• Analytical Science and Technology
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• v.19 no.4
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• pp.309-315
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• 2006

Two piperazine-templated metal sulfate complexes, $(C_4N_2H_{12})[Ni(H_2O)_6](SO_4)_2$, I and ($C_4N_2H_{12}$) $[Co(H_2O)_6](SO_4)_2$, II, have been synthesized by hydro/solvothermal reactions and their crystal structures analyzed by single crystal X-ray diffraction methods. Complex I crystallizes in the monoclinic system, $P2_1/n$ space group, a=12.920(3), b=10.616(2), $c=13.303(2){\AA}$, ${\beta}=114.09(1)^{\circ}$, Z=4, $R_1=0.030$ for 3683 reflections; II: monoclinic $P2_1/n$, a=12.906(3), b=10.711(2), $c=13.303(2){\AA}$, ${\beta}=114.10(2)^{\circ}$, Z=4, $R_1=0.032$ for 4010 reflections. The crystal structures of the piperazine-templated metal(II) sulfates demonstrate zero-dimensional compound constituted by diprotonated piperazine cations, metal(II) cations and sulfate anions. The structures of complex I and II are substantially isostructural to that of the previously reported our piperazine-templated copper(II) sulfate complex $(C_4N_2H_{12})[Cu(H_2O)_6](SO_4)_2$. The central metal(II) atoms are coordinated by six water molecules in the octahedral geometry. The crystal structures are stabilized by three-dimensional networks of the $O_{water}-H{\cdots}O_{sulfate}$ and $N_{pip}-H{\cdots}O_{sulfate}$ hydrogen bonds between the water molecules and sulfate anions and protonated piperazine cations. Based on the results of thermal analysis, the thermal decomposition reactions of the complex I was analyzed to have three distinctive stages whereas the complex II proceed through several stages.

• Journal of the Korean Ceramic Society
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• v.29 no.7
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• pp.533-538
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• 1992

Effect of Li2O.4B2O frit on the microstructural and thermal expansion behaviour of $\beta$-spodumene ceramics was investigated. With 4.0~8.0 wt.% frit addition, sintering temperature range was enlarged and densification was enhanced through liquid phase sintering. As the amount of frit addition was increased, thermal expansion coefficient was increased to 1.72$\times$10-6$^{\circ}C$-1 of its highest value, which indicated that the increment of thermal expansion coefficient due to the second phase was constrained.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.04a
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• pp.278-282
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• 1997

Thermal expension of the ball screw in semi-closed loop type CNC Lathe directly introduces positioning error along the travel axis. In this paper the thermal displacement of the ball screw is estimated by using macro variabie. The estimated dispacement of the ball screw are given to the NC in the form of pitch error compensation data into time interval. The thermal behaviour of the ball screw of the CNC Lasthe under the constant driving conditions was measured to examine the effectiveness of this compensation method. The results showed that thermal displacment of the ball screw were the positioning accuracy could be maintained to better then 6 .mu.m while using this compensation.

• Structural Engineering and Mechanics
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• v.4 no.6
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• pp.679-702
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• 1996

The finite element method is employed in conjunction with micromechanical modelling in order to assess the performance of ceramic thermal barrier coatings applied to structural components. The study comprises the conditions of the deposition of the coating by plasma spraying as well as the thermal cycling of the coated component, and it addresses particularly turbine blades. They are exposed to high temperature changes strongly influencing the behaviour of the core material and inducing damage in the ceramic material by intense straining. A concept of failure analysis is discussed starting from distributed microcracking in the ceramic material, progressing to the formation of macroscopic crack patterns and examining their potential for propagation across the coating. The theory is in good agreement with experimental observations, and may therefore be utilized in proposing improvements for a delayed initiation of failure, thus increasing the lifetime of components with ceramic thermal barrier coatings.

• Journal of the Korean Ceramic Society
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• v.29 no.8
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• pp.646-650
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• 1992

Effect of Li2O.4B2O3 frit addition on microstructural and thermal expansion behaviour of the $\beta$-spodumene ceramics made from kaolinite was investigated. With 2.0~4.0 wt% frit addition, the densification by liquid phase sintering caused low water absorption below 3% and enhancement of beding strength. As the amount of frit addition was increased, thermal expansion coefficient was increased to large scale, but in 2 wt% frit addition, its thermal expansion coefficient was constrained to 1.92$\times$10-6$^{\circ}C$-1.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2008.05a
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• pp.288-292
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• 2008

Plastics is commonly used in consumer electronics because of it is high strength per unit mass and good productivity. But plastic parts are usually distorted after injection molding due to the residual stress after filling, packing, cooling process, and etc. And plastic material is to be deteriorated according to various temperature conditions and operating time, which can be characterized by stress relaxation and creep. The viscoelastic behaviour of plastic materials in time domain can be expressed by the Prony series of the commercial code, ABAQUS. In the paper, the process to predict the post deformation under cyclic thermal loadings was suggested. The process was applied to the real panel, and the deformation predicted by the analysis was compared with that of real test, which showed the possibility of applying the suggested process to predict the post deformation of plastic product under thermal loadings.

• Advances in materials Research
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• v.6 no.4
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• pp.349-361
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• 2017

The nonlinear thermal buckling load parameter of the laminated composite panel structure is investigated numerically using the higher-order theory including the stretching effect through the thickness and presented in this research article. The large geometrical distortion of the curved panel structure due to the elevated thermal loading is modeled via Green-Lagrange strain field including all of the higher-order terms to achieve the required generality. The desired solutions are obtained numerically using the finite element steps in conjunction with the direct iterative method. The concurrence of the present nonlinear panel model has been established via adequate comparison study with available published data. Finally, the effect of different influential parameters which affect the nonlinear buckling strength of laminated composite structure are examined through numerous numerical examples and discussed in details.

• Nuclear Engineering and Technology
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• v.55 no.10
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• pp.3801-3807
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• 2023

Outcomes of the project "Comprehensive Verification of the FALCON Code for Calculation of Nuclear Fuel Temperature" relating to calculation of fuel temperature during relatively fast thermal transients are presented. Good prediction capabilities of the FALCON MOD01 code coupled with the GRSW-A code are shown as applied to the data of the TF3 and TF5 tests from the Transient Temperature Experiment IFA-507. The IFA-507 related dataset of the OECD/NEA International Fuel Performance Experiments (IFPE) Database is extended by the reconstructed dynamics of the axial power distribution in the rods during the transient phase of the experiment. Based on the code calculation, the time constant of the thermal fuel response to a power transient is estimated.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.11 s.254
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• pp.1107-1116
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• 2006

The droplet ejection process driven by an evaporating bubble in a thermal inkjet printhead is investigated by numerically solving the conservation equations for mass, momentum and energy. The phase interfaces are tracked by a level set method which is modified to include the effect of phase change at the interface and extended for multiphase flows with irregular solid boundaries. The compressibility effect of a bubble is also included in the analysis to appropriately describe the bubble expansion behaviour associated with the high pressure caused by bubble nucleation. The whole process of bubble growth and collapse as well as droplet ejection during thermal inkjet printing is simulated without employing a simplified semi-empirical bubble growth model. Based on the numerical results, the jet breaking and droplet formation behaviour is observed to depend strongly on the bubble growth and collapse pattern. Also, the effects of liquid viscosity, surface tension and nozzle geometry are quantified from the calculated bubble growth rate and ink droplet ejection distance.

• Steel and Composite Structures
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• v.34 no.2
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• pp.279-288
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• 2020

The computational post-buckling strength of the tilted sandwich composite shell structure is evaluated in this article. The computational responses are obtained using a mathematical model derived using the higher-order type of polynomial kinematic in association with the through-thickness stretching effect. Also, the sandwich deformation behaviour of the flexible soft-core sandwich structural model is expressed mathematically with the help of a generic nonlinear strain theory i.e. Green-Lagrange type strain-displacement relations. Subsequently, the model includes all of the nonlinear strain terms to account the actual deformation and discretized via displacement type of finite element. Further, the computer code is prepared (MATLAB environment) using the derived higher-order formulation in association with the direct iterative technique for the computation of temperature carrying capacity of the soft-core sandwich within the post-buckled regime. Further, the nonlinear finite element model has been tested to show its accuracy by solving a few numerical experimentations as same as the published example including the consistency behaviour. Lastly, the derived model is utilized to find the temperature load-carrying capacity under the influences of variable factors affecting the soft-core type sandwich structural design in the small (finite) strain and large deformation regime including the effect of tilt angle.