• 제목/요약/키워드: thermal runaway

검색결과 82건 처리시간 0.023초

함수비에 따른 유동성 뒤채움재의 열저항 특성 (Thermal Resistant Characteristics of Accelerated Flowable Backfill Materials on Water Content)

  • 오기대;김대홍
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 추계 학술발표회
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    • pp.1258-1263
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    • 2010
  • Backfill material of buried electrical transmission cable should dissipate the heat as rapidly as it is generated, or high temperatures will lead thermal runaway. These problems could raise thermal resistance and recude trasmission efficiency. So Backfill material of buried electrical transmission cable should have not only structual safty but good thermal property. So, in this study, we performed thermal resistancy test for various materials such as sand, weathered soil, clay and mixed soil to analyze the thermal characteristics of CLSM(controlled low strength materials) for water content.

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벌크 중합법에 의한 폴리스티렌 중합공정의 열적위험성 (Thermal Hazards of Polystyrene Polymerization Process by Bulk Polymerization)

  • 한인수;이정석;이근원
    • 한국가스학회지
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    • 제17권4호
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    • pp.1-8
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    • 2013
  • 본 연구에서는 벌크 중합법을 이용한 폴리스티렌 중합공정의 폭주반응에 대한 열적 위험성을 가속속도열량계(ARC)와 소규모 반응열량계(MM)를 이용하여 평가하였다. 당해 중합공정은 반응온도 $120^{\circ}C{\sim}130^{\circ}C$로 운전되어져야 하며, $130^{\circ}C$ 이상의 반응온도에서는 반응 생성물의 급격한 점도 증가로 인하여 반응기의 온도제어 실패에 따른 폭주반응의 위험성이 존재하였다. 또한 당해 중합공정의 반응온도($120^{\circ}C{\sim}130^{\circ}C$)에서 공정운전 초기에 반응기의 냉각실패가 발생할 경우 폭주반응으로 인해 반응기의 온도와 압력이 각각 30 ~ 50분 이내에 약 $340^{\circ}C$, 5.3 bar 까지 급격히 상승하여 반응기의 파열판이 파열되거나 반응기가 폭발할 수 있는 열적 위험성이 높게 나타났다.

산화아연 피뢰기 소자의 열적 특성 향상을 위한 연구 (A study on the improvement of the thermal properties of ZnO arrester blocks)

  • 김동성;이수봉;이승주;김동규;양순만;이복희
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2009년도 추계학술대회 논문집
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    • pp.335-338
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    • 2009
  • In this study, in order to investigate the thermal and electrical properties of ZnO arrester block against 60[Hz] AC voltage, the changes in leakage current were measured. The temperature distribution appearing on the ZnO arrester blocks was observed using a forward looking infrared camera. In particular, the correlation between the thermal and electrical properties of a ZnO arrester block was analyzed experimentally. From this analysis, the thermal phenomena resulting from the heat generation and dissipation of the ZnO arrester block were interpreted. The degradation and thermal runaway phenomena of ZnO arrester block are closely related to the temperature limit of the ZnO arrester block. The installation of an additional metal electrode has resulted in the decrease of the leakage current due to the heat dissipation.

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비닐아세테이트 중합공정에서 원료물질의 열적 안정성 평가 (An Evaluation of Thermal Stability of Raw Materials in the Vinyl Acetate Polymerization Process)

  • 이근원;한인수;이정석
    • 한국안전학회지
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    • 제25권3호
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    • pp.61-65
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    • 2010
  • Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.

되메움재 특성을 고려한 전력구 열환경 변화 예측 수치해석모델 개발 (Development of numerical model for estimating thermal environment of underground power conduit considering characteristics of backfill materials)

  • 김경훈;박상우;김민주;이대수;최항석
    • 한국터널지하공간학회 논문집
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    • 제19권2호
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    • pp.121-141
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    • 2017
  • 최근 전력구 지중 송전선의 허용 전류용량에 대한 정부규제로 인해 전력구 공사에 현장 되메움재의 열적 거동에 대한 연구가 중요해졌다. 점차 증대되는 고용량 전력공급에 대한 수요와 더불어, 허용 전류용량을 산정하기 위해, 전력 케이블 주변 온도 증가를 유발하는 요인을 예측하고 분석하는 것이 시급하다. 전력구 내부의 과도한 열확산으로 인한 지중 송전선로 주변의 온도 증가는 지중 송전선 자체의 열저항을 증가시켜 절연 파괴 및 열 폭주 현상을 야기한다. 따라서 전력구 설계 및 시공시, 되메움재에 따른 전력구 현장 열거동 메커니즘을 규명하는 것이 매우 중요하다. 본 논문에서는 현장 시험시공을 기반으로, 전력구내부와 주변지반의 온도 변화 및 열저항을 산정하기 위한 수치해석 모델을 개발하였다. 전력구 열거동 파악을 위한 수치해석은 현장시험 시공시 획득한 4개의 다른 종류의 되메움재의 열적 그리고 물리적 물성치를 기반으로 수행되었다. 또한, 실내 시험을 통해 산정한 각 되메움재의 열저항을 수치해석 모델에 입력변수로 적용했다. 전력구 내부에 일정한 열량이 공급될 때, 되메움재의 단위중량, 함수비, 열적 특성 등 여러 변수를 고려한 열거동 메카니즘을 모사할 수 있도록 열거동 수치해석 모델을 구성하고 1년 동안의 수행된 현장계측값과 비교를 통하여 개발된 수치해석 모델을 검증하였다.

웨어러블용 Nylon-Yarn NOx 가스 센서의 검출 온도 변화에 따른 열 특성 시뮬레이션 (Thermal Characteristics Simulation with Detecting Temperature for the Wearable Nylon-Yarn NOx Gas Sensors)

  • 장경욱
    • 한국전기전자재료학회논문지
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    • 제33권4호
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    • pp.321-325
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    • 2020
  • Atmospheric environmental problems have a major impact on human health and lifestyle. In humans, inhalation of nitrogen oxides causes respiratory diseases, such as bronchitis. In this paper, thermal analysis of a gas sensor was carried out to design and fabricate a wearable nylon-yarn gas sensor for the detection of NOx gas. In the thermal analysis method, the thermal diffusion process was analyzed while operating the sensors at 40 and 60℃ to secure a temperature range that does not cause thermal runaway due to temperature in the operating environment. Thermal diffusion analysis was performed using the COMSOL software. The thermal analysis results could be useful for analyzing gas adsorption and desorption, as well as the design of gas sensors. The thermal energy diffusion rate increased slightly from 10.05 to 10.1 K/mm as the sensor temperature increased from 40 to 60℃. It was concluded that the sensor could be operated in this temperature range without thermal breakdown.

Surface modified ceramic fiber separators for thermal batteries

  • Cheong, Hae-Won;Ha, Sang-Hyeon;Choi, Yu-Song
    • Journal of Ceramic Processing Research
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    • 제13권spc2호
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    • pp.308-311
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    • 2012
  • A wide range of possible hazards existing in thermal batteries are mainly caused by thermal runaway, which results in overheating or explosion in extreme case. Battery separators ensure the separation between two electrodes and the retention of ion-conductive electrolytes. Thermal runaways in thermal batteries can be significantly reduced by the adoption of these separators. The high operating temperature and the violent reactivity in thermal batteries, however, have limited the introduction of conventional separators. As a substitute for separators, MgO powders have been mostly used as a binder to hold molten salt electrolyte. During recent decades the fabrication technology of ceramic fiber, which has excellent mechanical strength and chemical stability, has undergone significant improvement. In this study we adopted wet-laid nonwoven paper making method instead of the electrospinning method which is costly and troublesome to produce in volume. Polymeric precursor can readily be coated on the surface of wet-laid ceramic paper, and be formed into ceramic film after heat treatment. The mechanical strength and the thermo-chemical stability as well as the wetting behaviors of ceramic separators with various molten salts were investigated to be applicable to thermal batteries. Due to their excellent chemical, mechanical, and electrical properties, wet-laid nonwoven separators made from ceramic fibers have revealed positive possibility as new separators for thermal batteries which operate at high temperature with no conspicuous sign of a short circuit and corrosion.

송배전관로 되메움용 순환골재의 열저항 측정 및 기존 열저항 예측 모델과의 비교 (Thermal Resistivity Measurement of Recycled Aggregates and Comparison with Conventional Prediction Model)

  • 위지혜;홍성연;최항석
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.199.1-199.1
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    • 2010
  • Use of recycled aggregates that are constituents of concrete or asphalt-based structures has become popular because the recycling is an eco-friendly way to overcome the depletion of natural aggregates. In order to adopt the recycled aggregates for backfilling a power transmission pipeline trench, their thermal resistivity should be low enough to prevent thermal runaway in the transmission system. In this study, a series of laboratory tests with QTM-500 and KD2 Pro was performed to measure the thermal resistivity of recycled aggregates prepared from various sources. Relationships between the thermal resistivity of recycled aggregates and the water content have been obtained with consideration of compaction effort. Similar to natural soils, the thermal resistivity of the recycled aggregates decreases with increasing the water content. In addition, this study compared the experimental data with conventional prediction models for the thermal resistivity in the literature, which suggests the availability of the recycled aggregates as backfill material substituting for natural aggregates when backfilling the power transmission pipeline trench.

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열저항 특성을 고려한 지중송전관로 되메움재의 최적화(II) (Optimization of the Backfill Materials for Underground Power Cables considering Thermal Resistivity Characteristics (II))

  • 김유성;조대성;박영준
    • 한국지반신소재학회논문집
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    • 제10권4호
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    • pp.123-130
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    • 2011
  • 본연구의 선행연구에서는 주로 강모래를 포함한 각종 되메움재 후보군에 대하여 함수비, 건조단위중량, 입도분포 등의 차이에 따른 열저항 특성을 조사, 비교 분석하였다. 이 연구에서는 선행연구 결과를 토대로 하여 지중송전관로의 송전용량의 증대 및 열폭주(thermal runaway) 현상을 방지할 수 있는 새로운 되메움재의 개발에 주안점을 두었다. 연구를 위해 강모래, 재생모래, 쇄석, 석분과 같은 원재료에 플라이 애쉬(fly-ash), 슬래그(slag), 플록(floc)과 같은 입자가 작고 보습효과가 있는 재료를 혼합하여 혼합비와 함수상태에 따룬 열저항률의 변화를 측정, 분석하였다. 연구결과 단일재료만으로는 되메움재로의 사용이 어려울 것으로 판단되나, 쇄석의 입도분포 개선을 위해 평균입경이 작은 재생모래와 석분, 술래그 및 플록을 혼합한 결과, 최적함수비에서 $50^{\circ}C$-cm/Watt이하의 열저항률을 얻을 수 있고, 최적함수비 상태 후의 건조시에도 열저항률의 증가가 일어나지 않고 있어, 어느 정도 되메움재로서의 최적화에 근접한 것으로 판단된다.

삭카린 중간체의 열분해 특성에 관한 연구 (A Study on the Thermal Decomposition Characteristics of Intermediate of Saccharin)

  • 김관응;김영수;신창섭
    • 한국안전학회지
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    • 제13권4호
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    • pp.180-185
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    • 1998
  • The evaluation of thermal and pressure hazard of chemicals on the manufacturing, transporting and storaging is important in the chemical industry for safety. In this study, the thermal decomposition characteristics of intermediate of Saccharin were investigated by using Accelerating Rate Calorimeter(ARC) and Differential Scanning Calorimeter(DSC). Experimental results showed that decomposition temperatures in p-TSA were about 280~$318^{\circ}C$ by DSC and $201^{\circ}C$ by ARC. In case of o-TSA were about $336^{\circ}C$~$360.8^{\circ}C$ by DSC and $299^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about $70^{\circ}C$ lower than that by DSC. The exothermic runaway reaction in case of p-TSA occured in 598 minute and o-TSA in 5 minute. For the safety in the chemical industry, we should consider the ARC data as well as DSC data in the handling and design of process.

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