• Journal of the Microelectronics and Packaging Society
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• v.22 no.4
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• pp.111-115
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• 2015

To improve the efficiency of the Si solar cell, high minority carrier life time is required. Therefore, the passivation technology is important to eliminate point defects on the silicon surface, causing the loss of minority carrier recombination. PECVD or post-annealing of thermally-grown $SiO_2$ is commonly used to form the passivation layer, but a high-temperature process and low thermal stability is a critical factor of low minority carrier lifetime. In this study, atomic layer deposition was used to grow the $Al_2O_3$ passivation layer at low temperature process. $Al_2O_3$ was selected as a passivation layer which has a low surface recombination velocity because of the fixed charge density. For the high charge density, an improved minority carrier lifetime, and a low surface recombination, nitrogen was doped in the $Al_2O_3$ thin film and the improvement of passivation was studied.

• Korean Journal of Materials Research
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• v.30 no.6
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• pp.301-307
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• 2020

In this study, factors considered to be causes of promotion of densification of sintered pellets identified during phase change are reviewed. As a result, conclusions shown below are obtained for each factor. In order for MA powder to soften, a temperature of 1,000 K or higher is required. In order to confirm the temporary increase in density throughout the sintered pellet, the temperature rise due to heat during phase change was found not to have a significant effect. While examining the thermal expansion using the compressed powder, which stopped densification at a temperature below the MA powder itself, and the phase change temperature, no shrinkage phenomenon contributing to the promotion of densification is observed. The two types of powder made of Ti-silicide through heat treatment are densified only in the high temperature region of 1,000 K or more; it can be estimated that this is the effect of fine grain superplasticity. In the densification of the amorphous powder, the dependence of sintering pressure and the rate of temperature increase are shown. It is thought that the specific densification behavior identified during the phase change of the Ti-37.5 mol.%Si composition MA powder reviewed in this study is the result of the acceleration of the powder deformation by the phase change from non-equilibrium phase to equilibrium phase.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.12
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• pp.793-799
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• 2016

In a hybrid fuel cell system, low-temperature reforming technology, which uses waste heat as a heat source, is applied to improve system efficiency. A low temperature reformer is required to optimize geometry in low thermal conditions so that the reformer can achieve the proper methane conversion rate. This study analyzed internal temperature distributions and the reaction patterns of a reformer by considering the change of the shape factor on the limited heat supply condition. Unlike the case of a high temperature reformer, analysis showed that the reaction of a low temperature reformer takes place primarily in the high temperature region of the reactor exit. In addition, it was confirmed that the efficiency can be improved by reducing the GHSV (gas hourly space velocity) or increasing the heat transfer area in the radial direction. Through reacting characteristic analysis, according to change of the aspect ratio, it was confirmed that a low temperature reformer can improve the efficiency by increasing the heat transfer in the radial direction, rather than in the longitudinal direction.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.159-159
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• 2016

Vertically-aligned carbon nanotubes (VCNT) have attracted much attention due to their unique structural, mechanical and electronic properties, and possess many advantages for a wide range of multifunctional applications such as field emission displays, heat dissipation and potential energy conversion devices. Surface modification of the VCNT plays a fundamental role to meet specific demands for the applications and control their surface property. Recent studies have been focused on the improvement of the electron emission property and the structural modification of CNTs to enable the mass fabrication, since the VCNT considered as an ideal candidate for various field emission applications such as lamps and flat panel display devices, X-ray tubes, vacuum gauges, and microwave amplifiers. Here, we investigate the effect of surface morphology of the VCNT by water vapor exposure and coating materials on field emission property. VCNT with various height were prepared by thermal chemical vapor deposition: short-length around $200{\mu}m$, medium-length around $500{\mu}m$, and long-length around 1 mm. The surface morphology is modified by water vapor exposure by adjusting exposure time and temperature with ranges from 2 to 10 min and from 60 to 120oC, respectively. Thin films of SiO2 and W are coated on the structure-modified VCNT to confirm the effect of coated materials on field emission properties. As a result, the surface morphology of VCNT dramatically changes with increasing temperature and exposure time. Especially, the shorter VCNT change their surface morphology most rapidly. The difference of field emission property depending on the coating materials is discussed from the point of work function and field concentration factor based on Fowler-Nordheim tunneling.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.410.2-410.2
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• 2016

Tandem structure is promising in organic solar cells because of its double open-circuit voltage (VOC) and efficient photon energy conversion. In a typical tandem device, the two single sub-cells are stacked and connected by an interconnecting layer. The fabrication of two sub-cells are usually carried out in a glovebox filled with nitrogen or argon gas, which makes it expensive and laborious. We report a glovebox-free fabricated inverted tandem organic solar cells wherein the tandem structure comprises sandwiched interconnecting layer based on p-doped hole-transporting, metal, and electron-transporting materials. Complete fabrication process of the tandem device was performed outside the glove box. The tandem solar cells based on poly(3-hexylthiophene) (P3HT) and (6,6)-phenyl C61-butyric acid methyl ester (PCBM) can realize a high VOC, which sums up of the two sub-cells. The tandem device structure was ITO/ZnO/P3HT:PCBM/PEDOT:PSS/MoO3/Au/Al/ZnO-d/P3HT:PCBM/PEDOT:PSS/Ag. The separate sub-cells were morphologically and thermally stable up to 160 oC. The high stability of the active layer benefits in the fabrication processes of tandem device. The performance of tandem organic solar cells comes from the sub-cells with an 50 nm thick active layer of P3HT:PCBM, achieving an average power conversion efficiency (PCE) of 2.9% (n=12) with short-circuit current density (JSC) = 4.26 mA/cm2, VOC = 1.10 V, and fill factor (FF) = 0.62. Based on these findings, we propose a new method to improve the performance and stability of tandem organic solar cells.

• Journal of Environmental Science International
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• v.25 no.2
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• pp.281-288
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• 2016

After analyzing of heating value of four kinds of RDF, the RDF-D has the highest heating value, was chosen to be mixed with carbonized sludge by different ratio. The 85%:15% ratio, which has the highest efficiency, was analyzed with thermogravimetric and pyrolysis kinetics. Applying of Kissinger method, activation energy was obtained from slope which is calculated from relation of ln(${\beta}/T^2{_m}$) and $1/T_m$. The kinetic parameters obtained from Kissinger method were 46.06 kJ/mol of RDF, 55.99 kJ/mol of carbonized sludge and 40.68 kJ/mol of mixture of RDF and carbonized sludge. The mixture of RDF and carbonized sludge has the lowest activation energy and frequency factor, during thermal decomposition reaction it has the slowest reaction rate and needs the lowest energy. Although activation energy with pyrolysis of RDF was irregularly scattered, it showed that activation energy was stabilized by co-pyrolysis of RDF and additives(Carbonized Sludge).

• Journal of the Korea Concrete Institute
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• v.15 no.5
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• pp.759-767
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• 2003

This paper presents the simplified but more rational analysis method for the prediction of additional internal forces induced in integral abutment bridges. These internal forces depend upon the degree of restraint provided tc the deck by the backfill soil adjacent to the abutments and piles. In addition, effect of the relative flexural stiffness ratio among pile foundations, abutment, and superstructure on the structural behavior is also an important factor. The first part of the paper develops the stiffness matrices, written in terms of the soil stiffness, for the lateral and rotational restraints provided by the backfill soil adjacent to the abutment. The finite difference analysis is conducted and it is confirmed that the results are agreed well with the predictions obtained by the proposed method. The simplified spring model is used in the parametric study on the behavior of simple span and multi-span continuous integral abutment PSC beam bridges in which the abutment height and the flexural rigidity of piles are varied. These results are compared with those obtained by loading Rankine passive earth pressure according to the conventional method. From the results of parametric study, it was shown that the abutment height, the relative flexural rigidity of superstructure and piles, and the earth pressure induced by temperature change greatly affect the overall structural response of the bridge system. It may be possible to obtain more rational and economical designs for integral abutment bridges by the proposed method.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.2 s.245
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• pp.126-135
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• 2006

The pressure drop characteristics in a rotating two-pass duct with rib turbulators are investigated in the present study. The square duct has a hydraulic diameter $(D_h)$ of 26.7 mm, and $1.5mm{\times}1.5mm$ square $90^{\circ}-rib$ turbulators are attached on the leading and trailing walls. The pitch-to-rib height ratio (p/e) is 10. The distance between the tip of the divider and the outer wall of the duct is $1.0D_h$ and the width of divider wall is 6.0mm or $0.225D_h$. The Reynolds number (Re) based on the hydraulic diameter is kept constant at 10,000 to exclude the Reynolds effect, and the rotation number (Ro) is varied from 0.0 to 0.20. The pressure drop distribution, the friction factor and thermal performance are presented for the leading, trailing and the outer surfaces. It is found that the curvature of the $180^{\circ}$-turn produces Dean vortices that cause high pressure drop in the turn. The channel rotation results in pressure drop discrepancy between leading and trailing surfaces so that non-dimensional pressure drops are higher on the trailing surface in the first-pass and on the leading and side surfaces in the second-pass. In the turning region, Dean vortices shown in the stationary case transform into one large asymmetric vortex cell, and subsequent pressure drop characteristics also change. As the rotation number increases, the pressure drop discrepancy enlarges.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.99-105
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• 2005

To evaluate structural safety factor of the jet vane for the thrust deflection system under the dynamic pressure and very high temperature($2700^{\circ}C$) of the combustion gas flow, the high temperature tension tests of refractory metals and 3-D nonlinear numerical simulations are performed. Through the analysis of high temperature structural behavior for jet vane, the structural safety of jet vane is evaluated, and numerical results are compared with static pound tests of jet vanes. It has been found that most of structural and thermal loading is concentrated on the vane shaft which worked as safe under $1400^{\circ}C$. From the comparison of static ground tests and numerical results, the evaluation criterion using the vane load and shaft displacement is more useful to estimate the structural safety than using the equivalent stress.

• Journal of Welding and Joining
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• v.27 no.5
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• pp.49-54
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• 2009

Recently, a demand of ferritic STS is increasing rapidly in automobile exhaust system. Exhaust manifolds are the part nearest to the engine so that the material is exposed to high temperature exhaust gas. Excellent heat resistant properties, especially high temperature strength, thermal fatigue resistance and high corrosion resistance are necessary for these parts. STS429L contains 15 weight percent of Cr and low Mo, so has good price competitive. And it has excellent high temperature strength and corrosion resistance, so receives attentions as material that applying to exhaust manifold. In tensile test of lap joint welded STS 429L, most of specimens are failed in base metal, but occurs brittle fracture in weld metals at some specimens in the face of good welding conditions. In the process of tensile test, lap joint welded STS429L specimens are transformed locally. The brittle fracture occurs that local transforming area exists in weld metals. But, butt welding specimens made by same materials showed ductile fracture in tensile test and bending test. In this study, suppose the reason of brittle fracture is in the combined local transform and tensile stress, through analysis of bead geometry, evaluate geometrical factor of brittle fracture in lap joint welded STS429L.