• Title/Summary/Keyword: thermal cracks

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A Study of Photo-electric Efficiency Improvement using Ultrasonic and Thermal Treatment on Photo-electrode of DSC (염료감응형 태양전지 광전극의 초음파 열처리를 통한 광전효율 개선에 관한 연구)

  • Kim, Hee-Je;Kim, Yong-Chul;Choi, Jin-Young;Kim, Ho-Sung;Lee, Dong-Gil;Hong, Ji-Tae
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.5
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    • pp.803-807
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    • 2008
  • A making process of DSC(dye sensitized solar cell) was presented. In general, Photo electrodes of DSC was made by using colloid paste of nano $TiO_2$ and processing of Doctor-blade printing and high temperature sintering for porous structure. These methods lead to cracks on $TiO_2$ surface and ununiform of $TiO_2$ thickness. This phenomenon is one factor that makes low efficiency to cells. After $TiO_2$ printing on TCO glass, a physical vibration was adapted for reducing ununiform of $TiO_2$ thickness. And a thermal treatment at low temperature(under $75^{\circ}C$) was adapted for reducing cracks on $TiO_2$ surface. In this paper, we have designed and manufactured an ultrasonic circuit (100W, frequency and duty variable) and a thermal equipment. Then, we have optimized forcing time, frequency and duty of ultrasonic irradiation and thermal heating for surface treatment of photo-electrode of DSC. In I-V characteristic test of DSC, ultrasonic and thermal treated DSC shows 19% improved its efficiency against monolithic DSC. And it shows stability of light-harvesting from drastically change of light irradiation test.

Finite Element Analysis of Thermal Stresses on a Hearth Roll Surface Depending on Changes in the Neck Shape (허스롤 목 부위 형상 변화에 따른 열응력 분포 변화 유한요소해석)

  • Na, D.H.;Lee, Y.
    • Transactions of Materials Processing
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    • v.25 no.3
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    • pp.169-175
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    • 2016
  • The hearth roll, which transfers the cold-rolled strip sheet in a Continuous Annealing Line (CAL), is always subjected to changes in the surface temperature and subsequently experiences thermal stress in service. These variations lead to the generation of thermal cracks on the hearth roll surface as well local plastic deformation. We performed finite element analysis to predict the thermal stress changes on the hearth roll surface and designed the collar shape of the hearth roll to minimize these thermal stresses. Results show that the hearth roll with a collar having an obtuse angle is much more effective than a hearth roll with collar having a right angle when the tangential stress, which is one of main causes leading to surface cracks, is compared for the various conditions. It was found that the tangential stress and the temperature on the surface of hearth roll can be reduced by 51.9% and 26℃ if the shape of roll on collar is re-designed.

Effects of a Lift Height on the Thermal Cracking in Wall Structures

  • Kim, Sang-Chel
    • KCI Concrete Journal
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    • v.12 no.1
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    • pp.47-56
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    • 2000
  • Once a structure fabricated with mass concrete is in a form of wall such as retaining wall, side walls of a concrete caisson and so on, cracks induced by hydration heat have been known to be governed by exterior restraints which are mainly related to the boundary conditions of the structure. However, it is thought that the degree of restraints can be alleviated considerably only if a lift height of concrete placement or a panel size of the wall is selected properly before construction. As a way of minimizing thermal cracking commonly observed in massive wall-typed structure, this study aimed at evaluating effects of geometrical configuration on the temperature rise and thermal stress through parametric study. Evaluation of the effect was also performed for cement types using anti-sulphate cement, blast furnace slag cement and cement blended with two mineral admixture and one ordinary Portland Cement. so called ternary blended cement. As a result of analytical study, it was found that a lift height of concrete placement is the most important factor in controlling thermal cracking in massive wall, and the increase of a lift height is not always positive to the crack occurrence as not expected.

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A Study on Thermal Shock, Thermal Expansion and Thermal Cracking of Rocks under High Temperature (고온하에서 암석의 열충격, 열팽창 및 열파괴에 관한 연구)

  • 이형원;이정인
    • Tunnel and Underground Space
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    • v.5 no.1
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    • pp.22-40
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    • 1995
  • Thermomechanical characteristics of rocks such as thermal shock, thermal expansion, thermal cracking were experimentally investigaed using Iksan granite, Cheonan tonalite and Chung-ju dolomite to obtain the basic data for proper design and Chung-ju dolomite to obtain the basic data for proper design and stability analysis of underground structures subjected to temperature changes. The effect of thermal shock did not appear when the heating speed was under 3$^{\circ}C$/min. and there existed little difference between multi-staged cyclic heating and single-cycled heating. Thermal expansion of rocks was affected by mineral composition, crack porosity and the degree of thermal craking. In quartz-beraring multimineralic rocks such as Iksan granite and Cheonan tonalite, the thermal expansion coefficient increaseed continuously with temperature rise, but that of Chung-ju dolomite which was a monomineralic rock showed a constant value for the temperature above 250$^{\circ}C$, Chung-ju dolomite yielded the lowest critical threshold temperature(Tc) of 100$^{\circ}C$ and unstable thermal cracking was initiated above the new threshold temperature(Tc')of 300$^{\circ}C$. Above Tc' thermal cracks grew but they were not interconnected. Iksan granite showed closing of microcracks to the temperature of 100$^{\circ}C$, then expanded linearly to Tc of 200$^{\circ}C$. Above Tc, thermal cracking was initiated and progressed rapidly and almost all the grain boundaries were cracked at 600$^{\circ}C$. Cheonan tonalite also showed similar behavior to iksan granite except that Tc was 350$^{\circ}C$ and that thermal cracks propagated more rapidly. Thermal expansions calculated by Turner's equation were found to be valid in predicting the thermal expansion and cracking behavior of rocks.

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Aluminium Titanate Sintering Study Aimed at Rational Design of Microstructure for Optimal Thermal Shock Characteristics

  • Alecu, Ioan D.;Stead, Rodney J.
    • The Korean Journal of Ceramics
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    • v.5 no.1
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    • pp.78-81
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    • 1999
  • Aluminium titanate is highly anisotropic in thermal expansion. As a result, thermal stresses build up in the material and intergranular cracks can develop. Both the outstanding thermal shock resistance and the low mechanical strength of aluminium titanate ceramics are a result of intergranular microcracking. The authors have previously identified a possibility of remarkably increasing fracture toughness of aluminium titanate without excessive penalty on strength. The paper shows that sintered density and porosity measurements can be used for optimizing the sintering and microstructure of aluminium titanate for an ideal balance between toughness and strength and, hence, the best thermal shock resistance.

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Factors affecting fracture of full contour monolithic zirconia dental prosthesis in laboratory process (구치부 심미수복, 풀지르코니아 크라운의 파절원인과 그 해결방안)

  • Lee, Soo Young
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.23 no.2
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    • pp.77-79
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    • 2014
  • There are several factors affected fractures of full contour zirconia (FCZ) dental prosthesis in laboratory process. First, residual moisture can cause zirconia cracks. Complete dry is requisite before zirconia sintering to prevent zirconia cracks. Second, slow cooling rate is essential to prevent cracks during zirconia sintering process. Cracks in bridge pontic area, thick dental implant prosthesis can be prevented by slow cooling rate such as 3 degree Celsius per minute during zirconia sintering. Third, slow heating rate and slow cooling rate during staining and glazing procedure is necessary to inhibit thermal shock of sintered dental zirconia. Lower preheat temperature of porcelain furnace is recommended. Finally, using diamond disc to open embrasure can lead cracks.

Efficiency Assessment of Crack Maintenance Material Using Ultra Fine Cement (초미립자시멘트를 이요한 균열보수재 성능평가 연구)

  • 백인관;박현수;정란
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1095-1100
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    • 2000
  • Concrete structure often exhibit cracks due to the combination of material construction and design error. Minor crack can be tolerated depending on exposure condition, but major cracks are aesthetically unpleasant and affect the durability and safety of the structure. All of the reinforced concrete structure have many inevitable cracks for various reason such as drying shrinkage, heat liberation of cement and over loads. Epoxy resin injection widely used for repairing cracks in concrete is too sensitive to high temperature. Besides, the problem in the epoxy resin injection is the difficulty of quality control after execution. Whereas, Ultra Fine Cement is similar in coefficient of thermal expansion and modulus of elasticity to concrete. The objective of the study is to find out that it is possible for Ultra Fine Cement to be used for repairing cracks in reinforced concrete.

Study on the Crack Occurrence and Progress by Durability Test for Vehicular Turbine Housing (차량용 터빈 하우징의 내구시험에 의한 균열 발생 및 진행에 대한 연구)

  • Shin, Sang-Yun;Lee, Do-Hoon;Won, Soon-Jea;Kim, Dong-Hyoung;Ye, Byung-Joon
    • Journal of Korea Foundry Society
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    • v.38 no.2
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    • pp.48-54
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    • 2018
  • To improve the durability of the turbocharger, it is important to suppress cracking of the turbine housing; therefore, we investigated the initiation and growth of these cracks. First, we initiated a crack in the turbine housing using endurance experiments. After the endurance test, cracks mainly occurred in the valve seat, the nozzle area, and the scroll part of the turbine housing. The results of a fracture analysis of the cracks showed that cracks in the valve seat were initiated by fatigue fracture. This seems to be caused by the accumulation of mechanical and thermal stresses due to vibration of the turbine wheel and high-temperature exhaust gas. Also, cracks in nozzle and scroll area were initiated by intergranular corrosion due to the exhaust gas. Thus, although there are differences in the cause of initiation according to the site, a concentric waveform was observed in all fracture planes. This phenomenon indicates that cracks gradually grow due to repeated stress changes, and the main causes are the temperature difference of the exhaust gas and the vibration caused by the turbine shaft.

A Study on the Construction Method for the Thermal Crack Control of Underground Box Structure (지하박스구조물 온도균열제어를 위한 시공방안연구)

  • 오병환;유성원;김의성;전세진
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.205-210
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    • 1998
  • The strength and dimension of recent constructed subway box structures are increased considerably. These increases are resulting in much initial cracks by hydration heat and thermal stress. According to previous studies, decrease of cement amount by using superplasticizer and L/H value is the best way to eliminate hydration heat and stress. The analyses using finite element model were performed. By the result of analysis, the use of superplasticizer and the decrease of the change of longitudinal placing length are proved to be more effective for elimination thermal cracks. By ACI Code, for longitudinal placing length 25 m, the amount of wall temperature reinforcement is always lack despite of concrete mix proportion. With analytical result and the inducing crack joint, the in-site test were performed and the analytical results proved to be effective. However, the inducing crack joint is not effective if it is a small size.

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Thermal Stability of 2.5Y-TZP under Low-Temperature Aging (2.5Y-TZP의 안정성에 관한 연구)

  • 장성도;오경영
    • Journal of the Korean Ceramic Society
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    • v.27 no.2
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    • pp.226-232
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    • 1990
  • The degradation phenomena and thermal stability of 2.5Y-TZP at low-temperature were studied by means of XRD, Raman spectra and microstructural analysis. The degradation of heat-treated 2.5Y-TZP at 20$0^{\circ}C$-20hr in air was observed on the TZP surface, be caused by the cracks generated from tlongrightarrowm transformation, and the cracks was propagated inside the polycrystalline body. The ZrO2 grain boundaries and grains near the crack were revealed as if these were diffused and dissolved. And it was also observed mlongrightarrowt transformation as the degraded TZP was refired at 140$0^{\circ}C$, and it was thought to be the fact that the moisture in atmosphere during the aging process contributed to the degradation. The thermal stability of 2.5Y-TZP was improved dramatically with an addition of 3w/o CeO2 or a provision of high Y2O3 concentration on the TZP surface.

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