• Title/Summary/Keyword: thermal character

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Influence of Surface Morphology and Substrate on Thermal Stability and Desorption Behavior of Octanethiol Self-Assembled Monolayers

  • Ito, Eisuke;Gang, Hun-Gu;Ito, Hiromi;Hara, Masahiko;No, Jae-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.219-219
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    • 2012
  • The formation and thermal desorption behaviors of octanethiol (OT) SAMs on single crystalline Au (111) and polycrystalline Au, Ag, and Cu substrates were examined by X-ray photoelectron microscopy (XPS), thermal desorption spectroscopy (TDS), and contact angle (CA) measurements. XPS and CA measurements revealed that the adsorption of octanethiol (OT) molecules on these metals led to the formation of chemisorbed self-assembled monolayers (SAMs). Three main desorption fragments for dioctyl disulfide (C8SSC8+, dimer), octanethiolate (C8S+), and octanethiol (C8SH+) were monitored using TDS to understand the effects of surface morphology and the nature of metal substrates on the thermal desorption behavior of alkanethiols. TDS measurements showed that a sharp dimer peak with a very strong intensity on single crystalline Au (111) surface was dominantly observed at 370 K, whereas a broad peak on the polycrystalline Au surface was observed at 405 K. On the other hand, desorption behaviors of octanethiolates and octanethiols were quite similar. We concluded that substrate morphology strongly affects the dimerization process of alkanethiolates on Au surfaces. We also found that desorption intensity of the dimer is in the order of Au>>Ag>Cu, suggesting that the dimerization process occurs efficiently when the sulfur-metal bond has a more covalent character (Au) rather than an ionic character (Ag and Cu).

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Insulation Characteristic of Waste Sawdust-mixing Concrete (폐톱밥 혼입 콘크리트의 단열특성에 관한 실험적 연구)

  • Hong, Seung-Ryul;Cho, Byung-Hun;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.20 no.2 s.70
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    • pp.98-104
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    • 2005
  • Saw dust concrete f3r finding out insulation characteristic was tested using test plate $30cm{\times}30cm{\times}5cm$. basically, molds f3r the test of compressive, tensile, normal without sawdust, $0.05\%,\;0.1\%,\;0.2\%,\; 0.4\%,\;0.6\%,\;0.8\%,\;1.0\%,\;1.2\%,\;1.4\%,\;1.6\%,\;1.5\%,\;2.0\%$, mixing proportion. heat conductivity of the saw dust concrete mixed with the above proportion was taken in this study. Thermal conduction of normal concrete depends on mixing proportion strength aggregate character, water content. all these items are specified here in fables. $1.8\%\~2.0\%$ saw-dust mising concrete shows as the faction as normal insulation material has its function. and the higher saw-dust mixing rate becomes, the thermal conduction becomes the less Then, the conclusions are that saw-dust using concrete has better insulation function than normal concrete.

The characteristics of mineral hydrate insulation material using activated cement prepared from pilot plant activation system

  • Seo, Sung Kwan;Chu, Yong Sik;Kim, Tae Yeon;Kim, Yoo
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.428-433
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    • 2018
  • In this study, using the pilot plant activation system, the activated cement has been manufactured and then applied to the manufacturing process of mineral hydrate insulating material. The fineness of the activated cement is controlled at $5,000cm^2/g$ and $7,500cm^2/g$ and the features of mineral hydrate insulating material, using OPC and the activated cement for each degree of fineness, has been analyzed. As the result of analyzing the crystal habit of the manufactured mineral hydrate insulting material, it is analyzed that the main crystal phase of specimen is tobermorite and some quartz peak has been detected. As the degree of fineness of the activated cement increases, the height of bubble of slurry increases as well, whereas the tendency for the density character to decrease has been detected. Along with it, as the density character decreases, the compression strength has decreases, whereas the tendency for the thermal characteristic to increases has been detected. The main features of mineral hydrate insulating material, using the activated cement with the fineness of $7,500cm^2/g$, the compression strength of 0.36 MPa, and the thermal conductivity of $0.044W/m{\cdot}K$, presents the excellent features as insulation.

An Experimental Study on Thermal Stratification of Pressurized Plenum Underfloor Air Distribution System during Cooling (가압식 바닥급기 시스템의 여름철 성층화 경향에 관한 실험적 연구)

  • Kim, Dong-Hee;Yu, Ki-Hyung;Cho, Dong-Woo;Seo, Jung-Seok;Han, Sung-Phil
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.340-345
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    • 2007
  • The underfloor air distribution system has been attracting to architects and building owners as one of valuable system for the renovated and newly office building. In this paper, we discussed the thermal stratification profile of pressurized plenum underfloor air distribution(UFAD) according to indoor setting temperature, diffuser number, diffuser type. For this, the space of office building(H corp.) is selected for measuring the air volume of underfloor diffuser and vertical temperature profile. As a result, the thermal stratification profile is influenced by the number and type of the underfloor diffuser and thermal storage character of the underfloor. Whereas indoor setting temperature have a lower significant impact on thermal stratification.

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Study on Manufacturing Desulfurization Sorbent using Eggshell (달걀 껍질을 재활용한 탈황제의 제조에 관한 연구)

  • 이병호;이봉헌;박흥재;김우성
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.693-696
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    • 1998
  • We tried to develope a desulfurization sorbent using eggshell for recycling, practicability, and economic development. The calcination character of the eggshell was examined by thermal gravimetric analysis and qualitative-quantitative character by X-ray diffractometer(XRD) and scanning electron microscope(SEM). The calcination was occurred easily in the case of eggshell and its form was changed from calcite($CaCO_3$) to lime(CaO). The grain and pore sizes of the calcined sample after base-treatment were larger and more crystallic. The adsorption ability of the eggshell was two- to six-times in the calcination temperature more than in the grain size. Therefore, the eggshell was thought to be usable as the desulfurization sorbent.

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Research on the relationship between the thermal characteristics and the type of land cover in Beijing urban area by ASTER data

  • Zhu, QiJiang;Zhang, Xin;Bai, Xianghua
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.277-279
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    • 2003
  • The study utilizes remote sensing as the main monitoring means. With different spatial high-resolution, multichannel ASTER remote sensing image as the main information in Beijing city zone; with regional border and statistical data as auxiliary factor a study between the thermal space distribution character and the underground medium is analyzed based on the GIS logical algorithm and synthetic analysis technology. Results show thermal forming mechanism and the rule of distribution is mainly related to the underground medium and the change of the city distribution. Different underground medium has different degree and intensity influence on the thermal space distribution. Furthermore, urban greenbelt and water areas can reduce the thermal effect and large-scale greenbelt creates green island effect. In addition, Road net, residential area, population density, heat resources and so on have some positive effect on the thermal distribution, which increase the local temperature and intensity on the other hand. It is important to study the thermal distribution and its related factors, which contributes to the plan, construction and development of the city.

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Analyzing nonlinear mechanical-thermal buckling of imperfect micro-scale beam made of graded graphene reinforced composites

  • Khalaf, Basima Salman;Fenjan, Raad M.;Faleh, Nadhim M.
    • Advances in materials Research
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    • v.8 no.3
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    • pp.219-235
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    • 2019
  • This research is devoted to analyzing mechanical-thermal post-buckling behavior of a micro-size beam reinforced with graphene platelets (GPLs) based on geometric imperfection effects. Graphene platelets have three types of dispersion within the structure including uniform-type, linear-type and nonlinear-type. The micro-size beam is considered to be perfect (ideal) or imperfect. Buckling mode shape of the micro-size beam has been assumed as geometric imperfection. Modified couple stress theory has been used for describing scale-dependent character of the beam having micro dimension. Via an analytical procedure, post-buckling path of the micro-size beam has been derived. It will be demonstrated that nonlinear buckling characteristics of the micro-size beam are dependent on geometric imperfection amplitude, thermal loading, graphene distribution and couple stress effects.