• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.126.2-126.2
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• 2010

The "grafting from" technology to prepare the well-defined microphase-separated structure of polymer using atom transfer radical polymerization (ATRP) will be introduced in this presentation. Various amphiphilic comb copolymers were synthesized through this approach using poly (vinylidene fluoride) (PVDF), poly (vinylidene fluoride-co-chlorotrifluoroethylene) (P(VDF-co-CTFE) and poly(vinyl chloride) (PVC) as a macroinitiator. Hydrophilic side chains such as poly (styrene sulfonic acid) (PSSA) or poly (sulfopropyl methacrylate) (PSPMA) were grafted from the mains chains using direct initiation of the chlorine atoms. The structure of mass transport channels has been controlled and fixed by crosslinking the hydrophobic domains, which also provides the greater mechanical properties of membranes. Successful synthesis and microphase-separated structure of the polymer were confirmed by $^1H$ NMR, FT-IR spectroscopy and TEM. The grafted/crosslinked membranes exhibited good mechanical properties (400 MPa of Young's modulus) and high thermal stability (up to $300^{\circ}C$), as determined by a universal testing machine (UTM) and TGA, respectively.

• Journal of Welding and Joining
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• v.32 no.6
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• pp.41-46
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• 2014

In this study, cracking susceptibility of laser cladding was investigated according to the processing parameters such as laser power, scan speed and feeding rate with blended powders of stellite#6 and technolase40s (WC+NiCr). The solidification microstructure of clad was composed of Co-based dendrite structures with ${\gamma}+Cr7C3$ eutectic phases at the dendritic boundaries. The crack propagation showed transgranular fracture along dendritic boundaries due to brittle chrome carbide at the eutectic phases. From results of fractography experiments, the fracture surface was typical cleavage brittle fracture in the clad and substrate. The number of clad cracks, caused by a tensile stress after the solidification, increased with increase of laser power, scan speed and feeding rate. Increase of the laser power caused large pores by facilitating WC decarburizing reaction. And the pores affected increase of crack susceptibility. High scan speed caused increment of clad cracks due to thermal stress and WC particle fractures. Also, increase of the feeding rate accompanied an amount of WC particles causing crack initiation and decarburizing reaction.

• 한국방재학회:학술대회논문집
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• 2007.02a
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• pp.340-343
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• 2007

The temperature variation of concrete pavement at early-age significantly affects the initiation and movement of joint cracks. For this analysis, we have built on IIA(Incheon International Airport) concrete pavement construction zone, and we measured the temperature and movement of the concrete slabs by using thermocouples, moisture sensors, V/W strain gages, and Demac discs. The analysis results showed that pavement's temperature significantly affected the joint movement. The widths of the joint cracks increased at evening and early in the morning when the temperature dropped but, those decreased in the day time when the temperature rose because of the effect of thermal expansion of the concrete slabs. The movements of the joints where the cracks never developed showed opposite trend to the cracked joints.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.11
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• pp.2219-2227
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• 2002

In a nuclear power plant, reactor pressure vessel (RPV) is the primary pressure boundary component that must be protected against failure. The neutron irradiation on RPV in the beltline region, however, tends to cause localized damage accumulation, leading to crack initiation and propagation which raises RPV integrity issues. The objective of this paper is to estimate the integrity of RPV under hot leg leaking accident by applying the finite element analysis. In this paper, a parametric study was performed for various crack configurations based on 3-dimensional finite element models. The crack configuration, the crack orientation, the crack aspect ratio and the clad thickness were considered in the parametric study. The effect of these parameters on the maximum allowable nil-ductility transition reference temperature ($(RT_{NDT})$) was investigated on the basis of finite element analyses.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.1
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• pp.133-142
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• 2001

Investigation on ignition and flame propagation of pyrolyzing fuel in a cylindrical enclosure is accomplished. The pyrolyzing fuel of cylindrical shape is located in an outer cylinder sustained at high-temperature. Due to gravity, the buoyancy motion is inevitably incurred in the enclosure and this affects the flame initiation and propagation behavior. The radiative heat transfer plays an important role since a high temperature difference is involved in the problem. Therefore in all cases presented here, the intrinsic radiation effects are considered. Numerical studies have been performed over various governing parameters, such as Grashof number, overheat ratio, and vertical fuel eccentricity. Depending on the Grashof number, the flame behavior is found to be totally different: a separated visible flame appears as the Grashof number reaches 10(sup)7. The location of flame onset is also affected by the vertical eccentricity of inner pyrolyzing fuel as well as thermal conditions applied.

• Proceedings of the KSME Conference
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• 2001.11a
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• pp.186-191
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• 2001

Tensile residual stress happen by difference of coefficients of thermal expansion between fiber and matrix is one of the serious problems in metal matrix composite(MMC). In this study, TiNi alloy fiber was used to solve the problem of the tensile residual stress as the reinforced material. TiNi alloy fiber improves the tensile strength of composite by occurring compressive residual stress in matrix using shape memory effect of it. Pre-strain was added to generate compressive residual stress inside TiNi/A16061 shape memory alloy(SMA) composite. It was also evaluated the effect of compressive residual stress corresponding to pre-strains variation and volume fraction of TiNi alloy. AE technique was used to clarify the microscopic damage behavior at high temperature and the effect of pre-strain difference of TiNi/A16061 SMA composite. In addition, two dimensional AE source location technique was applied to inspect the crack initiation and propagation in composite.

• Transactions of Materials Processing
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• v.23 no.4
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• pp.238-243
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• 2014

Recently, magnesium alloys have been widely used in the automotive, aerospace and electronics industries with the advantages of high specific strength, excellent machinability, high electrical conductivity, and high thermal conductivity. Deep drawn magnesium alloys not only meet the demands environmentally and the need for lighter products, but also can lead to remarkably improved productivity and more rapid qualification of the product The current study reports on a failure prediction procedure using finite element modeling (FEM) and a ductile fracture criterion and applies this procedure to the design of a deep drawing process. Critical damage values were determined from a series of uniaxial tensile tests and FEM simulations. They were then expressed as a function of strain rate and temperature. Based on the plastic deformation histories obtained from the FEM analyses of the warm drawing process and the critical damage value curves, the initiation time and location of fracture were predicted. The proposed method was applied to the process design for fabrication of a Mg automotive compressor case and verified with experimental results. The final results indicate that a Mg case part 39% lighter than an Al die casting part can be produced without any defects.

• Journal of the Korea Institute of Military Science and Technology
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• v.7 no.3 s.18
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• pp.129-139
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• 2004

DXD-19 is a flexible sheet explosive, which is a new polymer-bonded explosives(PBX's). DXD-19 is relatively insensitive and can be extruded into various configurations to be applied to munitions. A typical application includes multi-point initiation for the warhead, cutting/severance devices and transfer lines. The DXD-19 composition employs a binder system derived from the thermoplastic elastomer(HyTemp 4454) containing $5\%$ OH terminated with isocyanate curable for increasing mechanical properties. The use of an elastomer CAB increases its mechanical properties and the use of an energetic plasticizer BDNPF/BDNPA(F/A) improves the process ability as well as energy contents. The composition of the extruded DXD-19 formulation is formed $\%$ weight of $PETN/HyTemp/ATEC/(F/A)/CAB=72\~73/12\~13/6\~7/6\~7/1\~2$. Our safety tests of DXD-19 shows Insensitivity to an impact test and friction test, good thermal stability and excellent mechanical properties.

• Journal of the Korean Ceramic Society
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• v.46 no.2
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• pp.211-218
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• 2009

For the Y5V characteristic MLCC which is very prone to crack, it is important to to find out the basic cause of the crack. After finding out the crack origin, the materials and processes should be developed to remove the crack. The microstructures of the cracks were investigated using the fractographic method for the various types of cracks such as an exterior crack, a cyclic thermal shock crack, and an piezo-electric crack. It was found out that the crack origin was the pore at the end of the Ni inner electrode after bake-out. Even though the three dimensional crack shapes were different, the crack origins were seemed to be similar. The exterior crack could grow from the origin with the aids of residual and applied stress. FEM (finite element method) analysis was used to calculate the stress distribution of residual and applied stress. And the concept of fracture mechanics was applied for the explanation of the crack initiation and propagation from the stresses concentration.

• Nuclear Engineering and Technology
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• v.33 no.1
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• pp.12-24
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• 2001

The post-LOCA long term cooling (LTC) performance of the Korean Standard Nuclear Power Plant (KSNPP) is analyzed for both small break loss-of-coolant accidents (LOCA) and large break LOCA at cold leg. The RELAP5/MOD3.2.2 beta code is used to calculate the LTC sequences based on the LTC plan of the Korean Standard Nuclear Power Plants (KSNPP). A standard input model is developed such that LOCA and the followed LTC sequence can be calculated in a single run for both small break LOCA and large break LOCA. A spectrum of small break LOCA ranging from \ulcorner.02 to 0.5 k2 of break area and a double-ended guillotine break are analyzed. Through the code calculations, the thermal-hydraulic behavior and the boron behavior are evaluated and the effect of the important action including the safety injection tank (SIT isolation and the simultaneous injection in LTC procedure is investigated. As a result, it is found that the sufficient margin is available in avoiding the boron precipitation in the core. It is also found that a further specific condition for the SIT isolation action need to be setup and it is recommended that the early initiation of the simultaneous injection be taken for larger break LTC sequences.