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Characterization and assessment of the dolomite powder for application as fillers in the marble-type ore (대리암형 백운석의 분체 특성과 충전재로서의 응용성 평가)

  • Noh, Jin-Hwan;Lee, Na-Kyoung
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.71-81
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    • 2007
  • The marble-type dolomite from the Jasung Mine, which was farmed by duplicated affects of contact metamorphism and subsequent hydrothermal alteration, corresponds to a high-purity dolomite ranging up to above 98wt.% in dolomite contents. The dolomite contain minor impurities such as quartz, muscovite, and pyrite. It is characteristic that the dolomite is fairy Fe-rich corresponding to 0.4 wt.% due to the presence of pyrite of possible hydrothermal origin. The dolomite is nearly white-colored and constituting with subhedral crystals ranging $0.35{\sim}0.46mm$M in size, forming equigranular texture. Compared to the typical high-Ca limestone from the Pungchon Formation, the powder characteristics of dolomite is rather superior in milling efficiency, yields of fine particles, and size distribution. In addition, except for iron contents, the dolomite powder is no less superior than the limestone in quality and characteristics as fillers with respects to not only whiteness, oil absorption, and specific surface area but also shape characters such as elongation ratio, aspect ratio, and sphericity. This good characteristics of dolomite powder seem to be originated basically from comparatively higher grade and crystallinity of dolomite. Higher iron contents and the presence of sulfides prevents the dolomite from application for uses by thermal treatment, except for metallic manufacture. However, if proper ore separation procedure is available, the dolomite can be sufficiently utilized as substitutes for high-Ca limestone in most fields of filler industries.

Thermal Stability of Ti-Si-N as a Diffusion Barrier (Cu와 Si간의 확산방지막으로서의 Ti-Si-N에 관한 연구)

  • O, Jun-Hwan;Lee, Jong-Mu
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.215-220
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    • 2001
  • Amorphous Ti-Si-N films of approximately 200 and 650 thickness were reactively sputtered on Si wafers using a dc magnetron sputtering system at various $N_2$/Ar flow ratios. Their barrier properties between Cu (750 ) and Si were investigated by using sheet resistance measurements, XRD, SEM, RBS, and AES depth profiling focused on the effect of the nitrogen content in Ti-Si-N thin film on the Ti-Si-N barrier properties. As the nitrogen content increases, first the failure temperature tends to increase up to 46 % and then decrease. Barrier failure seems to occur by the diffusion of Cu into the Si substrate to form Cu$_3$Si, since no other X- ray diffraction intensity peak (for example, that for titanium silicide) than Cu and Cu$_3$Si Peaks appears up to 80$0^{\circ}C$. The optimal composition of Ti-Si-N in this study is $Ti_{29}$Si$_{25}$N$_{46}$. The failure temperatures of the $Ti_{29}$Si$_{25}$N$_{465}$ barrier layers 200 and 650 thick are 650 and $700^{\circ}C$, respectively.ely.

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A Study on the Integrated Management System of Municipal Solid Waste from Seoul Metropolitan City (서울시 일반폐기물의 통합적 관리체계에 관한 연구)

  • 우세홍;홍상균
    • Journal of Environmental Health Sciences
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    • v.19 no.4
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    • pp.51-58
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    • 1993
  • The integrated solid waste management for Seoul Metropolitan city can be established on the basis of the following hierarchy of priorities: 1. Efforts for source reduction should be propelled by both government and citizens to achieve the effects of resource conservation. The adequate production and consumption which are environmentally amenable and sustainable can be induced by the reasonable imposition of deposit money for waste treatment to one-time use products. To accomplish source reduction effectively, the induction of legal and institutional regulation of producer and consumer participation is requisite. 2. For resource recovery, wastes generated should be recycled as far as practicable. Community residents are responsible to separate discharge, the authorities concerned have responsibility of separate collection, and recycling industry should be assissted through tax reduction and financing. Resource separation facilities can be constructed at Kimpo Metropolitan landfill site for wastes not separately collected due to some unavoidable circumstances. 3. Garbage should be composted. Garbage is uneconomical for incineration, because it has high moisture content and low calorie, thus there is no reason for the incineration of garbage even though garbage is classified into combustibles. Composting facilities can be located at sites which are not densely populated and easily accessible to transportation, for example, Kimpo Metropolitan landfill site. Compost produced can be managed by the authorities for the use of fertilizer to a green tract of suburban land and farms. 4. Nonhazardous combustible wastes not recyclable can be utilized for thermal recovery at the incinerators which are completely equipped with pollution control devices. According to the trend of local autonomy and the equity principle of local autonomous entities, incineration facilities of minimal capacity required can be constructed at each districts of Seoul Metropolitan city which have organized local assembly. In case of Yangcheon district, the economically combustible waste quantity is about 260 tons/day which exceeds 150 tons/day, the incineration capacity of existing facility. But, from now on, waste quantity can be reduced substantially by the intensive efforts of citizens for source reduction and recycling and the institutional support of administrative organizations. Especially, it is indispensable for the government to constitute institutional and technological bases that can recycle paper and plastics form 43% of waste generated. A good time for constructing of incineration facilities for municipal solid waste can be postponed to the time that pollution control technologies of domestic enterprises are fully developed to satisfy the standards of air pollution prevention, because the life expectancy of Kimpo Metropolitan landfill site is about 25 years. Within this period, institutional improvements and technological advancements can be attained, while the air qual. ity of Seoul Metropolitan city can be ameliorated to the level to afford incineration facilities. 5. For final disposal, incombustibles and ash are landfilled sanitarily at Kimpo Metropolitan landfill site.

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Properties of ZnO nanostructures by metal deposited on Si substrates (Metal 증착한 Si 기판 상의 ZnO 나노 구조 특성)

  • Jang, Hyeon-Gyeong;Jung, Mi-Na;Park, Seung-Hwan;Shin, Dae-Hyeon;Yang, Min;Yao, Takafumi;Chang, Ji-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • v.9 no.1
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    • pp.1034-1037
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    • 2005
  • The variation of shapes and related properties of ZnO nanostructures grown on the metal pattern and Si substrate have been investigated. Ni, Cr metal patterns were formed on Si (111) substrates by e-beam evaporation, and ZnO nanostructures were fabricated on it by using thermal evaporation of Zn powder in air. Growth temperature was controlled from 500 $^{\circ}$C to 700 $^{\circ}$C. When the growth temperature was relatively low, no considerable effect was found. However, UV emission intensity decreased, and Green-emission intensity, which is regarded as originated from the defect state in the ZnO nanostructure, increased as growth temperature increase. Also, the variation of nanostructure shape at high temperature (700 $^{\circ}$C) is understood in terms of the enhanced incorporation of metal vapor during the nanostructure formation.

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Performance Analysis of the Powerline Communication for Condition Monitoring System of an MW Class Offshore Wind Turbine's Nacelle (MW급 해상풍력발전기 나셀의 상태 감시를 위한 전력선 통신 성능 분석)

  • Sohn, Kyung-Rak;Kim, Kyoung-Hwa;Jeong, Seong-Uk;Nam, Seung-Yun;Kim, Hyun-Sik
    • Journal of Navigation and Port Research
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    • v.40 no.3
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    • pp.159-164
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    • 2016
  • The goal of this study is to implement a communication system that can monitor the status of the nacelle using the power cable itself, without the dedicated communication lines such as an UTP cable and optical fiber for the offshore wind turbine. An inductive coupling powerline communication system for a MW class offshore wind turbine was proposed and its communication performance was demonstrated. The inductive couplers was designed for operation at up to 500 A using a ferrite composite materials. Field test was carried out on the wind farms of Jeju island. Using the iperf communication test program, we have obtained more than 15 Mbps data transmission rate through the 100 m power cable that was installed between the nacelle and the bottom of the power converter. In the data transmission stability test for a week, there was no failure ever. The minimum transmission rate was 15 Mbps and the average data rate was about 20 Mbps. Next, we have installed an infrared camera inside the nacelle in order to measure the temperature distribution and variation of the nacelle. The real-time thermal image taken by the camera was successfully sent to the monitoring system without error.

The study on the measurement of volatile organic compounds in the air of A and B industrial area (모 공단 대기 중 휘발성 유기화합물 측정에 관한 연구)

  • Shin, Ho-Sang;Ahn, Hye-Sil
    • Analytical Science and Technology
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    • v.17 no.2
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    • pp.130-144
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    • 2004
  • Recently, the air pollution in A and B industrial area has become one of the most important issues, then 60 VOCs in the area were measured using a highly sensitive method. The VOCs were adsorbed onto Carbotrap using air sampler and subsequently desorbed by a thermal desorber system into gas chromatograph-mass spectrometry (TDS-GC-MS). The peaks of all compounds had good chromatographic properties and offered very sensitive response for the EI-MS (SIM). Method detection limits (MDL) ranged from 0.01 to 0.1 ppt(v/v), and linearities of calibration curves were over 0.995. We analyzed total 90 atmosphere air samples of A and B industrial complex using the method. Benzene, toluene, ethylbenzene, xylene, n-hexane, fluorotrichloromethane, carbon tetrachloride, 1,2-dichloroethane, 1,1,1-trichloroethane, trichloroethylene, tetrachloroethylene, styrene, 1,3,5-trimethylbenzene, 1,2,4-trimethylbenzene, sec-butylbenzene and naphthalen were identified as the major compounds in the air, and their average concentrations were 0.81, 5.02 1.30, 3.0, 0.81, 37.9, 0.07, 0.15, 0.15, 0.79, 0.06, 0.33, 0.03, 0.12, 0.23, and 0.35 ppb(v/v), respectively. The concentrations of VOCs were low in summer and high in fall or winter. When the concentrations detected in air compare with WHO's norm, no case exceed it.

Thermal and Ventilative Characteristics of Single-Span Oak Mushroom Production Facility as Affected by Area of Roof Opening and Shading Rates (단동 표고재배시설의 천창면적과 차광율에 따른 온도 및 환기특성)

  • 손정익
    • Journal of Bio-Environment Control
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    • v.9 no.2
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    • pp.120-126
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    • 2000
  • The quality of oak mushoom(Lentinus edodes(Berk) Sing) is sensitively affected by environmental factors, especially moisture by the rain during the growing period. To protect mushrooms from being wet, plastic-covered facilities with side openings are mostly being used. However, the indoor temperature and humidity f the facility without roof opening become higher due to its poor ventilation, and consequently reduce the productivity and quality as well. In this study, we analyzed the ventilation rates and indoor temperatures of improved facilities as affected by the area of roof opening and shading rate by the model. The indoor temperature decreased by more than 2.5$^{\circ}C$ as the shading rate increased from 50% to 90%, and especially the effect of wind speed on indoor temperature was significantly great under as low as 50% of shading rate. The ventilation rate became higher under wind speed of 1~2m.s-1 regardless of the shading rate. As the wind speed increased from 0m.s-1 to 2m.s-1, the indoor temperature decreased by more than 2.$0^{\circ}C$. Moreover, the indoor temperature became lower with increasing roof opening ratio, but showed no significant differences at more than 50% of roof opening ratio. At lower shading rate, the indoor temperature sensitively decreased with increasing area of roof opening. Additionally, we obtained the higher ventilation performance with the area of roof opening more or less equal to side opening, regardless of the wind speed and shading rate.

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Phonology and Minimum Temperature as Dual Determinants of Late Frost Risk at Vineyards (발아시기 정밀추정에 의한 포도 만상해 경보방법 개선)

  • Jung, Jea-Eun;Yun, Jin-I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.8 no.1
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    • pp.28-35
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    • 2006
  • An accurate prediction of budburst in grapevines is indispensable for vineyard frost warning system operations in spring because cold tolerance depends heavily on phonology. However, existing frost warning systems utilize only daily minimum temperature forecasts since there is no way to estimate the site-specific phonology of grapevines. A budburst estimation model based on thermal time was used to project budburst dates of two grapevine cultivars (Kyoho and Campbell Early), and advisories were issued depending on phonology as well as temperature. A 'warning' is issued if two conditions are met: the forecasted daily minimum temperature falls below $-1.5^{\circ}C$ and the estimated phonology is within the budburst period. A 'watch' is issued for a temperature range of -1.5 to $+1.5^{\circ}C$ with the same phonology condition. Validation experiments were done at 8 vineyards in Anseong in spring 2005, and the results showed a good agreement with the observations. This method was applied to the climatological normal year (1971-2000) to determine sites with high frost risk at a 30 m grid cell resolution. Among 608,585 grid cells constituting Anseong, 1,059 cells were identified as high risk for growing Kyoho and 2,788 cells for Campbell Early.

Climate Change Impact on the Flowering Season of Japanese Cherry (Prunus serrulata var. spontanea) in Korea during 1941-2100 (기후변화에 따른 벚꽃 개화일의 시공간 변이)

  • Yun Jin-I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.8 no.2
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    • pp.68-76
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    • 2006
  • A thermal time-based two-step phenological model was used to project flowering dates of Japanese cherry in South Korea from 1941 to 2100. The model consists of two sequential periods: the rest period described by chilling requirement and the forcing period described by heating requirement. Daily maximum and minimum temperature are used to calculate daily chill units until a pre-determined chilling requirement for rest release is met. After the projected rest release date, daily heat units (growing degree days) are accumulated until a pre-determined heating requirement for flowering is achieved. Model calculations using daily temperature data at 18 synoptic stations during 1955-2004 were compared with the observed blooming dates and resulted in 3.9 days mean absolute error, 5.1 days root mean squared error, and a correlation coefficient of 0.86. Considering that the phonology observation has never been fully standardized in Korea, this result seems reasonable. Gridded data sets of daily maximum and minimum temperature with a 270 m grid spacing were prepared for the climatological years 1941-1970 and 1971-2000 from observations at 56 synoptic stations by using a spatial interpolation scheme for correcting urban heat island effect as well as elevation effect. A 25km-resolution temperature data set covering the Korean Peninsula, prepared by the Meteorological Research Institute of Korea Meteorological Administration under the condition of Inter-governmental Panel on Climate Change-Special Report on Emission Scenarios A2, was converted to 270 m gridded data for the climatological years 2011-2040, 2041-2070 and 2071-2100. The model was run by the gridded daily maximum and minimum temperature data sets, each representing a climatological normal year for 1941-1970, 1971-2000, 2011-2040, 2041-2070, and 2071-2100. According to the model calculation, the spatially averaged flowering date for the 1971-2000 normal is shorter than that for 1941-1970 by 5.2 days. Compared with the current normal (1971-2000), flowering of Japanese cherry is expected to be earlier by 9, 21, and 29 days in the future normal years 2011-2040, 2041-2070, and 2071-2100, respectively. Southern coastal areas might experience springs with incomplete or even no Japanese cherry flowering caused by insufficient chilling for breaking bud dormancy.

Effect of Alkaline Activator and Curing Condition on the Compressive Strength of Cementless Fly Ash Based Alkali-Activated Mortar (시멘트를 사용(使用)하지 않은 플라이애시 알칼리 활성(活性) 모르타르의 압축강도(壓縮强度)에 미치는 알칼리 활성제(活性劑) 및 양생조건(養生條件)의 영향(影響))

  • Kang, Hyun-Jin;Ryu, Gum-Sung;Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Kim, Sung-Wook;Lee, Jang-Hwa
    • Resources Recycling
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    • v.18 no.2
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    • pp.39-50
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    • 2009
  • Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.