• The Journal of the Convergence on Culture Technology
• /
• v.7 no.2
• /
• pp.443-451
• /
• 2021

This study compared and analyzed the thermal characteristics based on the ratio of moisture content of infected and non-infected Bursaphelenchus Xylophilus by heat of combustion experiment. The experiment results are as follows. The analysisresult of the ratio of water content shows that 19.92% on average for infected Bursaphelenchus Xylophilus and 26.27% for non-infected which decreases water content as the size of conduction, convection, and radiant heat increases in case of fire. As the vaporization of the moisture content accelerates, the average moisture content is reached, and the result is contrary to the thermal characteristics of the wood that the moisture content is not ignited by a heat source when the moisture content is under 15%. The combustion heat analysis result showed that infected and non-infected Bursaphelenchus Xylophilus had no significant difference in combustion heat at about 3%. However, it shows that combustion heat is higher than other species. In conclusion, decreasing in moisture content based on the increasing conduction, convection, and radiant heat is one of the direct causes of ignition, and the lower the moisture content, the faster the fire spreads.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.35 no.5
• /
• pp.299-308
• /
• 2022

This study was conducted to predict the tendency for heat exchange and boil-off gas (BOG) in a liquefied hydrogen tank under sloshing excitation. First, athe fluid domain excited by sloshing was modeled using a multiphase-thermal flow domain in which liquid hydrogen and hydrogen gas are in the saturated state. Both the the volume of fluid (VOF) and Eulerian-based multi-phase flow methods were applied to validate the accuracy of the pressure prediction. Second, it was indirectly shown that the fluid velocity prediction could be accurate by comparing the free surface and impact pressure from the computational fluid dynamics with those from the experimental results. Thereafter, the heat ingress from the external convective heat flux was reflected on the outer surfaces of the hydrogen tank. Eulerian-based multiphase-heat flow analysis was performed for a two-dimensional Type-C cylindrical hydrogen tank under rotational sloshing motion, and an inflation technique was applied to transform the fluid domain into a computational grid model. The heat exchange and heat flux in the hydrogen liquid-gas mixture were calculated throughout the analysis,, whereas the mass transfer and vaporization models were excluded to account for the pure heat exchange between the liquid and gas in the saturated state. In addition, forced convective heat transfer by sloshing on the inner wall of the tank was not reflected so that the heat exchange in the multiphase flow of liquid and gas could only be considered. Finally, the effect of sloshing on the amount of heat exchange between liquid and gas hydrogen was discussed. Considering the heat ingress into liquid hydrogen according to the presence/absence of a sloshing excitation, the amount of heat flux and BOG were discussed for each filling ratio.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.222-222
• /
• 2012

Metal oxide gas sensors based on semiconductor type have attracted a great deal of attention due to their low cost, flexible production and simple usability. However, most works have been focused on n-type oxides, while the characteristics of p-type oxide gas sensors have been barely studied. An investigation on p-type oxides is very important in that the use of them makes possible the novel sensors such as p-n diode and tandem devices. Monoclinic cupric oxide (CuO) is p-type semiconductor with narrow band gap (~1.2 eV). This is composed of abundant, nontoxic elements on earth, and thus low-cost, environment-friendly devices can be realized. However, gas sensing properties of neat CuO were rarely explored and the mechanism still remains unclear. In this work, the neat CuO layers with highly ordered mesoporous structures were prepared by a template-free, one-pot solution-based method using novel ink solutions, formulated with copper formate tetrahydrate, hexylamine and ethyl cellulose. The shear viscosity of the formulated solutions was 5.79 Pa s at a shear rate of 1 s-1. The solutions were coated on SiO2/Si substrates by spin-coating (ink) and calcined for 1 h at the temperature of $200{\sim}600^{\circ}C$ in air. The surface and cross-sectional morphologies of the formed CuO layers were observed by a focused ion beam scanning electron microscopy (FIB-SEM) and porosity was determined by image analysis using simple computer-programming. XRD analysis showed phase evolutions of the layers, depending on the calcination temperature, and thermal decompositions of the neat precursor and the formulated ink were investigated by TGA and DSC. As a result, the formation of the porous structures was attributed to the vaporization of ethyl cellulose contained in the solutions. Mesoporous CuO, formed with the ink solution, consisted of grains and pores with nano-meter size. All of them were strongly dependent on calcination temperature. Sensing properties toward H2 and C2H5OH gases were examined as a function of operating temperature. High and fast responses toward H2 and C2H5OH gases were discussed in terms of crystallinity, nonstoichiometry and morphological factors such as porosity, grain size and surface-to-volume ratio. To our knowledge, the responses toward H2 and C2H5OH gases of these CuO gas sensors are comparable to previously reported values.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.17 no.4
• /
• pp.268-273
• /
• 2014

Experiments on carbonization were conducted using fish offal generated from fish market for the purpose of resource recycling. Elemental composition of fish offal and effect of carbonation temperature on the overall yield were investigated. Carbon and hydrogen contents of fish offal were 51.1% and 7.6%, respectively in view of elemental composition. Particularly, nitrogen and sulfur contents were as high as 9.8% and 1.0%, respectively. These values suggests that odor problem of fish offal can be serious. Comparing elemental composition of fish offal with other waste materials, it is thought that carbon and hydrogen contents are considerably high. These implies that thermal disposal will be the best option for final disposal method of fish offal. As a results of carbonization experiments on Mackerel, Hairtail, Croaker and mixed sample of Mackerel, Hairtail and Croaker, carbonization patterns were quite similar irrespective of fish species. Carbonization yield was varied significantly depending on carbonization temperature at the carbonization time of 5 minutes and 10 minutes. When the carbonization time was maintained longer than 30 minutes, yield variation depending on time variation at each temperature was insignificant. Thus, it can be concluded that effect of carbonization time on overall yield was minor when the carbonization time was maintained longer than 30 minutes. Primary vaporization in carbonization conducted at the temperature of $400^{\circ}C$ was minor. Thus, difference of yield between temperature of $500^{\circ}C$ and $400^{\circ}C$ was appeared greatly. It can be concluded that yield difference depending on carbonization temperature can be neglected if the carbonizing temperature exceed $600^{\circ}C$ and carbonizing time exceed 10 minutes at the same time.

• Journal of the Korea Concrete Institute
• /
• v.21 no.4
• /
• pp.465-471
• /
• 2009

To prevent the explosive spalling of the high strength concrete and control the rise of temperature in the steel rebar during fire, a fiber cocktail method has been proposed simultaneously with the use of polypropylene and steel fiber. After applying the fiber cocktail (polypropylene and steel fibers) into the mixture of high strength concrete with a compressive strength of between 40 and 100 MPa and evaluating the thermal properties at elevated temperatures, the fire test was carried out on structural members in order to evaluate the fire resistance performance. Two column specimens were exposed to the fire without loading for 180 minutes based on the standard curve of ISO-834. No explosive spalling has been observed and the original color of specimen surface was changed to light pinkish grey. The inner temperature of concrete dropped rapidly starting from 60mm deep. After 60 minutes of exposure to the fire, the temperature gradient of fiber cocktail reinforced high strength concrete was measured as 2.2oC/mm, which is approximately 5 times less than that of normal concrete. The final temperatures of steel rebar after 180 minutes of fire test resulted in 488.0oC for corner rebar, 350.9oC for center rebar, and 419.5oC for total mean of steel rebar. The difference of mean temperature between corner and center rebar was 137.1oC The tendency of temperature rise in concrete and steel rebar changed between 100oC and 150oC The cause of decrease in temperature rise was due to the water vaporization in concrete, the lower temperature gradient of the concrete with steel and polypropylene fiber cocktails, the moisture movement toward steel rebars and the moisture clogging.

• Journal of the Korea Concrete Institute
• /
• v.24 no.2
• /
• pp.173-183
• /
• 2012

Recently, experimental studies to prevent explosive spalling based on spalling mechanism and addition of Polypropylene fiber in high strength concrete (HSC) are performed actively. However, with respect to ultra high strength concrete (UHSC), its compact internal structure is more difficult release vapor pressure at rapid rising temperature compared to HSC. Therefore, in this study, an experiment was conducted to evaluate spalling properties of UHSC using ${\Box}$ $100mm{\times}100{\times}H200mm$ rectangular specimen according to ISO-834 standard fire curve. With respect melting point of fiber, three fiber types of Polyethylene, Polypropylene, and Nylon fibers with melting temperature of $110^{\circ}C$, $165^{\circ}C$, and $225^{\circ}C$, respectively, were considered. Mixed fiber of 0.15% and 0.25% of concrete volume was used to consider spalling properties based on water vapor pressure release. Then, TGDTA test on fiber and FEM analysis were performed. The results showed that it is difficult to prevent initial spalling without loss of fiber mass even if fiber melting temperature is low. Also, in preventing thermal spalling, fiber that melts to rapidly create porosity within 10 minutes of fire is more effective than that of low melting temperature property of fiber.

• Tunnel and Underground Space
• /
• v.31 no.3
• /
• pp.167-183
• /
• 2021

It is essential to understand the complex thermo-hydro-mechanical-chemical (THMC) coupled behavior in the engineered barrier system and natural barrier system to secure the high-level radioactive waste repository's long-term safety. The heat from the high-level radioactive waste induces thermal pressurization and vaporization of groundwater in the repository system. Groundwater inflow affects the saturation variation in the engineered barrier system, and the saturation change influences the heat transfer and multi-phase flow characteristics in the buffer. Due to the complexity of the coupled behavior, a numerical simulation is a valuable tool to predict and evaluate the THMC interaction effect on the disposal system and safety assessment. To enhance the knowledge of THMC coupled interaction and validate modeling techniques in geological systems. DECOVALEX, an international cooperation project, was initiated in 1992, and KAERI has participated in the projects since 2008 in Korea. In this study, we introduced the main contents of all tasks in the DECOVALEX-2023, the current DECOVALEX phase, to the rock mechanics and geotechnical researchers in Korea.