• Title/Summary/Keyword: the viscosity

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Ettect of Electrolytes on Flow Properties of Aqueous Bentonite Suspension

  • Kisoon Park;Taikyue Ree;Henry Eyring
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.303-312
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    • 1971
  • Dependence of the flow behavior of aqueous suspension of Black Hills bentonite on the concentration and the types of electrolytes was stydied. The flow properties were measured with a Couette-type totational viscometer. On addition of monovalent cations, the apparent viscosity determined from the reproducible flow curves (shear rate vs. shear stress) decreased followed by a rise as the ionic concentration further increased. Addition of multivalent cations (di- and tri-) resulted in the viscosity which increased to a maximum then decreased to a constant value. Anions of different chatges produced essentially the same relationship between viscosity and electrolyte concentration. The flow behavior of the electrolyte-containing suspensions was rationalized in terms of the Derjaguin-Landau-Verwey-Overbeek theory of colloidal stability and the generalized theory of viscosity.

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Solution Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp. (호 알칼리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 용액 특성)

  • 이신영;강태수김갑수
    • KSBB Journal
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    • v.10 no.4
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    • pp.386-392
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    • 1995
  • The high viscous ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) from alkalophilic Alcaligenes sp. was purified and its solution property was investigated. The intrinsic viscosities for Na+ form and H+ form of ${\gamma}$-PGA were 31.1 and 0.38d$\ell$/g, respectively. The viscosity of H+-PGA was not influenced by pH or salts while that of Na+-PGA was influenced. The intrinsic viscosity of Na+-PGA solution decreased remarkably at the alkaline or acidic pH and showed the sharp decrease when salts were added. ${\gamma}$-PGA exhibited the property of the polyelectrolyte showing the .sharp decrease of intrinsic viscosity by the addition of NaCl, and intrinsic viscosity of dilute solution with the low concentration of NaCl was exponentially dependent on temperature and its temperature dependency increased with increasing NaCl concentration. The chain stiffness, coil overlap parameter and critical concentration of Na+-PGA were 0.08, 5.25 and 0.07g/d$\ell$, respectively.

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Relative Property Evaluation of Pro-Environmental Warm Polymer-Modified Asphalt Binder (친환경형 중온 폴리머 개질 아스팔트 바인더의 상대적 물성 비교평가)

  • Kim, Nakseok;Lee, Jingoo
    • Journal of the Society of Disaster Information
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    • v.6 no.1
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    • pp.10-24
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    • 2010
  • In this paper, warm asphalt binder was proposed as a substitute for the polymer-modified asphalt binder to get higher viscosity than that of the polymer-modified at the same temperature. Performance grade test and rotational viscosity of warm asphalt binder were conducted to evaluate the property variations due to the addition of admixture. Research results showed that the viscosity of warm asphalt binder at $100^{\circ}C$ was similar to that of the conventional asphalt binder. The performance and durability of warm asphalt binder were also comparable to those of the polymer-modified. It is considered that the active applications of warm asphalt binder can reduce environmental damages due to less diffusions of carbon dioxide compared to the conventional.

Persistence length calculation from light scattering and intrinsic viscosity of dilute semiflexible polyimide solutions with different degree of imidization

  • Hansol Cho;Kim, Youn-Cheol;Kim, Sang-Ouk;Chung, In-Jae
    • Korea-Australia Rheology Journal
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    • v.12 no.1
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    • pp.69-76
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    • 2000
  • We have derived the translation diffusion coefficient and the intrinsic viscosity formula adopting the Kholodenko's theory using 3+1 dimensional Dirac propagator in the Kirkwood and Riseman scheme. We also performed static light scattering experiments and intrinsic viscosity measurement of dilute solutions of polyimides with different rigidities. In the framework of Kholodenko's theory, we can easily measure the persistence length of polyimide. We prepared five different polyamic acids and polyimides with different degree of imidization by controlling imidization temperatures. From experimental results, we obtained molecular weights and persistence lengths according to the Kholodenko's plot. The molecular weight and the intrinsic viscosity decreased and then increased with the imidization temperature but the persistence length increased monotonically and then leveled off. The persistence lengths calculated from intrinsic viscosities showed very good agreement with those from light scattering experiments.

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Design Guidelines for the Automatic Ball Balancer in CD/DVD Systems with Varying Eccentricity (편심이 변하는 CD/DVD시스템의 자동 볼 평형장치 설계 지침)

  • 김보현;류제하
    • Journal of KSNVE
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    • v.9 no.2
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    • pp.387-392
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    • 1999
  • This paper presents design guidelines for the automatic ball balancer in CD/DVD systems with varying eccentricity. In these systems, the size of balancing balls should be limited by the restricted race space so that determination of the number and mass of balls should consider the radii of the race and the balls. In addition, the effects of viscosity and friction also should be taken into account for sufficient balancing. Based on the static equilibrium conditions, the number and mass of balls corresponding to the range of varying eccentricity have been determined. Dynamic simulation with viscosity and friction shows sufficient viscosity must exist to ensure stability and friction between balls and race must be minimized to guarantee accurate balancing.

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A Study on the Viscosity and Flowability of Polymer-Cement Composites for Repairing Cracks of RC Structures (RC 구조물의 균열 보수용 폴리머 시멘트 복합체의 점도와 유동성에 관한 연구)

  • Hong, Dae-Won;Kim, Sang-Hyuk;Kwon, Woo-Chan;Jo, Young-Kug
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.166-167
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    • 2021
  • The purpose of this study is to evaluate the viscosity and flowability of polymer-cement composites for repairing cracks of RC structures. The viscosity and flowability of the polymer cement composites differed greatly depending on the type of polymer and the polymer cement ratio, and the polymer cement composites could be produced that could repair fine cracks in the RC structure without material separation by adjusting the proper water-cement ratio. In particular, the mixing of high viscosity EVA-modified polymer composites could be adjusted.

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Influence of viscosity and locality on a fiber-reinforced thermoelastic solid with two different theories

  • Samia M. Said;Mohamed I.A. Othman;Esraa M. Gamal
    • Advances in materials Research
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    • v.13 no.4
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    • pp.253-267
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    • 2024
  • The current study attempts to discuss the effects of viscosity and locality on a fiber-reinforced thermoelastic solid. The problem is solved analytically in the context of the three-phase-lag model as well as the Green-Naghdi theory without energy dissipation (G-N II). The method of normal mode analysis is used to obtain analytical expressions for the displacement, stress, and temperature distributions. Compute the physical fields with suitable boundary conditions and perform numerical calculations using MATLAB programming. Comparisons are carried out with the results in the absence and presence of locality as well as viscosity. The locality and viscosity have great effects on all considered physical fields since the amplitudes of these quantities are vary. This procedure remains valid when a nonlocal elastic solid is replaced with an elastic one.

Viscosity Study to Optimize a Slurry of Alumina Mixed with Hollow Microspheres

  • Bukhari, Syed Zaighum Abbas;Ha, Jang-Hoon;Lee, Jongman;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.403-409
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    • 2015
  • Porous alumina ceramics are involved in many industrial applications due to the exceptional properties of these products. This study addresses the preparation of porous alumina ceramics using hollow microspheres as a pore-forming agent and slip casting as a green-body-forming technique. A uniform distribution of pores is a basic requirement of a porous material. This study investigates three different slurry systems, i.e., as-prepared alumina slurry, alumina slurry electrostatically dispersed by hydrochloric acid (HCl), and slurry dispersed by the commercial dispersant 'Darvan C-N'. At a low viscosity, the hollow microspheres in the slurry tend to float, which causes a non-uniform pore distribution. To avoid this phenomenon, the viscosity of the slurry was increased to the extent that the movement of hollow microspheres ceased in the slurry. As a result, a uniform pore distribution was achieved.

Influence of Input Parameters on Shock Wave Propagation in Quasi-3D Hydrodynamic Model (준3차원 동수역학 모형의 입력변수가 충격파 전파에 미치는 영향)

  • Rhee, Dong Sop;Kim, Hyung-Jun;Song, Chang Geun
    • Journal of the Korean Society of Safety
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    • v.32 no.2
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    • pp.112-116
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    • 2017
  • Present study investigated the influence of time step size, turbulent eddy viscosity, and the number of layer on rapid and unsteady propagation of dam break flow. When the time step size had a value such that it resulted in Cr of 0.89, a significant numerical oscillation was observed in the vicinity of the wave front. Higher turbulent viscosity ensured smooth and mild slope of velocity and water stage compared with the flow behavior by no viscosity. The vertical velocity at the lower layer positioned near the bottom showed lower velocity compared with other layers.

Process Analysis and Experimental Evaluation by the Viscosity Measurement of Rheological Materials (레오로지 소재의 점도측정에 의한 공정해석 및 실험적 평가)

  • 서판기;강충길
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.05a
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    • pp.70-73
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    • 2002
  • Using a simple compression test, the viscosity measurement experiment is carried out with the grain-refined Al-Si alloy(A356). The measured rheological data are expressed with power-law(Ostwald-de Waele) model and using commercial package, MAGMAsoft, coefficients of Ostwald-de Waele model and Carreau-Yasuda model are calculated. To verify the viscosity data, the die is designed to be applicable to the semi-solid die casting of automotive component and filling test is carried out. The filling test and the simulation result are compared and in good agreement. Hereafter, these data are considered to be usefully allied other product in the semi-solid die casting.

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