• Title/Summary/Keyword: thermal pretreatment

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Impact of CO2 Laser Pretreatment on the Thermal Endurance of Bragg Gratings

  • Gunawardena, Dinusha Serandi;Lai, Man-Hong;Lim, Kok-Sing;Ahmad, Harith
    • Journal of the Optical Society of Korea
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    • v.20 no.5
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    • pp.575-578
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    • 2016
  • The thermal endurance of fiber Bragg gratings (FBGs), written with the aid of 193-nm ArF excimer laser irradiation on H2-loaded Ge/B codoped silica fiber, and pretreated with a CO2 laser and a subsequent slow cooling process, is investigated. These treated gratings show relatively less degradation of grating strength during the thermal annealing procedure. The thermal decay characteristics of treated and untreated fiber, recorded over a time period of 9 hours, have been compared. The effect on the Bragg transmission depth (BTD) and the center-wavelength shift, as well as the growth of refractive-index change during the grating inscription process for both treated and untreated fiber, are analyzed.

Integrated Digestion of Thermal Solubilized Sewage Sludge to Improve Anaerobic Digestion Efficiency of Organic Waste (유기성 폐기물의 혐기성 소화효율 향상을 위한 열가용화 하수슬러지의 통합소화)

  • Oh, Kyung Su;Hwang, Jung Ki;Song, Young Ju;Kim, Min Ji;Park, Jun Gyu;Pak, Dae Won
    • Journal of Korean Society on Water Environment
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    • v.38 no.2
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    • pp.95-102
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    • 2022
  • Studies for improving the efficiency of the traditional anaerobic digestion process are being actively conducted. To improve anaerobic digestion efficiency, this study tried to derive the optimal pretreatment conditions and mixing conditions by integrating the heat solubilization pretreatment of sewage sludge, livestock manure, and food waste. The soluble chemical oxygen demand (SCOD) increase rate of sewage sludge before and after heat solubilization pretreatment showed an increased rate of 224.7% compared to the control group at 170℃ and 25 min and showed the most stable increase rate. As a result of the biomethane potential test of sewage sludge before and after heat solubilization pretreatment, the total chemical oxygen demand (TCOD) and SCOD removal rates increased as the heat solubilization temperature increased, but did not increase further at temperatures above 170℃. In the case of methane generation, there was no significant change in the cumulative methane generation from 0.134 to 0.203 Sm3-CH4/kg-COD at 170℃ for 15 min. As a result of the integrated digestion of organic waste, the experimental condition in which 25% of the sewage sludge, 50% of the food waste, and 25% of the livestock manure were mixed showed the highest methane production of 0.3015 m3-CH4/kg-COD, confirming that it was the optimal mixing ratio condition. In addition, under experimental conditions mixed with all three substrates, M4 conditions mixed with 25% sewage sludge, 50% food waste, and 25% livestock manure showed the highest methane generation at 0.2692 Sm3-CH4/kg-COD.

The Involvement of Protein kinase C in Glutamate-Mediated Nociceptive Response at the Spinal Cord of Rats (흰쥐의 척수에서 Glutamate가 매개하는 Nociceptive Response에 있어서 Protein kinase C의 관련성)

  • 김성정;박전희;이영욱;양성준;이종은;이병천;손의동;허인회
    • YAKHAK HOEJI
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    • v.43 no.2
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    • pp.263-273
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    • 1999
  • When glutamate was infected intrathecally, the result is similar to those produced by TPA injected. The involvement of protein kinase C (PKC) in the nociceptive responses in rat dorsal horn neurons of lumbar spinal cord was studied. In test with formalin, a PKC inhibitor (chelerythrine) inhibited dose-dependently the formalin-induced behavior response. Neomycin also inhibited it significantly. But, a PKC activator (12-O-tetradecanoylphorbol-13-ester, TPA) showed reverse effect. When gluatamate was injected intrathecally, we observed the result is smilar to those produced by TPA injection. On the other hand, intrathecal injection of glutamate induced thermal and mechanical hyperalgesia. In Tail-flick test, we examined the involvement of PKC on the glutamate-indeced thermal hyperalgesia. Chelerythrine showed an inhibitory effect and TPA enhanced thermal response. Glutamate decreased the mechanical threshold significantly. A pretreatment of chelerythrine and neomycin inhibited glutamate-induced mechanical hyperalgesia, but the effect of neomycin was not significant. TPA had little effect on the mechanical nociceptive response. These results suggest that the PKC activation through metabotropic receptor at postsynaptic region of spinal cord dorsal horn neurons may influence on the persistent nociception produced by chemical stimulation with formalin, thermal and mechanical hyperalgesia induced by glutamate.

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Preparation of High-purity Porous Alumina Carrier for Gas Sensor (가스센서용 고순도 다공질 알루미나 담체의 제조)

  • 이창우;현성호;함영민
    • Fire Science and Engineering
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    • v.11 no.3
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    • pp.15-23
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    • 1997
  • In this study, the alumina for gas sensor was prepared by anodic oxidation. It was stable thermally and chemically, and pore diameter and pore distribution was uniform. And the shape of pore was cylinderical. The aluminum plate was carried out by the thermal oxidation, chemical polishing and electropolishing pretreatment. The pore diameter, pore size distribution, pore density and thickness of alumina was observed with the change of reaction temperature, electrolyte concentration and current density. As a results, It was able to use for carrier because alumina which was prepared by anodic oxidationhas uniform pore size distribution.

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Growth of Highly Purified Carbon Nanotubes by Thermal Chemical Vapor Deposition (열화학기상증착법에 의한 고순도 탄소나노튜브의 성장)

  • Yu, Jae-Geun;Park, Jeong-Hun;Kim, Dae-Un;Lee, Cheol-Jin;Son, Gwon-Hui;Sin, Dong-Hyeok;Mun, In-Gi
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.12
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    • pp.649-653
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    • 2000
  • We have grown carbon nanotubes by thermal chemical vapor deposition of $C_{2}H_{2}$ on catalytic metal deposited on silicon oxide substrates. Highly purified carbon nanotubes are uniformly grown on a large area of the silicon oxide substrates. It is observed that surface modification of catalytic metals deposited on substrates by either etching with dipping in a HF solution and/or $NH_{3}$ pretreatment is a crucial step for the nanotube growth prior to the reaction of $C_{2}H_{2}$ gas. The diameters of carbon naotubes could be controlled by applying the different catalytic metals.

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Growth of Bi2O3 doped ZnO nanostructures fabricated by thermal evaporation method

  • Kim, Gyeong-Beom;Kim, Seon-Hong;Jeong, Yeong-Hun;Lee, Yeong-Jin;Baek, Jong-Hu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.243-243
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    • 2009
  • Bi2O3 doped ZnO nanostructures structure were successfully synthesized by a thermal evaporatiion process and their structural characteristics were investigated. It is demonstrated that the growth condition such as the areal density, pretreatment of the substrates and growth temperature have great influence on the morphology and the alignment of the nanorods arrays. The density of Bi2O3 doped ZnO nanostructures is controlled by the gold (Au) nanoparticle density deposited on the silicon substrates. Relatively homogenous size and shape were observed by introducing gold(Au) seed-layer as nucleation centers on the substrates prior to the VLS reaction. The samples were characterized by X-ray diffraction, scanning electron microscopy.

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Disintegration of Flotation Scum in Food Wastewater Using Thermo-Alkaline Pretreatment (열-알칼리 전처리를 통한 음식물류 폐수 부상 스컴의 가용화)

  • Choi, Jae-Min;Lee, Chae-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.1
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    • pp.71-78
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    • 2015
  • This study was performed to optimize the integrated thermal-alkali pre-treatment of flotation scum for the enhanced biodegradability. The optimum conditions of the integrated thermal-alkali pre-treatment were obtained using response surface methodology. The disintegration degree of carbohydrate (69.2%) and protein (57.3) were estimated under the optimum conditions. Although the optimum conditions were different, the disintegration degrees were similarly. A fermentative hydrogen batch test was conducted to evaluate the hydrogen production from scum with and/or without. The maximum hydrogen production from scum with pre-treatment was of 0.64 mol H2/mol hexoseadded, which about 1.4 times higher than without pre-treatment.

Growth of carbon nanotubes on a large area of Si substrate by the thermal chemical vapor deposition (열화학기상증착법에 의한 대면적 실리콘 기판위에서의 탄소나노튜브 성장)

  • 김대운;이철진;이태재;박정훈;손권희;강현근;송홍기;최영철;박영수
    • Proceedings of the IEEK Conference
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    • 1999.06a
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    • pp.954-957
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    • 1999
  • We have synthesized carbon nanotubes by thermal chemical vapor deposition of $C_2$H$_2$ on transition metal-coated silicon substrates. Carbon nanotubes are uniformly synthesized on a large area of the plain Si substrates, different from previously reported porous Si substrates. It is observed that surface modification of transition metals deposited on substrates by either etching with dipping in a HF solution and/or NH$_3$ pretreatment is a crucial step for the nanotube growth prior to the reaction of $C_2$H$_2$gas. We will demonstrate that the diameters of carbon naotubes can be controlled by applying the different transition metals.

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The Effect of Mechanochemical Treatment of Supported Catalyst on the Growth of Carbon Nanotubes

  • Yu, Hyung-Kyun;Kim, Jung-Sik;Lee, Byung-Il;Saito, Fumio;Ryu, Ho-Jin
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.617-619
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    • 2004
  • As an pretreatment, a Fe$(NO_3)_3{\cdot}9H_2O-Al(OH)_3$mixture was ground by a high energy mill and used as a supported catalyst for the growth of carbon nanotubes by a thermal CVD. The crystal structure of the catalyst disordered by the grinding influenced significantly the synthesis of carbon nanotubes in a thermal CVD.

Controlled growth of Carbon Nanotubes using thermal CVD

  • Lee, Tae-Jae;Lyu, Seung-Chul;Choi, Sang-Kyu;Lee, Cheol-Jin;Lee, Jin-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.674-677
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    • 2002
  • Vertically aligned CNTs were grown on Fe-deposited $SiO_2$ substrates using thermal CVD of acetylene gas. The size of Fe particle is controlled by the flow rate of $NH_3$ and pretreatment time, which leads to control the diameter of CNTs. As the diameter of CNTs decreases, the growth rate is enhanced with an inverse dependence of the CNT diameter. The growth rate of CNTs increases linearly as the growth time increases until 30 min but is rapidly decreased over 40 min. We found an inverse relation between the diameter and growth rate of carbon nanotubes. As the diameter of CNTs increases, the compartment layers of bamboo-shaped CNTs appear more frequently. A base-growth model is suitable to explain the dependence of growth rate and structure of CNTs on the diameter size of catalytic particles.

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