• Title/Summary/Keyword: the volume functional

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Electrochemical Characteristics of the Activated Carbon Electrode Modified with the Microwave Radiation in the Electric Double Layer Capacitor (전기이중층캐패시터에서 마이크로파에 의해 개질된 활성탄소전극의 전기화학적 특성)

  • Sun, Jin-Kyu;Um, Eui-Heum;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.11-17
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    • 2010
  • Modifying surface of activated carbon for the electrode of EDLC with an organic electrolyte was investigated to improve the electrochemical performance of EDLC by the microwave radiation. Three kinds of activated carbons, prepared activated carbon from petroleum cokes and pitch cokes and commercial activated carbon BP-25, were used for this study. For all investigated activated carbons, hydrophilic functional groups-containing oxygen disappeared from the surface of activated carbon as microwave radiation. And as microwave radiation time was increased, the specific surface area and total pore volume of activated carbons were reduced and average pore diameter were increased. From theses effects, interfacial resistance of EDLC with the modified activated carbon electrode was drastically decreased, and discharge capacitance was increased although the specific surface area of activated carbon was reduced by this microwave radiation.

Effects of the Fluorination of Activated Carbons on the Chromium Ion Adsorption (활성탄소의 불소화가 크롬이온 흡착에 미치는 영향)

  • Kim, Min-Ji;Jung, Min-Jung;Choi, Suk Soon;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.92-98
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    • 2015
  • In this study, phenol-based activated carbons (ACs) were fluorinated at various fluorine partial pressures (0.01~0.03 MPa) and the $Cr^{6+}$ ion adsorption of fluorinated ACs was investigated. According to BET and XPS results, the specific surface area and total pore volume of fluorinated ACs increased by 24.7 and 55.8%, respectively, and fluorine functional groups were introduced to AC surface. The most optimized condition of $Cr^{6+}$ ion adsorption was confirmed at the fluorine partial pressure of 0.02 MPa. And also the removal efficiency of $Cr^{6+}$ ion was up to 98% at 300 mg/L of the initial concentration, and these results showed an approximately three-fold increase compared to that of using untreated ACs. Furthermore, the $Cr^{6+}$ ion adsorption of fluorinated ACs was completed in less than 30 min in contrast with untreated ACs, which was expected to be an increase of the affinity between $Cr^{6+}$ ions and ACs surfaces by fluorination.

Effect of Oxyfluorination of Activated Carbon Fibers on Adsorption of Benzene Gas Causing Sick House Syndrome (새집증후군 유발 벤젠가스 흡착에 미치는 활성탄소섬유의 함산소불소화 영향)

  • Lim, Hyung Soon;Kim, Min-Ji;Kong, Eun Young;Jeong, Jin-do;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.29 no.3
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    • pp.312-317
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    • 2018
  • In this study, activated carbon fibers (ACFs) were treated by oxy-fluorination to improve the adsorption property of benzene gas, one of the gases causing sick house syndrome. Surface properties and pore characteristics of oxyfluorinated activated carbon fibers were confirmed by X-ray photoelectron Spectroscopy (XPS) and Brunauer-Emmett-Teller (BET), and adsorption properties of benzene gas were evaluated by gas chromatography (GC). As a result of XPS data, it was confirmed that the fluorine functional groups on activated carbon fibers surface increased with increasing the fluorine partial pressure. The specific surface area of all samples decreased after the oxyfluorination treatment, but the micropore volume ratio increased when the fluorine partial pressure was at 0.1 bar. The oxyfluorinated activated carbon fibers adsorbed 100 ppm benzene gas for an 11 h, it was found that the adsorption efficiency of benzene gas was improved about twice as much as that of untreated ones.

Evaluations on Salivary Flow Induction and Dissolution Patterns in Saliva of Pilocarpine Chewing Tablet in Healthy Human Volunteers (건강한 성인 지원자를 대상으로 한 필로칼핀 저작정의 타액분비 유도 및 타액중 용출패턴 평가)

  • Park, Kyoung-Ho
    • Journal of Pharmaceutical Investigation
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    • v.27 no.4
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    • pp.331-335
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    • 1997
  • Xerostomia is caused by organic or functional changes affecting the salivary system at different levels. Patients suffering from xerostomia may also complain of an oral burning sensation, ulceration or soreness, difficulty in swallowing, and poor denture retention. And pilocarpine is administered orally to induce salivary secretion. In Seoul National University Hospital(SNUH) pharmacy, the pilocarpine chewing tablets are prepared and supplied to patients of xerostomia in request of the dental hospital in SNUH. And we tested the salivary flow induction and the dissolution patterns of these products in saliva by a double-blind, sequential cross-over trials to eight healthy human volunteers with placebo. The pilocarpine chewing tablet contained 5 mg of pilocarpine, and placebo consisted of same materials as test drug, but didn't contain pilocarpine. In vivo experiment, all subjects were instructed to chew as 60-80 times/min. Mixed saliva was collected in the ranges of intervals such as 0-2, 2-5, 5-10, 10-15, 15-20, 20-30, 30-45 and 45-60 min after pilocarpine chewing tablet or placebo administration. Saliva volume was measured in each collecting time interval, and saliva pilocarpine concentrations were determined by reversed phase HPLC. The 82.5 percent $(4.13{\pm}0.69\;mg)$ of pilocarpine was extracted from chewing tablets during mastication of 60-80 times per minute for 60 minutes. Among these dissolved amounts, 90 percent was extracted within 20 minutes. The salivary flow rates were more increased in a group who administered pilocarpine chewing tablet at the interval of 5-10, 10-15, 20-30 and 45-60 min rather than a placebo-group, but only extracted amount of pilocarpine at 45-60 min interval is significanly different between two groups (p<0.05). But total amounts of saliva secreted for 1 hour in two group-pilocarpine and placebo treated- were $46.36{\pm}9.72\;ml\;and\;39.09{\pm}7.81\;ml$, respectively, and were not significantly different between two groups.

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Activation of peroxisome proliferator-activated receptor gamma induces anti-inflammatory properties in the chicken free avian respiratory macrophages

  • Mutua, Mbuvi P.;Steinaa, Lucilla;Shadrack, Muya M.;Muita, Gicheru M.
    • Journal of Animal Science and Technology
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    • v.57 no.11
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    • pp.40.1-40.7
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    • 2015
  • Background: Activation of peroxisome proliferator activated receptor gamma ($PPAR{\gamma}$) in the alveolar macrophages (AM) by selective synthetic $PPAR{\gamma}$ ligands, improves the ability of the cells to resolve inflammation. In birds, respiratory macrophages are known as free avian respiratory macrophages (FARM) and show distinct functional differences from AM. The effects of treating FARM with $PPAR{\gamma}$ ligands are unclear. Methods: FARM were harvested by lavage of chicken respiratory tract and their morphology assessed at microscopic level. The effects of $PPAR{\gamma}$ agonists on the FARM in vitro viability, phagocytic capacity and proinflammatory cytokine (TNF-${\alpha}$) production were assessed. Results: FARM had eccentric nucleus and plasma membrane ruffled with filopodial extensions. Ultrastructurally, numerous vesicular bodies presumed to be lysosomes were present. FARM treated with troglitazone, a selective $PPAR{\gamma}$ agonist, had similar in vitro viability with untreated FARM. However, treated FARM co-cultured with polystyrene particles, internalized more particles with a mean volume density of 41 % compared to that of untreated FARM of 21 %. Further, treated FARM significantly decreased LPS-induced TNF-${\alpha}$ production in a dose dependent manner. Conclusion: Results from this study show that $PPAR{\gamma}$ synthetic ligands enhance phagocytic ability of FARM. Further the ligands attenuate production of proinflammatory cytokines in the FARM, suggesting potential therapeutic application of $PPAR{\gamma}$ ligands in the management of respiratory inflammatory disorders in the poultry industry.

A Study on the Yield of Functional Components of Citrus Peel Extracts using Optimized Hot Water Extraction and Enzymatic Hydrolysis (열수추출 및 효소처리에 따른 감귤 과피 추출물의 기능성성분 수득에 대한 연구)

  • Noh, Jung-Eun;Yoon, Sung-Ran;Lim, Ae-Kyoung;Kim, Hye-Jeong;Huh, Dam;Kim, Dae-Ik
    • Korean journal of food and cookery science
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    • v.28 no.1
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    • pp.51-55
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    • 2012
  • This study was conducted to investigate the physicochemical properties of citrus peel extracts with different hot water extraction and enzymatic hydrolysis conditions. Enzymatic hydrolysis was also employed using Viscozyme L and results were compared with that of optimized hot water extract. Hot water extraction was performed under different parameters; the sample to solvent ratio(1:20, 1:15, 1:10), extraction time(2, 4 hrs), extraction temperature(85, $95^{\circ}C$) and enzymatic hydrolysis(0, 1%) and the subsequent extracts were used for determining their physicochemical properties, such as total yield, total phenolics, total flavonoids, and electron donating ability (EDA). With the increase in the sample to solvent ratio and extraction time, total yield, total phenolics, total flavonoids and EDA increased. But extraction temperature did not significantly affect the hot water extract. As hot water extract was hydrolyzed by the enzyme, total yield and active ingredients increased rapidly. In the result of total yield, total phenolics, total flavonoids and EDA, the activity of enzyme-treated extract was higher than those of enzyme-untreated extract. Based upon the overall hot water extraction efficiency, it was found that 20 times volume or 120 min at a time at $95^{\circ}C$ after enzyme treatment was optimal.

Physicochemical Characteristics of Pound Cake Added with $\beta-Glucan$ ($\beta-Glucan$ 첨가 Pound Cake의 이화학적$\cdot$관능적 특성)

  • Shin Yu-Mi;Kim Mi-Kyoung;Cho Han-Young;Kim Mee-Ree
    • Journal of the East Asian Society of Dietary Life
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    • v.15 no.6
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    • pp.728-737
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    • 2005
  • This study was conducted to evaluate the physicochemical characteristics of pound cake made of substituted flour with different amount of $\beta-glucan$ i.e. 3, 6 and $9\%$ respectively. $\beta-glucan$ is a functional food material produced from Agrobacterium sup. R259 KCTC 10197BP. The specific gravity and pH of dough were found to be increased according to $\beta-glucan$ content Rheological property such as adhesiveness of dough has no difference between control and $\beta-glucan$ added groups. The pH of baked pound cake was not significantly different between control and $\beta-glucan$ groups. The volume of baked pound cake wag not significantly different between control and the ones with up to $6\%$ $\beta-glucan$, Lightness (L), redness (a) and yellowness (b) value of Hunter color system of cake crumb were not significantly different among teated groups, except a value of crust in $9\%$ $\beta-glucan$ group. the moisture content of cake increased according to $\beta-glucan$ content. Hardness by texture analyser was decreased with increasing $\beta-glucan$ content although cohesiveness wag not changed in β$\beta-glucan$ groups, compared with the control. Sensory evaluation results showed that the mean scores of over·all acceptability in 3 and $6\%$ $\beta-glucan$ were higher than that of control. Based on these results, the addition of $\beta-glucan$ to pound cake up to $6\%$ was considered to be desirable especially in terms of texture.

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USE OF MAGNETS IN THE TREATMENT OF ECTODERMAL DYSPLASIA (외배엽 이형성증 어린이에서 magnetic attachment를 이용한 보철치료)

  • Ju, Jin-Hyung;Lee, Kwang-Hee;Kim, Dae-Eop;Lee, Jong-Seon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.4
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    • pp.626-632
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    • 2001
  • Ectodermal dysplasia is a hereditary disease characterized by congenital dysplasia of one or more ectodermal structures. Intraorally, common findings are anodontia or oligodontia, conical teeth, and, consequently, generalized spacing. This case presented the oral rehabilitation of a child with hypohidrotic ectodermal dysplasia. Oral rehabilitation is important from functional, esthetic, and psychologic perspectives. Due to the absence of teeth, the volume of alveolar bone and its growth are decreased, resulting in a loss of vertical dimension and protuberant lips. The treatment involved increasing the patient's vertical dimension of occlusion, fabricating a maxillary partial denture, and using magnets to help retain the mandibular partial denture. A 5-year 7-month old Korean boy was referred to the pediatric department for examination, evaluation and treatment of his disorder. we used magnets on '73 and '83 for enhanced retention of a mandibular overdenture. The magnet used in this case was the Magfit system(GC Co., Japan).

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A Study on Management Plans through Case Analysis of Residential Complexes in Commercial Areas in Daejeon (대전시 상업지역 주거복합건축물 사례 분석을 통한 관리방안 연구)

  • Ryu, Kyungsoo
    • Journal of the Korean Regional Science Association
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    • v.39 no.2
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    • pp.63-76
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    • 2023
  • Recently, due to the location of residential complexes in commercial areas of large cities, the urban function is shifting from commercial to residential.In order to improve the use volume system in the commercial area of Daejeon Metropolitan City, the system of special and metropolitan cities was compared and analyzed, and problems were derived by analyzing 8 cases. First, use classification of mixed-residential buildings, Second, unbalance of urban planning for functional loss of commercial area, Thrid, damage on urban environment due to difference of development density. Accordingly, improvement measures include First, securing the ratio of residential function and mixed use at least 10%, Second, securing urban competitiveness by inducing facilities that combine various uses and functions. The overall floor area ratio of housing is applied, Third, the development density is presented through the establishment of the district unit plan and consultation.

Effect of Lithium Bis(Oxalato)Borate Additive on Thermal Stability of Si Nanoparticle-based Anode (리튬 이차 전지용 실리콘 나노입자 음극의 고온 열안정성에 대한 Lithium bis(oxalato)borate첨가제의 효과)

  • Kim, Min-Jeong;Choi, Nam-Soon;Kim, Sung-Soo
    • Journal of the Korean Electrochemical Society
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    • v.17 no.2
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    • pp.79-85
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    • 2014
  • Silicon (Si) has been investigated as promising negative-electrode (anode) materials because its theoretical specific capacity of 4200 mAh/g for $Li_{4.4}Si$ is far higher than that of carbonaceous anodes in current commercial products. However, in practice, the application of Si to Li-ion batteries is still quite challenging because Si suffers from severe volume expansion and contraction and lead to a continuous solid electrolyte interphase (SEI)-filming process by cracking of Si. This process consumes the limited $Li^+$ source, builds up thick and unstable SEI layer on the Si active materials, and will eventually disable the cell. Since unstable SEI reduces electrochemical performance and thermal stability of the Si anode, the surface chemistry of the anode should be modified by using a functional additive. It is found that lithium bis(oxalato)borate (LiBOB) as an additive effectively protected the Si anode surface, improved capacity retention when stored at $60^{\circ}C$, and alleviated exothermic thermal reactions of fully lithiated Si anode.