• Journal of the Korean Ceramic Society
• /
• v.37 no.3
• /
• pp.288-293
• /
• 2000

Effects of contact damage and residual stress for two kinds of dental restorative layered ceramics, porcelain/alumina and porcelain/zirconia bilayers, were observed with Hertzian and Vickers indentation methods. Indentation stress-strain behavior of each material, strength degradation of the coating material, and crack propagation behavior in the coating layer after Vickers indentation were examined by an optical microscope. As a result, porcelain as coating materials showed the classical brittleness. It was inferred that damage and strength in two bilayer system were dependent on thermal expansion mismatch between the coating material and the substrate, which affected the strength degradation. Residual stress resulting from thermal expansion mismtch was formed in the coating layer, and specially in the case of porcelain/zirconia, residual stress was eliminated as coating thickness decreased.

• Geomechanics and Engineering
• /
• v.18 no.2
• /
• pp.133-140
• /
• 2019

Strain-rate and temperature have significant effects on the one-dimensional (1D) compression behavior of soils. This paper focuses on the bonding degradation effect of soil structure on the time and temperature dependent behavior of soft structured clay. The strain-rate and temperature dependency of preconsolidation pressure are investigated in double logarithm plane and a thermal viscoplastic model considering the combined effect of strain-rate and temperature is developed to describe the mechanical behavior of unstructured clay. By incorporating the bonding degradation, the model is extended that can be suitable for structured clay. The extended model is used to simulate CRS (Constant Rate of Strain) tests conducted on structural Berthierville clay with different strain-rates and temperatures. The comparisons between predicted and experimental results show that the extended model can reasonably describe the effect of bonding degradation on the stain-rate and temperature dependent behavior of soft structural clay under 1D condition. Although the model is proposed for 1D analysis, it can be a good base for developing a more general 3D model.

• Progress in Superconductivity and Cryogenics
• /
• v.7 no.4
• /
• pp.4-9
• /
• 2005

The degradation behavior of the critical current $(I_c)$ of Bi-2223 superconducting tapes under pressurized liquid nitrogen were investigated using a newly developed p-shaped sample holder which gives a series of bending strains to a sample. Three kinds of commercially available multi-filamentary Bi-2223 superconducting tapes were used. At atmospheric pressure, the Ie degradation behavior depended on the manufacturing process undergone by each tape. The tapes externally reinforced or densified by over pressure showed better bending strain tolerance than the Ag alloy-sheathed Bi-2223 tape. But these tapes showed a significant $I_c$ degradation when pressurized to 1 MPa in liquid nitrogen. For all samples, after depressurization to atmospheric pressure from 1 MPa, the Ie was completely recovered to its initial values at atmospheric pressure. When the samples were subjected to a thermal cycle wherein the tape was warmed up to room temperature after being depressurized from 1 MPa, it was found that the larger degradation of $I_c$ occurred at the regions where significant ballooning occurred, such as $0\%\;and\;0.2\%$. However, an improved ballooning damage tolerance was observed in the highly-densified tape.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2000.04a
• /
• pp.31-37
• /
• 2000

Metal matrix composites(MMCs) are rapidly becoming one of the strongest candidates for structural materials for many high temperature application. Among the high temperature environment, thermal shock is known to cause significant degradation in most MMC system. Therefore, the nondestructive evaluation on thermal shock damage behavior of SiC/A16061 composite has been carried out using ultrasonic surface and SH-waves. For this study, Sic fiber reinforced metal matrix composite specimens fabricated by a squeeze casting technique were thermally cycled in the temperature range 25~$400^{\circ}C$ up to 1000 cycles. Three point bend test was conducted to investigate the effect of thermal shock damage on mechanical properties. The relationship between thermal shock damage behavior and the change of ultrasonic velocity and attenuation were discussed by considering SEM observation of fracture surface.

• Journal of the Korean Ceramic Society
• /
• v.50 no.6
• /
• pp.523-527
• /
• 2013

Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.

• International Journal of Industrial Entomology and Biomaterials
• /
• v.37 no.1
• /
• pp.29-32
• /
• 2018

Silkworm powder's thermal property is an important factor for its storage and marketing. This study examined the effect of edible enzyme on the thermal property of silkworm powder using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). Results of the TGA showed that regardless of the enzyme treatment, the weight loss patterns of silkworm powders exhibited 3 step thermal property deterioration at approximately $80^{\circ}C$, $280^{\circ}C$, and $480^{\circ}C$ due to water evaporation and thermal degradation. This is similar with the DSC which also resulted in all samples two endothermic peaks attributed also to water evaporation and thermal degradation. These results indicated that the use of enzyme such as protease and cellulase might not affect significantly the thermal properties of silkworm powder.

• Progress in Superconductivity and Cryogenics
• /
• v.7 no.2
• /
• pp.11-15
• /
• 2005

The I$_{c}$ degradation behavior of Bi-2223 tapes bent at RT and 77K were investigated using the bending device invented by Goldacker. Test results on fixing the tape at RT and 17K showed no difference. At 17K and RT bending, the critical strain was 0.67 and 0.50$\%$, respectively, for the VAM-l tape. For the AMSC tape, it was 0.94 and 0.88$\%$, respectively. These results show that there is additional residual stress in the superconducting filaments to be bent at 17K which shifts the formation of cracks into smaller bending radii. This was proved by computational analysis based on the mixture rule of composites. For the VAM-l tape, the Ie degradation behavior using the Goldacker type device shifted to higher strain levels at about 0.5$\%$, as compared with the FRP sample holders which have a critical bending strain of about 0.24$\%$. Also, for the externally reinforced AMSC tape, Ie degradation using the Goldacker type device begins at a higher strain level, at 0.88$\%$ as compared with using FRP sample holders, at 0.74$\%$. The difference between both cases can be explained by the tensile' and thermal stresses that the tapes were subjected to during fixing (soldering) when the FRP sample holders were used.

• Journal of Sericultural and Entomological Science
• /
• v.40 no.1
• /
• pp.70-77
• /
• 1998

This study was carried out in order to find out the relationship between physical and chemical properties of silk fiber treated by concentrated calcium nitrate solution. The tensile, thermal and dynamic mechanical properties are also examined on Ca(NO3)2 treated silk fibers. The tensile properties of silk fibers treated by calcium nitrate changed with a concentration. The thermal behavior were also affected by the concentration of calcium nitrate. The degradation temperature (endotherms) and glass transition temperature shifted to lower temperature as the treated concentration increased. It is thought that the physical properties are strongly related to the structure and morphology of Ca(NO3)2 treated silk fibers. As a result, these give property changes with a concentration dependence.

• Polymer(Korea)
• /
• v.24 no.3
• /
• pp.314-325
• /
• 2000

Thermal degradation of thermoplasitc polyurethane modified polycarbonate has been investigated by means of DSC, GPC and FT-IR techniques. The polyurethanes used in this study are TPU-35 and TPU-53 containing 35.5 and 53.4 wt% of hard segments, respectively. The more content of hard segment, the higher the glass transition temperature (T$_{g}$) of TPU was observed. On the other hand, the T$_{g}$ of the TPU modified PC decreased with the content of TPU and the annealing temperature regardless of the hard segment contents. The latter behavior nay arise from the thermal degradation of TPU upon annealing process: the observed thermal degradation temperatures were at 240 and 25$0^{\circ}C$ for the PC/TPU-35 and PC/TPU-53, respectively. The molecular weight, molecular weight distribution and viscosity agree well with the DSC measurement, which implicates a thermal degradation of TPU. In addition, thermal stability of the TPU modified PC linearly decreased with an incorporation of TPU. Transesterification or any interaction was not observed using FT-IR: the evidence was no frequency shift or any variance betwere the carbonyl stretching and NH group. For the specimens prepared below the degradation temperature, the enhancement of the thickness dependent impact strength of the PC/TPU blend was observed, and the morphology of the two blends was compared.d.

• Journal of the Korean Wood Science and Technology
• /
• v.44 no.5
• /
• pp.685-694
• /
• 2016

In this study, the thermal degradation behavior of biomass during torrefaction was studied by thermogravimetric and byproduct gas analysis. Torrefaction temperature, time, and heating rate were $220{\sim}300^{\circ}C$, 110 min, and $10{\sim}30^{\circ}C/min$, respectively. The degradation rate of yellow poplar was 8.01~8.81% at $220^{\circ}C$ and 71.86~77.38% at $300^{\circ}C$ depending on heating rate. The degradation rate significantly increased at temperature over $240^{\circ}C$. On the other hand, degradation rate of larch was relatively low as 49.58~54.15% at $300^{\circ}C$. The activation energy of yellow poplar was 87.32~91.24 kJ/mol; these values did not significantly change with heating rate. The activation energy of larch was 83.85~91.60 kJ/mol. The major components of the gas generated during torrefaction were derived from hemicellulose. The component types and concentrations increased with torrefaction severity. High concentrations of furfural and acetic acid were detected during torrefaction of yellow poplar.