identification model have been given. Moreover, necessary optimality condition is proposed. Furthermore, the optimal algorithm for the identification model is constructed. By using the optimal thermodynamic parameters of Arctic sea ice, the numerical simulation is implemented, and the numerical results of temperature distribution of Arctic sea ice are demonstrated.

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Theoretical Analysis of a Spark Ignition Engine by the Thermodynamic Engine Model

  • Han, Sung Bin
    • 에너지공학
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    • 제24권3호
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    • pp.55-60
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    • 2015
  • Recent engine development has focused mainly on the improvement of engine efficiency and output emissions. The improvements in efficiency are being made by friction reduction, combustion improvement and thermodynamic cycle modification. Computer simulation has been developed to predict the performance of a spark ignition engine. The effects of various cylinder pressure, heat release, flame temperature, unburned gas temperature, flame properties, laminar burning velocity, turbulence burning velocity, etc. were simulated. The simulation and analysis show several meaningful results. The objective of the present study is to develop a combustion model for a spark ignition engine running with isooctane as a fuel and predicting its behavior.

계면활성제의 임계 미셀농도에 대한 열역학적 접근 (Thermodynamic Approach on The Critical Micelle Concentration of Surfactant)

  • 김세봉;김영찬
    • 한국응용과학기술학회지
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    • 제28권4호
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    • pp.449-454
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    • 2011
  • This surfactant can be used as a cosmetics and chemical dispersants. The variation of critical micelle concentration(CMC) with temperature for N-eicosyl pyridinium bromide over the range $40^{\circ}C$ to $60^{\circ}C$ has been measured by drop methods. Thermodynamic quantities for micellization of N-eicosyl pyridinium bromide in water have been calculated by polynominal equation.

Canonical Ensemble 로 代表된 系의 에너지 分布則 및 熱力學的牀態量의 道出에關하여 (A New Method on the Derivation of the Thermodynamic Quantities for a System Represented by the Canonical Ensemble)

  • 김순경
    • 대한화학회지
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    • 제3권1호
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    • pp.3-8
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    • 1954
  • Fowler obtained thermodynamic quantities assuming the theory which could be derived by representing the system with microcanonical ensemble, in order to introduce the temperature T of the system proper, he considered the combined systems which are composed of the system proper and another arbitrary system that is in thermal contact with the former, and represented the combined system by a microcanonical ensemble, here, he used the steepest descent method in his calculation. This Fowler's treatment is not only unsatisfactory at the point of theoretical view but also he could not make the formulation of free energy of Helmholtz's so that this formular was forced to be assumed. From the point of Quantum Statistical Mechanical view, the materially closed system which is in an equilibrium state with the temperature T is best represented by canonical ensemble. At the actual derivation of the distribution law and thermodynamic quantities, however, in order to avoid the difficulty of calculation Tolman proceeded his calculation either representing the system proper by the grand-canonical ensemble or adding a certain limitation.

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