• Journal of the Korean Society for Heat Treatment
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• v.15 no.6
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• pp.272-278
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• 2002

The changes in damping capacity with volume fractions of thermal and deformation-induced ${\varepsilon}$ martensites were compared and analyzed in an Fe-23%-Mn alloy. The volume fraction of thermal ${\varepsilon}$ martensite increased with decreasing cooling temperature, whereas that of deformation-induced ${\varepsilon}$ martensite increased steeply up to 10%- of cold rolling and nearly saturated in further cold rolling. In the case of thermal ${\varepsilon}$ martensite, the damping capacity increased linearly with the increase in ${\varepsilon}$ martensite content. For the deformation-induced ${\varepsilon}$ martensite, however, the damping capacity increased continuously up to 70%- of ${\varepsilon}$ martensite, over which it decreased suddenly. TEM microstructures showed that the deterioration of damping capacity above 70%- of deformation-induced ${\varepsilon}$ martensite is ascribed to the introduction of perfect dislocations, which play a important role in inhibiting the movement of damping sources such as stacking fault boundaries inside ${\varepsilon}$ martensite, ${\varepsilon}$ martensite variant boundaries and ${\gamma}/{\varepsilon}$ interfaces.

• Journal of the Korean Society for Heat Treatment
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• v.4 no.3
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• pp.31-38
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• 1991

Effect of thermal cycling on shape memory effect and stabilization of austenite was investigated in Fe-21%Mn alloy. The thermal cyclic treatment was carried out with two types, room temperature${\leftrightarrow}215^{\circ}C$ and room temperature${\leftrightarrow}260^{\circ}C$. In case of the room temperature${\leftrightarrow}215^{\circ}C$, the SME was rapidly increased up to 3 cycles and maintained nearly constant value regardless of further cycles. In case of the room temperature${\leftrightarrow}260^{\circ}C$, however, the SME was increased with increasing the thermal cycle up to 5 cycles and decreased gradually with further cycle. The variation of the ${\varepsilon}$ martensite volume pet with the thermal cycle was in good agreement with the variation of the SME. Therefore, the change of the SME due to the cyclic treatment was explained with the change of the ${\varepsilon}$ martensite content. As the thermal cycle was increased, the $M_s$ temperature was decreased, and the $A_s$ and $A_f$ temperatures were increased, respectively.

• Journal of the Korean Society for Heat Treatment
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• v.14 no.3
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• pp.160-166
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• 2001

The change of ribbon geometry, microstructure and shape recovery with Mn contents, wheel speed and various annealing temperature have been studied in Fe-X%Mn-5Cr-5Co-4Si (X%=15, 20, 24) shape memory alloy (SMA) ribbons rapidly solidfied by single roll chill-block melt-spinning process. The thickness and width of melt-spun ribbons are reduced, results in refining and uniformalizing grains with increasing wheel speed. In the ribbons melt-spun at a wheel speed of 15m/sec, both ${\varepsilon}$ and ${\alpha}^{\prime}$martensites are formed in ribbon 1 (15.5wt%Mn), while only ${\varepsilon}$ martensite is revealed in ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn). The volume fraction of ${\varepsilon}$ martensite is decreased with increasing Mn contents, and those of ${\varepsilon}$ as well ${\alpha}^{\prime}$martensites are increased due to thermal stress relief and grain growth with increasing annealing temperature. Ms temperatures of the ribbons 1, 2 and 3 are fallen with increasing Mn contents. $M_s$ temperatures of the ribbons 1, 2 and 3 annealed at $300^{\circ}C$ for 3 min are risen abruptly, but are nearly constant even at higher annealing temperature, i.e., 400, 500 and $600^{\circ}C$ for 3 min. Shape recovery of the ribbons 1, 2 and 3 increased 30%, 52% and 69% with Mn contents, respectively. Shape recovery of ribbon 1 (15.5wt%Mn) formed ${\varepsilon}$ and ${\alpha}^{\prime}$martensites decreased because of the presence of ${\alpha}^{\prime}$martensite but those of ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn) formed ${\varepsilon}$ martensite increased with increasing annealing temperature.

• Journal of the Korean Society for Heat Treatment
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• v.7 no.2
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• pp.118-128
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• 1994

Five alloys were selected randomly in the composition range showing the best shape memory effect in Fe-Mn-Si system reported by Murakami. The shape memory effects of those alloys were mainly investigated through the training treatment which consisted of the repetition of 2% tensile deformation at room temperature and subsequent annealing at $600^{\circ}C$ above $A_r$ temperature. At the same deformation degress in rolling $600^{\circ}C$-annealing for 1 hr. showed the best shape memory effect, and 10%-deformation degrees represented maxima of the shpae memory effects at all annealing temperatures, $500^{\circ}C$, $600^{\circ}C$ and $700^{\circ}C$. The shape memory effects of the alloys were increased by increasing training cycle up to 5 cycles. This was because a large number of dislocations introduced by training process gave rise to increase in the austenite yield stress, and acted as nucleation sites for stress induced ${\varepsilon}$ martensite. The thermal cycling treatment, repetition of cooling in nitrogen at $-196{\circ}C$ and heating to $300^{\circ}C$ for 5 min., did not improve the shape memory effect.