• 제목/요약/키워드: thermal stability enhancement

검색결과 87건 처리시간 0.031초

탄소나노튜브의 합성수율 증대와 저온 합성에 미치는 기판 전처리의 영향 (Effect of substrate pretreatment on the growth yield enhancement and growth temperature decrease of carbon nanotubes)

  • 신의철;조성일;정구환
    • 산업기술연구
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    • 제39권1호
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    • pp.7-14
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    • 2019
  • Carbon nanotubes (CNT) on metal substrates are definitely beneficial because they can maintain robust mechanical stability and high conductivity between CNT and metal interfaces. Here, we report direct growth of CNT on Ni-based superalloy, Inconel 600, using thermal chemical vapor deposition (CVD) with acetylene feedstock in the growth temperature range of $400-725^{\circ}C$. Furthermore, we studied the effect of substrate pretreatment on the growth yield enhancement and growth temperature decrease of CNT on Inconel 600. Activation energy (AE) for CNT growth was estimated from the CNT height change with respect to the growth temperature. The AE values significantly decreased from 205.03 to 24.35 kJ/mol by the pretreatment of thermal oxidation of Inconel substrate at $725^{\circ}C$ under ambient. Higher oxidation temperature tends to have lower activation energy. The results have shown the importance of pretreatment temperature on CNT growth yield and growth temperature decrease.

The Effect of Surface Modification with La-M-O (M = Ni, Li) on Electrochemical Performances of Li[Ni0.8Co0.15Al0.05]O2 Cathode

  • Ryu, Jea-Hyeok;Kim, Seuk-Buom;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.657-660
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    • 2009
  • The surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode particle was modified by lanthanum based oxide to improve electrochemical property and thermal stability. The XRD pattern of surface layer was indexed with that of $La_4NiLiO_8$. The discharge capacity of modified electrode was higher than that of pristine sample, specially at fast charge-discharge rate and high cut-off voltage. In the DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by surface modification. Such enhancement may by attributed to the presence of stable lanthanum based oxide, which effectively suppressd the reaction between electrode and electrolyte on the surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ electrode.

Fuzzy Applications in a Multi-Machine Power System Stabilizer

  • Sambariya, D.K.;Gupta, Rajeev
    • Journal of Electrical Engineering and Technology
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    • 제5권3호
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    • pp.503-510
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    • 2010
  • This paper proposes the use of fuzzy applications to a 4-machine and 10-bus system to check stability in open conditions. Fuzzy controllers and the excitation of a synchronous generator are added. Power system stabilizers (PSSs) are added to the excitation system to enhance damping during low frequency oscillations. A fuzzy logic power system stabilizer (PSS) for stability enhancement of a multi-machine power system is also presented. To attain stability enhancement, speed deviation ($\Delta\omega$) and acceleration ($\Delta\varpi$) of the Kota Thermal synchronous generator rotor are taken as inputs to the fuzzy logic controller. These variables have significant effects on the damping of generator shaft mechanical oscillations. The stabilizing signals are computed using fuzzy membership functions that are dependent on these variables. The performance of the fuzzy logic PSS is compared with the open power system, after which the simulations are tested under different operating conditions and changes in reference voltage. The simulation results are quite encouraging and satisfactory. Similarly, the system is tested for the different defuzzification methods, and based on the results, the centroid method elicits the best possible system response.

Effect of added mesophase pitch during the pitch synthesis reaction of PFO

  • Kim, Ji Hong;Kim, Jong Gu;Lee, Chul Wee;Lee, Ki Bong;Im, Ji Sun
    • Carbon letters
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    • 제23권
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    • pp.48-54
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    • 2017
  • This research considers the effect of added mesophase pitch (MP) as an additive during the pitch synthesis reaction of pyrolyzed fuel oil (PFO). Two effects are generated by adding MP. One is an enhancement of thermal stability due to the high thermal property of the additive; the other is that the volatile compounds that were removed by vaporization of PFO during the thermal reaction can participate in the pitch synthesis reaction ($PFO{\rightarrow}pitch$) more efficiently. The effect differs according to the amount of the additive. When the amount of the additive is less than 7 wt%, the first effect is dominant, whereas the second effect is dominant when the additive amount exceeds 10 wt%.

Assessment of Total Transfer Capability Using IPLAN: An Application of UPFC for Total Transfer Capability Enhancement

  • Lee Byung Ha;Kim Jung-Hoon;Kwak No-Hong;Lee Woon-Hee
    • KIEE International Transactions on Power Engineering
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    • 제5A권3호
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    • pp.244-251
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    • 2005
  • Power transfer capability has been recently highlighted as a key issue in many utilities. It is determined by the thermal stability, dynamic stability and voltage stability limits of generation and transmission systems. In particular, voltage stability affects power transfer capability to a great extent in many power systems. This paper presents a tool for determining total transfer capability from a static voltage stability viewpoint using IPLAN, which is a high level language used with the PSS/E program. The tool was developed so as to analyze static voltage stability and to determine the total transfer capability between different areas from a static voltage stability viewpoint by tracing stationary behaviors of power systems. A unified power flow controller (UPFC) is applied for enhancing total transfer capability between different areas from the viewpoint of static voltage stability. Evaluation of the total transfer capability of a practical KEPCO power system is performed from the point of view of static voltage stability, and the effect of enhancing the total transfer capability by UPFC is analyzed.

Polyethylene/Montmorillonite Nanocomposite의 난연성 평가 (Assessment on the Flame Retardancy for Polyethylene/Montmorillonite Nanocomposite)

  • 송영호;정국삼
    • 한국화재소방학회논문지
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    • 제20권4호
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    • pp.72-76
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    • 2006
  • 고분자/점토의 nanocomposite는 고분자에 소량의 점토를 첨가해도 물리적, 기계적, 열적 특성이 증가하기 때문에 최근 이에 관련된 연구가 증가되고 있다. 특히 montmorillonite(MMT)와 같은 smectite 계열의 점토는 높은 종횡비, 판형의 층상구조, 경제성 때문에 산업적으로 이용가치가 많다고 할 수 있다. 본 연구에서는 PE/MMT nanocomposite는 고분자를 용융시킨 후 점토를 삽입하여 시편을 제조하였다. 나노입자의 구조는 XRD 및 TEM을 이용하여 확인하였고, 난연성은 LOI, 탄화층 생성량, 연기중량농도의 측정을 통하여 검토하였다. 또한 PE/MMT nanocomposite의 열적 안정성은 DTG-DTA 분석을 통하여 검토하였다. 그 결과 종래의 화합물보다 그 특성이 보강되었다. 난연성은 연소시 탄화층 형성에 의하여 증가 되었음을 확인할 수 있었다.

Quaternary Ammonium-Based Room Temperature Ionic Liquids as Components of Carbonate Electrolytes for Li-ion Batteries: Electrochemical Performance and Thermal Properties

  • Chernyshov, Denis V.;Shin, Woo Cheol
    • Journal of Electrochemical Science and Technology
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    • 제5권4호
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    • pp.95-104
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    • 2014
  • Electrochemical performance of Li-ion cells with $LiMn_2O_4$ cathodes and graphite anodes with carbonates electrolytes containing quaternary ammonium-based room temperature ionic liquids (ILs) is investigated. Eight different ILs based on tetraalkylammonium, pyrrolidinium or piperidinium cations paired with bis(trifluoromethylsulfonyl)imide or tris(pentafluoroethyl)trifluorophosphate anions are examined in combination with dimethyl carbonate as a main solvent and fluoroethylene carbonate as a solid electrolyte interface forming agent. It is shown that cycling properties of the cells are strongly affected by the content of ILs in the electrolyte mixtures and its increase corresponds to lower discharge capacity retention. Since viscosity and conductivity of ILs are of a great importance for the electrolytes formulation, some kind of combined parameter should be used for the assessment of IL applicability and calculated values of Walden products for neat ILs represent one of the possible options. Besides, positive effect of ILs on reduction of flammability and enhancement of thermal stability of electrolytes in contact with charged electrodes have been demonstrated by means of self-extinguishing time test and differential scanning calorimetry respectively.

전력계통의 FACTS적용을 위한 직병렬 보상방안 연구 (The Study of Compensation Strategy for FACTS Application in Power System)

  • 이근준;장병훈;김영한
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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    • pp.112-116
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    • 1996
  • This paper presents the study results of FACTS application plan for transmission capability Enhancement. Power transfer across the KEPCO system resulting from a concentration of load in the Kyung-In area are subject to thermal, voltage and stability constrains. In the analysis study of the KEPCO system in 2000 and 2006 year. voltage stability analysis. modal analysis and dynamic stability were simulated by the power system analysis tools(VSTAB, PSS/E).

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Interface engineering for high-k dielectric integration on III-V MOSFETs

  • 이성주
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.154-155
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    • 2012
  • In this work, we report the comprehensive study of performance enhancement of InGaAs n-MOSFET by plasma $PH_3$ p assivation. The calibrated plasma $PH_3$ passivation of the InGaA ssurface before CVD high-k dielectric deposition significantly improves interface quality, resulting in suppressed frequency dispersion in C-V, increase in drive-current with high electron mobility, and excellent thermal stability.

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전력 수송능력 증대를 위한 FACTS의 전력계통 적용효과 연구 (The Study of FACTS Application Effects for Power Transmission Capability Enhancement in Power System)

  • 장병훈;이근준;김영한
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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    • pp.117-122
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    • 1996
  • This paper presents the study results of FACTS application effect for transmission capability Enhancement. In a study of the application of series and shunt compensation to the mid and long term KEPCO system in 2000 and 2006 year, it was concluded that the successful application of FACTS would ve capable of controlling power flow in KEPCO system with incr eased transfers without exceeding existing thermal and dynamic stability limits.

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