• Journal of Conservation Science
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• v.27 no.4
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• pp.421-430
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• 2011

Thermal conditions in practice at the traditional bronze workshop of the Korean Folk Village in Yongin were examined along with the microstructures of some high tin bronze objects made there. Laboratory experiments approximating the conditions of the workshop were also carried out and the results were compared. The operating temperature of the workshop furnace was measured to range from $750^{\circ}C$ to $850^{\circ}C$ while the surface temperature of an object, upon its removal from the furnace for additional thermo-mechanical treatments, was generally in the range of $600^{\circ}C$ to $685^{\circ}C$. This variation in working temperatures was reflected in varying microstructures developed upon quenching. The products of the Folk Village were found to consist of microstructures where the ${\alpha}$ grains of the Cu-Sn system were distributed in the background of different phases including the ${\beta}$-martensite phase, retained ${\gamma}$ phase, ${\alpha}+{\delta}$ eutectoid or their mixtures. This variability, which is also identified in objects made in ancient times as well as in our laboratory experiments, suggests that the actual thermal conditions given during the quenching treatments are much more complicated than is inferred from the temperature measurements. This paper will present detailed accounts of the thermo-mechanical treatments as observed in the high tin bronze workshop of the Korean Folk Village and discuss the evolution of varying microstructures in terms of the substantial variability involved in the implementation of the traditional forged high tin bronze technology of Korea.

• Tunnel and Underground Space
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• v.30 no.4
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• pp.271-305
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• 2020

An effect of coupled thermo-hydro-mechanical and chemical (THMC) behavior is an essential part of the performance and safety assessment of geological disposal systems for high-level radioactive waste and spent nuclear fuel. Furthermore, numerical models and modeling techniques are necessary to analyze and predict the coupled THMC behavior in the disposal systems. However, phenomena associated with the coupled THMC behavior are nonlinear, and the constitutive relationships between them are not well known. Therefore, it is challenging to develop numerical models and modeling techniques to analyze and predict the coupled THMC behavior in the geological disposal systems. It is also difficult to verify and validate the development of the models and techniques because it requires expensive laboratory tests and in-situ experiments that need to be performed for a long time. DECOVALEX was initiated in 1992 to efficiently develop numerical models and modeling techniques and validate the developed models and techniques against the lab and in-situ experiments. In Korea, Korea Atomic Energy Research Institute has participated in DECOVALEX-2011, DECOVALEX-2015, and DECOVALEX-2019 since 2008. In this study, all tasks in the three DECOVALEX projects were introduced to the researcher in the field of rock mechanics and geotechnical engineering in Korea.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.371-378
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• 2012

Hydrophilic silica nanoparticles (SNPs) were treated by using 3-glycidoxypropyltrimethoxy silane (GPTMS) and then they were blended with polyurethane-urea (PUU) emulsions to obtain SNPs/PUU nanocomposite films. Thermo-mechanical properties of the nanocomposite films were investigated by varying the grafted amount of GPTMS onto SNPs and the contents of SNPs in the PUU matrix. The thermo-mechanical properties of the nanocomposite films were also compared in terms of the dispersibility of SNPs in the PUU matrix and thermal curing of the GPTMS-grafted SNPs. The maximum amount of grafted GPTMS was $1.99{\times}10^{-6}\;mol/m^2$, and which covered ca. 53% of the total SNP surface area. $^{29}Si$ CP/MAS NMR analyses with the deconvolution of peaks revealed the details of polycondensation degree and patterns of GPTMS in the surface modification of SNPs. The surface modification did not significantly affect colloidal stability of the SNPs in aqueous medium; however, the hydrophobic modification of SNPs offered a favorable effect on the dispersibility of SNPs in the PUU matrix as well as better thermal stability. XRD patterns revealed that GPTMS-grafted SNPs broadened the reduced the characteristic peak of polyol in PUU matrix. The composite films became rigid and less flexible as the SNP content increased from 5 wt.% to 20 wt.%. Particularly, Young's modulus and tensile modulus significantly increased after the thermal curing reaction of the epoxy groups in the SNPs.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.21 no.1
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• pp.35-42
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• 2008

In the nuclear power plant, early detection of fatigue crack by non-destructive test (NDT) equipment due to the thermal cyclic load is very important in terms of strict safety regulation. To this end, many efforts are exerted to the fabrication of artificial cracked specimen for practicing engineers in the NDT company. The crack of this kind, however, cannot be made by conventional machining, but should be made under thermal cyclic load that is close to the in-situ condition, which takes tremendous time due to the repetition. In this study, thermal loading condition is investigated to minimize the time for fabricating the cracked specimen using simulation technique which predicts the crack initiation and propagation behavior. Simulation and experiment are conducted under an initial assumed condition for validation purpose. A number of simulations are conducted next under a variety of heating and cooling conditions, from which the best solution to achieve minimum time for crack with wanted size is found. In the simulation, general purpose software ANSYS is used for the stress analysis, MATLAB is used to compute crack initiation life, and ZENCRACK, which is special purpose software for crack growth prediction, is used to compute crack propagation life. As a result of the study, the time for the crack to reach the size of 1mm is predicted from the 418 hours at the initial condition to the 319 hours at the optimum condition, which is about 24% reduction.

• Polymer(Korea)
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• v.32 no.3
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• pp.256-262
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• 2008

Copolyimides containing pendant trifluoromethyl ($CF_3$) groups were synthesized from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and bis[4-(3-aminophenoxy)phenyl]sulfone (BAPS) with various concentrations of 2,2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane(BAPP) to poly(amic acid)(PAA), followed by thermal imidization. These copolyimides were readily soluble in N,N'-dimethylacetamide (DMAc) and could be solution-cast into a flexible and tough film. The thermomechanical properties, morphology and an optical transparency of the copolyimide films were determined using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), wide angle X-ray diffraction (XRD), scanning electron microscopy (SEM), universal tensile machine (UTM), and a UV-Vis spectrometer. The cast copolyimide films exhibited high optical transparency with a cut-off wavelength (${\lambda}_0$) of $275{\sim}319\;nm$ in UV-vis absorption and a low yellow index(YI) value of $3.65{\sim}10.37$. The thermo-mechanical properties of copolyimide films were enhanced linearly with increasing a BAPP content. In contrast, the optical transparency of the copolyimide films was found to get worse with increasing a BAPP content.

• Journal of the Microelectronics and Packaging Society
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• v.16 no.3
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• pp.31-37
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• 2009

Cu-Cu thermo-compression bonding process was successfully developed as functions of the $N_2+H_2$ forming gas annealing conditions before and after bonding step in order to find the low temperature bonding conditions of 3-D integrated technology where the quantitative interfacial adhesion energy was measured by 4-point bending test. While the pre-annealing with $N_2+H_2$ gas below $200^{\circ}C$ is not effective to improve the interfacial adhesion energy at bonding temperature of $300^{\circ}C$, the interfacial adhesion energy increased over 3 times due to post-annealing over $250^{\circ}C$ after bonding at $300^{\circ}C$, which is ascribed to the effective removal of native surface oxide after post-annealing treatment.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.11
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• pp.7667-7671
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• 2015

Recently, Zinc coating is often used with environment friendly features and high performance. Generally The coating temperature is one of main factors for determining coating thickness and coating ability, so the optimal coating temperature is strongly required. In this paper, the thermo-flow simulation considering the air flow inside the coating rooms for analyzing the temperature distributions of Zinc spray coating room was performed. Two spray coating rooms, preheating room and drying room were all modeled by SolidWorks program and the temperature distributions were analyzed by Flow simulation program. The analysis results were verified with the measured data by thermal image camera. The characteristics of temperature distributions of the first spray room and the second spray room were understood and the results showed that the temperatures of two spray coating room were low compared with the target temperature $25^{\circ}C$. To the exclusion of heater addition, the simulation with all the same conditions exclusive the exhaust fan was performed, which showed that the temperatures of the first and the second spray rooms increased by $6.2^{\circ}C$ and $5.8^{\circ}C$. This analysis can be applicable for designing a new spray coating room for improving performance.

• Tunnel and Underground Space
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• v.30 no.1
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• pp.39-62
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• 2020

In this study, Barcelona Basic Model (BBM) was implemented into TOUGH2-MP/FLAC3D for the numerical analysis of coupled thermo-hydro-mechanical (THM) behavior of unsaturated soils and the prediction of long-term behaviors. Similar to the methodology described in a previous study for the implementation of BBM into TOUGH-FLAC, the User Defined Model (UDM) of FLAC based on the Modified Cam Clay Model (MCCM) and the FISH function of FLAC3D were used to extend the existing MCCM module in FLAC3D for the implementation of BBM into TOUGH2-MP/FLAC3D. In the developed BBM module in TOUGH2-MP/FLAC3D, the plastic strains due to change in suction increase (SI) in addition to mean effective stress are calculated. In addition to loading-collapse (LC) yield surface, suction increase (SI) yield surface is changed by hardening rules in the developed BBM module. Several numerical simulations were conducted to verify and validate the implementation of BBM: using an example presented in the FLAC3D manual for the standard MCCM, simulation results using COMSOL, and experimental data presented in SKB Reports. In addition, the developed BBM analysis module was validated by simultaneously performing a series of modeling tests that were performed for the validation of the Quick tools developed for the purpose of effectively deriving BBM parameters, and by comparing the Quick tools and Code_Bright results reported in a previous study.

• Tunnel and Underground Space
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• v.31 no.6
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• pp.593-609
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• 2021

We proposed a numerical method for the thermo-mechanical behavior of rock fracture using a grain-based distinct element model (GBDEM) and simulated thermally induced fracture slip. The present study is the benchmark simulation performed as part of DECOVALEX-2023 Task G, which aims to develop a numerical method to estimate the coupled thermo-hydro-mechanical processes within the crystalline rock fracture network. We represented the rock sample as an assembly of Voronoi grains and calculated the interaction of the grains (blocks) and their interfaces (contacts) using a distinct element code, 3DEC. Based on an equivalent continuum approach, the micro-parameters of grains and contacts were determined to reproduce rock as an elastic material. Then, the behavior of the fracture embedded in the rock was characterized by the contacts with Coulomb shear strength and tensile strength. In the benchmark simulation, we quantitatively examined the effects of the boundary stress and thermal stress due to heat conduction on fracture behavior, focusing on the mechanism of thermally induced fracture slip. The simulation results showed that the developed numerical model reasonably reproduced the thermal expansion and thermal stress increment, the fracture stress and displacement and the effect of boundary condition. We expect the numerical model to be enhanced by continuing collaboration and interaction with other research teams of DECOVALEX-2023 Task G and validated in further study experiments.

• Polymer(Korea)
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• v.36 no.6
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• pp.761-767
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• 2012

The polycarbonate (PC)-based optical diffusers for direct-lit LED backlight unit were prepared by using extrusion compounding followed by compression molding process. The application of inorganic porous silica particles as a diffusing agent in addition to conventional poly(methyl methacrylate) (PMMA) beads was attempted, and the optical, thermal, and mechanical properties of the prepared diffusers were investigated. The morphological observations revealed that the diffusing agents could be uniformly dispersed in the PC matrix without agglomeration by high shear stress generated during extrusion process. The incorporation of the porous silica particles mixed with PMMA beads remarkably enhanced the luminance uniformity with respect to both location and view angle for the diffuser, while minimizing the reduction in the absolute luminance, as compared with the diffuser containing only PMMA beads. In addition, thermal and mechanical properties of the diffusers were shown to be improved upon addition of the porous silica particles.