• Title/Summary/Keyword: thermal treatment.

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Simultaneous Treatment of Tar and Particles Using Oil Scrubber and Bag Filter in Biomass Gasification (오일 스크러버 및 집진장치를 통한 바이오매스 가스화 공정 발생 타르 및 입자 제거 연구)

  • Kim, Joon Yub;Jo, Young Min;Kim, Sang Bum
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.712-718
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    • 2019
  • A combustible producer gas composed of H2, CO and CH4 could be obtained by the thermal-chemical conversion of biomass. However, a large amount of particulate matters including tar generated causes the mal-function of turbines and engines or the fouling of pipelines. In this study, a wet scrubber using the soybean oil and bag filter were installed, and the removal efficiency was investigated. Hydrate limestone and wood char base activated carbon were pre-coated on the filter medium to prevent clogging of open pores. The removal efficiencies by the bag filter were 86 and 80% for the hydrated limestone and activated carbon coating, respectively. Overall, the collection when using a series of oil scrubbers and bag filters were 88%, while 83% for the filter coating material.

Fabrication of PbZrO$_3$ thin films crystal by sol-gel processing (Sol-Gel법에 의한 PbZrO$_3$박막 결정의 제작)

  • 전기범;김원보;배세환
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.3
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    • pp.211-218
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    • 2000
  • $PbZrO_3$precursor was prepared for the spin coating on the Pt/Ti/$SiO_2$/Si substrate. Two different heat treatment methods were used and the differencies were studied. One of the method is that the films were inserted into the furnace for 30 minutes and the other is that the films were annealed by rapid thermal annealing (RTA) for 1 minute at the same temperatures. We also examined the tendency of crystallization by annealing at the fixed temperature, $700^{\circ}C$ as a function of time, namely during 1, 10, 20, and 30 minitues, respectively. The optimum conditions for the crystallization of these films were at $550^{\circ}C$ during 30 min. and at $700^{\circ}C$ during 10 min. in muffle furnace and at $650^{\circ}C$ during 1 min in RTA furnace. The best condition for making good quality grains needs 30 min. at $700^{\circ}C$.

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HTGR Nuclear Fuel Microsphere Preparation Using the Modified Sol-Gel Method (변형 Sol-Gel 방법을 이용한 고온가스로 핵연료 미세구입자 제조)

  • Jeong, Kyung-Chai;Kim, Yeon-Ku;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.574-582
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    • 2009
  • $UO_2$ microsphere particles, core material of HTGR(High Temperature Gas Reactor) nuclear fuel, were prepared using by the GSP(Gel Supported Precipitation) method which is a modified-method of the wet sol-gel process. The spherical shape of initial liquid ADU droplets from the vibration nozzle system was continuously kept till the conversion to the final $UO_2$ microsphere. But the size of a final $UO_2$ microsphere was shrunken to about 25% of an initial ADU droplet size. Also, we found that the composition of dried-ADU gel particles was constituted of the very complicated phases, coexisted the U=O, C-H, N-H, N-O, and O-H functional groups by FT-IR. The important factors for obtain the no-crack $UO_2$ microsphere during the thermal treatment processes must perfectly wash out the remained-$NH_4NO_3$ within the ADU gel particle in washing process and the selections of an appropriate heating rate at a suitable gas atmosphere, during the calcining of ADU gel particles, the reducing of $UO_3$ particles, and the sintering of $UO_2$ particles, respectively.

Electro-fatigue Characteristic of Shape Memory Alloy Applied to the Electrosurgical Knee Wand of Variation of Wand Head Angle in Electrosurgical Knee Surgeries (헤드각이 변화하는 Electrosurgical Knee Wand에 적용된 형상기억합금 스프링의 전기적 피로특성)

  • An, Jae-Uk;Kim, Cheol-Woong;Lee, Ho-Sang;Wang, Joon-Ho;Oh, Dong-Joon
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1547-1552
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    • 2008
  • The tip of these catheter with straight needles is not able to reach in the vicinity of the disc bulging, which are the cause of the low back pain and because the far indirect radio-frequency treatment results in the decompression, the nucleoplasty has the limit. Many incurable diseases has not been solved due to the unexistence of the advanced technique for the MIS human body catheter device. To increase the possibility of nucleoplasty, the needle tip should be located at the closest area of the lesion. For this reason, the best way to increase the success rate of the operation is that the needle tip should access 3-dimensionally to the operating field as soon as possible. To achieve this aim, our studies are restricted as follows: 1) the SMA catheter design to control the 3-dimensional direction, 2) the security of the immediate response by the positive control of the SMA element thermal distribution using Peltier thermoelectric elements, 3) the aquisition of the control data by monitoring the relationship between the temperature of SMA element and the displacement, and 4) the design of the controller to guarantee the accurate location.

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A Study on Ageing Characteristics and Alloy Elements of SiCp Reinforced Al Matrix Composites (SiCp입자강화 Al 복합재료에 대한 합금원소의 영향과 시효특성에 관한 연구)

  • Kim, Sug-Won;Lee, Ui-Jong;Woo, Kee-Do;Kim, Dong-Keun
    • Journal of Korea Foundry Society
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    • v.21 no.1
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    • pp.7-14
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    • 2001
  • The research on new DRA(discontinuous reinforced alloy) and CRA(continous reinforced alloy) composites has been carried out to improve the properties of ceramic fiber and particle reinforced metal matrix composites(MMCs). Effects of alloying elements and aging conditions on the microstructures and aging behavior of Al-Si-Cu-Mg-(Ni)-SiCp composite have been examined. The specimens used in this study were manufactured by duplex process. The first squeeze casting is the process to make precomposite and the second squeeze casting is the process to make final composite. The hardening behavior was accelerated with decreasing the size of SiCp particle in the composites. It is considered that the dislocation density increased with increasing SiCp size, due to the different thermal deformation between Al matrix and SiCp during quenching after the solution treatment. Peak aging time to obtain the maximum hardness in 3 ${\mu}m$ SiCp reinforced Al composite was reduced than that in large size(5, 10 ${\mu}m$) of SiCp because of difference in dislocation density. Aging hardening responce(${\Delta}H$ = $H_{Max}.-H_{S.T}$) of composites was greater than that of unreinforced Al alloy because of higher density of second phases in matrix.

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Synergistic Effect of Tocopherol, Citric Acid and Sodium Polyphosphate on the Thermal Oxidation of Blending Oil (혼합유(混合油)의 열산화(熱酸化)에 대(對)한 Tocopherol, 구연산 및 인산염(燐酸鹽)의 상승효과)

  • Chang, Hun-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.7 no.1
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    • pp.63-70
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    • 1990
  • Influence of mixing ratio of blending oil (rice bran oil : RBD palm olein = 1 : 1, 1 : 4 mixture: w/w) and natural tocopherol, citric acid, and sodium polyphosphate on enhancement of oxidation stability of blending oil under the condition of tap water infulx(1 ml/min/200g oil) were compared by AOM test after heating these system at l80$^{\circ}C$. In addition, the effects of tocopherol, and synergist on oxidition stability were also tested with potato chips fried with blending oil(1 : 4 mixture). The result obtained were as followes; 1. The test of RBD palm olein addition of 50% and 80% against rice bran oil on oxidation stability showed that the higher the palm olein contents in blending oil, the higher the oxidation stability. 2. The test of oxidation stability, adding l00ppm, 200ppm and 400ppm of natural tocopherol in two different types of blending oils, A(1 : 1 mixture) and B(1 : 4 mixture), disclosed that blending oil B was more positively effective, and this trend was superior at 200ppm level particularly, Furthermore, oxidation stability was enhanced remarkably upon addition of 100ppm of natural tocopherol, and 50ppm of citric acid together with 50ppm, 100ppm and 200ppm of sodium polyphosphate in general. Especially, 200ppm of sodium polyphosphate addition induced the most synergetic effect on oxidation stability showing as much as 3 times compare to control. 3. The results of oxidation stability obtained by peroxide value on potato chips fried with blending oil (1:4 mixture} added tocopherol, citric acid and sodium polyphosphate and preserved at $60^{\circ}C$ revealed that addition of tocopherol and 50ppm of citric acid together with 200ppm of sodium polyphosphate treatment was the most synergistic coinciding with AOM test results.

A Clinical Study on Adolescent Idiopathic Scoliosis using DITI (DITI를 활용한 청소년기 특발성 척추측만증에 대한 임상적 고찰)

  • Yang, Tae Jun;Jeong, Sang Jun;Kwak, Min Kyung;Jang, Yeo Jin;Hyun, Min Kyoung;Yoon, Tae Kyung;Kim, Ha Na;Wei, Tung Shuen
    • Journal of Acupuncture Research
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    • v.33 no.4
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    • pp.7-14
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    • 2016
  • Objectives : This study was performed to investigate the correlation between Cobb's angle and digital infrared thermographic imaging(DITI) on adolescent idiopathic scoliosis. Methods : A total of 56 patients with adolescent idiopathic scoliosis were classified into four groups according to their Cobb's angle. Four groups were made for each increment of $5^{\circ}$: group $5-10^{\circ}$, group $11-15^{\circ}$, group $16-20^{\circ}$, and group $21-25^{\circ}$. Next we checked thermal differences of 6 acupoints(GB21, BL13, BL15, BL20, BL23, BL26) on DITI and analyzed correlation by SPSS ver. 20.0.0 for windows. Results : 1. The average patient age was approximately 13 years old. 2. The majority of patients complained of pain on both sides. 3. Significant correlation was found between group $11-15^{\circ}$ and group $16-20^{\circ}$, group $16-20^{\circ}$ and group $21-25^{\circ}$ on Simsu(BL15) by Duncan test. Conclusion : Using DITI, Simsu(BL15) is expected to be a valid indicator for the diagnosis and treatment of adolescent idiopathic scoliosis.

Percutaneous Radiofrequency Thermocoagulation Under Fluoroscopic Image-Guidance for Idiopathic Trigeminal Neuralgia

  • Son, Byung-Chul;Kim, Hyung-Suk;Kim, Il-Sup;Yang, Seung-Ho;Lee, Sang-Won
    • Journal of Korean Neurosurgical Society
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    • v.50 no.5
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    • pp.446-452
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    • 2011
  • Objective : We retrospectively investigated the long-term results of percutaneous radiofrequency thermocoagulation (RFT) using fluoroscopic image-guidance for treatment of trigeminal neuralgia. Methods : A total of 38 patients diagnosed and treated with RFT as an idiopathic trigeminal neuralgia were investigated. To minimize the risks related to conventional technique based on cutaneous landmarks, and to eliminate the need to frequent reposition of cannula, we adopted a technique of image-guided fluoroscopic cannulation of the foramen ovale. To minimize sensory complication following thermal lesion, our target response was a generation of a lesion with mild to moderate hypalgesia rather than dense hypalgesia. Results : The immediate pain-relief was achieved in all patients underwent RFT. With mean duration of follow-up of 38.2 months (range,12-72), 11 (28.9%) experienced recurrence of pain. The mean timing of recurrence was 26.1 months (range,12-46). A 42.7% recurrence rate was estimated by Kaplan-Meier analysis for the 38 patients at 46 months; 20.2% within 2 years, 29.1% within 3 years. In the long-term, 27 patients (71%) and 6 patients (15.8%) showed Barrow Neurological Institute (BNI) score I and BNI score II responses. Three (7.9%) patients was assessed as BNI score III, 2 patients (5.3%) showed BNI score IV response. As a complication, troublesome dysesthesia occurred in 3 of 38 patients (7.9%), however, there was no permanent cranial nerve palsy or morbidity. Conclusion : These results indicates that RFT under fluoroscopic image-guided cannulation of foramen ovale is a safe, effective, and reliable means of treating trigeminal neuralgia.

Effects of OH Radical Density from Atmospheric Plasma to Induce Cell Death in Lung Cancer and Normal Cells

  • Park, Dae-Hun;Kim, Yong-Hui;Sim, Geon-Bo;Baek, Gu-Yeon;Eom, Hwan-Seop;Choe, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.254.1-254.1
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    • 2014
  • Atmospheric plasma's electron temperature is less than thermal plasma, so it is useful at bio experiment. We have investigated the optical emission spectroscopy (OES) lines by spectrometer during Atmospheric plasma bombardment onto the PBS surface by using an Ar gas flow. Also we have measured the OH radical density inside the solution induced by the Atmospheric plasma bombardment. OH radical species are appeared at 308 nm and 309 nm. Densities of OH radical species has been found to be significantly decreased versus depth of the solution from 2 mm to 6 mm. OH radical density inside the PBS is measured to be about $1.87{\times}1016cm-3$ downstream at 2 mm from the surface under optimized Ar gas flow of 200 sccm in Atmospheric plasma. Also we have investigated cell viability of lung cancer and normal cell after Atmospheric plasma treatment for fixed exposure time in 60 seconds, but different depths. We used SEM, we observed change of cell morphorogy, did experiment about FDA & PI Staining method. It is found that there is selectivity between the lung cancer and lung normal cell, in which cancer cell definitely has higher cell death ratio more than normal cell. We have investigated change of bond structure in FT-IR spectroscopy, the following peaks were observed: and intense O-H peak at 3422 cm-1 and at 2925 cm-1 corresponds to C-H stretch vibrations of methylene group.

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A Study of Reactively Sputtered Ti-Si-N Diffusion Barrier for Cu Metallization (혼합기체 sputtering 법으로 증착된 Cu 확산방지막으로의 Ti-Si-N 박막의 특성 연구)

  • Park, Sang-Gi;Lee, Jae-Gap
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.503-508
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    • 1999
  • We have investigated the physical and diffusion barrier property of Ti-Si-N film for Cu metallization. The ternary compound was deposited by using reactive rf magnetron sputtering of a TiSi$_2$target in an Ar/$N_2$gas mixture. Resistivities of the films were in range of 358$\mu$$\Omega$-cm, to 307941$\mu$$\Omega$-cm, and tended to increase with increasing the $N_2$/Ar flow rate ratio. The crystallization of the Ti-Si-N compound started to occur at 100$0^{\circ}C$ with the phases of TiN and Si$_3$N$_4$identified by using XRD(X-ray Diffractometer). The degree of the crystallization was influenced by the $N_2$/Ar flow ratio. The diffusion barrier property of Ti-Si-N film for Cu metallization was determined by AES, XRD and etch pit by secco etching, revealing the failure temperature of 90$0^{\circ}C$ in 43~45at% of nitrogen content. In addition, the very thin compound (10nm) with 43~45at% nitrogen content remained stable up to $700^{\circ}C$. Furthermore, thermal treatment in vacuum at $600^{\circ}C$ improved the barrier property of the Ti-Si-N film deposited at the $N_2$(Ar+$N_2$) ratio of 0.05. The addition of Ti interlayer between Ti-Si-N films caused the drastic decrease of the resistivity with slight degradation of diffusion barrier properties of the compound.

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