• The Transactions of the Korean Institute of Electrical Engineers C
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• v.48 no.7
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• pp.550-555
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• 1999

This paper deals with the effect of lightning impulse current on electrical characteristics of ZnO blocks used in distribution lightning arrester. The electrical characteristics of ZnO blocks are degraded by overtime impulse current, and the degraded ZnO block is brought to a thermal runaway and finally destroyed. It is therefore important to estimate the change of electrical characteristics of ZnO blocks. In this study, an impulse current generator which can produce 8/20$[\mus]$, 3[㎄] and 4/10$[\mus]$, 5[㎄] waveform is designed and fabricated to simulate the lightning impulse current of power systems. Total energy applied to the ZnO blocks at each time is 739[J] in 8/20$[\mus]$, and 523[J] in 4/10$[\mus]$, impulse current, respectively. From the experimental results, the 3rd harmonic of the leakage current increases continuously with the number of applied impulse current, but no significant changes in residual voltage and in reference voltage are observed until the ZnO block is destroyed. Also, it is confirmed that the main factor on degradation of ZnO blocks is rather the total energy applied to ZnO blocks than the peak value of the impulse current.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1631-1633
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• 2004

The surge current characteristics of ZnO-$Pr_6O_{11}$-CoO-$Cr_2O_3-Dy_2O_3$-based varistors were investigated with various $Dy_2O_3$ contents. The sintered density decreased in the range of $5.2{\sim}4.6g/cm^3$ with increasing $Dy_2O_3$ content. The incorporation of $Dy_2O_3$ markedly enhanced the nonlinear properties of varistors above 10 times in nonlinear exponent, compared with the varistor without $Dy_2O_3$. The varistor ceramics doped with 0.5 mol% $Dy_2O_3$ exhibited the highest electrical stability. However, the remainder varistors resulted in thermal runaway due to low density of varistor ceramics. The clamping voltage ratio exhibited a minimum value of 2.03 in 1.0 mol% $Dy_2O_3$ at surge current of 100 A(8/20 ${\mu}s$).

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.12
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• pp.1071-1076
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• 2003

The nonlinear properties and their stability of ZPCCD- based varistors, which are composed of ZnO P $r_{6}$ $O_{ll}$ - CoO-C $r_2$ $O_3$-D $y_2$ $O_3$-based ceramics, were investigated in the D $y_2$ $O_3$ content range of 0.0∼2.0 mol%. The incorporation of D $y_2$ $O_3$ greatly affected the nonlinear properties and the best nonlinearity was obtained from 0.5 mol% D $y_2$ $O_3$ with nonlinear exponent of 66.6 and leakage current of 1.2 $\mu$A. Further addition of D $y_2$ $O_3$ deteriorated the nonlinear properties. In stability against DC accelerated aging stress state: 0.95 $V_{1mA}$/15$0^{\circ}C$/24 h, the 0.5 mol％ D $y_2$ $O_3$-doped varistor exhibited the highest stability, in which the variation rate of varistor voltage and nonlinear exponent are -1.9% and 10.5%, respectively. The remainder varistors resulted in thermal runaway due to low density of ceramics.s.s.

• Journal of the Korean Society of Safety
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• v.25 no.2
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• pp.18-23
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• 2010

This paper describes a cause of fire accidents on power system fire DC electric traction vehicles. We investigated fire scene of power line for DC electric traction vehicles. From analysis results, the cause of fire on power line turned out line to ground fault between a feeder of electric power services(pantagraph) and DC electric traction vehicle roof. Fire accident of DC electric traction vehicles be assumed that electric sparks had been produced between the pantagraph and the power line conductor by repetitively making contact and separation, maybe if some material like branches get in between connecting rod it makes progress line to ground fault. ZnO arresters are widely used to protect DC electric traction vehicles against overvoltages caused by lightning or switching surges. However, the arresters are deteriorated by commercial overvoltages and/or lightning one. The deteriorated arresters could lead power failures, such as line to ground fault by a thermal runaway resulting from the increases in leakage current even in a nominal power system voltage. Finally, the power failures would be causative of the fire accident.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.383-386
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• 2004

DC accelerated aging characteristics of Zn-Pr-Co-Cr-La oxides-based varistors were investigated with various sintering temperatures. The varistors sintered at $1240^{\circ}C$ exhibited the highest nonlinearity, with a nonlinear exponent of 79.3 and a leakage current of $0.3\;{\mu}A$, whereas completely degraded because of thermal runaway owing to low sintered density. The varistors sintered at $1250^{\circ}C$ exhibited not only a high nonlinearity with the nonlinear exponent 61.4 and the leakage current 0.7 ${\mu}A$, but also a high stability with the variation rates of varistor voltage and nonlinear exponent are -1.01% and -10.67%, respectively, under DC stress condition such as $(0.85\;V_{1mA}/115^{\circ}C/24\;h)+(0.90\;V_{1mA}/120^{\circ}C/24\;h)+(0.95\;V_{1mA}/125^{\circ}C/24\;h)+(0.95\;V_{1mA}/150^{\circ}C/24\;h)$.

• Proceedings of the KSR Conference
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• 2008.11b
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• pp.241-247
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• 2008

This paper describes a cause of fire accidents on power system for DC electric traction vehicles. We investigated fire scene of power line for DC electric traction vehicles. From analysis results, the cause of fire on power line turned out line to ground fault between a feeder of electric power services(pantagraph) and DC electric traction vehicle roof. Fire accidents of DC electric traction vehicles be assumed that electric sparks had been produced between the pantagraph and the power line conductor by repetitively making contact and separation, maybe if some material like branches get in between connecting rod it make progress line to ground fault. ZnO arresters are widely used to protect DC electric traction vehicles against overvoltages caused by lightning or switching surges. However, the arresters are deteriorated by commercial frequency overvoltages and/or lightning one. Deteriorated arresters could lead power failures, such as line to ground fault by a thermal runaway resulting from the increases in leakage current even in a nominal power system voltage. The power failures, such as line to ground fault would be causative of the fire accidents.

• Journal of the Korean Society of Safety
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• v.37 no.2
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• pp.76-87
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• 2022

Lithium-ion batteries (LIBs) have attracted much interest for their high energy density (>150 mAh/g), high capacity, low self-discharge rate, and high coulombic efficiency. However, with the successful commercialization of LIBs, fire and explosion incidents are likely to increase. The thermal runaway is known as the major factor in battery-related accidents that can lead to a series of critical conditions. Considering this, recent studies have shown an increased interest in countering the safety issues associated with LIBs. Although safety standards for LIB use have recently been formulated, little attention has been paid to the safety around the manufacturing process for battery products. The present study introduces a risk assessment method suitable for assessing the safety of the LIB-manufacturing process. In the assessment method, a compensation parameter (Z-factor) is employed to correctly evaluate the process's safety on the basis of the type of material (e.g., metal anode, liquid electrolyte, solid-state electrolytes) utilized in a cell. The proposed method has been applied to an 18650 cell-manufacturing process, and three sub-processes have been identified as possibly vulnerable parts (risk index: >4). This study offers some crucial insights into the establishment of safety standards for battery-manufacturing processes.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.69-70
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• 2006

In lithium-ion batteries, separator membrane's, main role is to physically isolate a cathode and an anode while maintaining rapid transport of ionic charge carriers during the passage of electric current. As far as battery safety is concerned, the electrical isolation of electrodes is most crucial since unexpected short-circuits across the membrane induces hot spots where thermal runaway may break out. Internal short-circuits are generally believed to occur by protrusions on the electrode surface either by unavoidable deposits of metallic impurities or by dendritic lithium growth during battery operation. Another cause is shrinkage of the separator membrane when exposed to heat. If separator membrane can be engineered to prevent the internal short-circuit, it will not be difficult to improve lithium-ion batteries' safety. Commonly the separators employed in lithium-ion batteries are made of polyethylene (PE) and/or polypropylene (PP). These materials have terrible limitations in preventing the fore-mentioned internal short-circuit between electrodes due to their poor dimensional stability and mechanical strength. In this study we have developed a novel separator membrane that possesses very high thermal and mechanical stability. The cells employing this separator provided noticeable safety improvement in the various abuse tests.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.27 no.10
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• pp.623-629
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• 2014

For the semiconductor device safety from over current in the digital electronic circuit system must be surely designed that it's surface mount type micro fuse device. In this paper, We has analysed to the fusing character of micro fuse as a function changed thickness of thermosetting ink epoxy. To the change of thermosetting ink epoxy thickness with in production lot, in the electrically character (fusing test in the 2 multiple over current and 10 multiple over current, surface temperature test in the 1.25 multiple over current) of micro fuse has been tested. According to the electrically character result, changed thickness of thermosetting ink epoxy in designed micro fuse withheld direct effect in both end resistance changes. Also, because high thermal energy in the micro fuse test of over current was occurred to effect such as thermal runaway and explosion. Therefore, screen printing process in the design of micro fuse using thermosetting ink epoxy is very important for production quality improvement.

• Fire Science and Engineering
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• v.32 no.6
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• pp.91-99
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• 2018

Recently, the spread of ESS in Korea has increased and a fire accident has also occurred. By July 2018, there were a total of 7 cases. All 7 cases were ESS systems consisting of lithium-ion batteries and were burned down. Both the automatic fire extinguisher and the fire department were not able to digest. In this paper, the characteristics of ESS fire are analyzed based on recent ESS fire situation and field investigation, and the cause of fire is divided into environmental, electrical and thermal factors. As a result, it was found that the ESS fire was correlated with the installation environment of the system. In the domestic and overseas lithium ion battery test standard and ESS facility standard survey, the trends and differences of domestic and overseas facilities standards were identified. Based on the fire status and field investigationy, and domestic and overseas facility standard survey, measures were suggested to prevent and prevent the spread of fire in ESS fire.