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Strength Property of Ternary System Non-Cement Matrix according to the Curing Method (3성분계 무시멘트 경화체의 양생방법에 따른 강도특성)

  • Lee, Jin-Woo;Lee, Sang-Soo
    • The Journal of the Korea Contents Association
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    • v.14 no.4
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    • pp.389-396
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    • 2014
  • This study was conducted as the basic research for the replacement of Blast Furnace Slag, Red Mud, Silica Fume, etc., with cement as a solution to the problems arising from the global warming caused by the generation of $CO_2$, and conducted the experimental review to examine the feasibility of matrix having properties identical to those of cement by using the Blast Furnace slag, Red mud, Silica fume, and alkali-activator. For this, by using the the inorganic binder, such as Blast Furnace Slag, Red Mud, Silica Fume, etc., and NaOH, $Na_2SiO_3$ and others as the cement substitute material, the strength characteristic according to the mixture time variation was performed in the tentative experiment. Based on the preceding experiment, this study performed the experiment to analyze the strength properties of hardener through the curing by air-dry temperature, curing by temperature in water, coating curing, and Korean paper curing. For the water curing at $80^{\circ}C$, the compressive strength and flexural strength were found to be the most excellent at the age of the 28th day, and furthermore, it was found that the non-cement hardener could be made, which is considered to affect the production of eco-friendly concrete.

Properties of Epoxy Modified PVC-sol Sealants (에폭시가 함유된 PVC졸 실란트의 물성)

  • Lee, Seung-Jin;Kim, Hyun-Kyo;Park, Hwan-Man;Cho, Won-Jei;Ha, Chang-Sik
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.199-211
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    • 1999
  • In this work, the effects of the addition of epoxy on the properties of PVC-sol sealants were investigated. PVC-sol was plasticized with dioctyl phthalates(DOP). Two kinds of epoxy resins having different epoxy equivalent weight (E.E.W.) were used. It was found that the properties of the PVC-sol sealants were significantly affected by the contents and types of the added epoxy resins. The viscosity behaviors of the epoxy-modified sealants, in the case of epoxy A addition, the viscosity was decreased with increasing the epoxy contents, but In the case of $CaCO_3$ addition, the viscosity was increased with increasing the $CaCO_3$ contents. The viscosity of epoxy modified sealants aged at $45^{\circ}C$ waterbath was decreased with increasing epoxy contents, since the epoxy acted on the sealants as a stabilizer. The thermal stability of the PVC-sol sealants was slightly improved by adding epoxy. The tensile strength and elongation of sealants modified with epoxy A(two functionalities of epoxy) were increased with increasing the epoxy contents up to a certain epoxy contents but was decreased with further increasing the epoxy contents. In the case of $CaCO_3$ addition, the tensile strength of sealants were decreased with increasing the $CaCO_3$ contents. In view of the electrical properties, such as tan ${\delta}$($0.1{\pm}0.04$) and ${\epsilon}_r$($0.5{\pm}0.04$), it was found that the epoxy modified sealants were as good as insulators.

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Synthesis of polycrystalline powder of $Li_xNi_{1-y}Co_yO_2$ via the PVA-precursor method : the effect of synthetic variation on the electrochemical property of the lithium ion battery (PVA-전구체법을 적용한 $Li_xNi_{1-y}Co_yO_2$ 다결정성 분말의 합성 : 합성조건에 따른 리튬이온전지의 전기화학적 특성 고찰)

  • Kim Sue Joo;Song Me Young;Kwon Hye Young;Park Seon Hui;Park Dong Gon;Kweon Ho-Jin
    • Journal of the Korean Electrochemical Society
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    • v.2 no.1
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    • pp.5-12
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    • 1999
  • By the PVA-precursor method, polycrystalline powder of $Li_xNi_{1-y}Co_yO_2$, cathode material for lithium battery, was synthesized. Using the powder as the cathode material, lithium ion batteries were fabricated, whose electrochemical properties were measured. The effect of changing synthetic conditions, such as PvA/metal mole ratio, concentration of PVA, degree of polymerization of PVA, pyrolysis condition, and metal stoichiometry, on the battery performance was investigated. Considering the initial performance of the cell, the optimum stoichiometry of the $Li_xNi_{1-y}Co_yO_2$, synthesized by the PVA-precursor method was observed to be x: 1.0 and y=0.26. A minor phase of $Li_2CO_3$, which was generated by the residual carbon in the powder precursor, deteriorated the performance of the cell. In order to eliminate the minor phase, the precursor had to be pyrolyzed under the flow of dry air. Annealing the powder at $500^{\circ}C$ under the flow of dry air also eliminated the minor phase, and the performance of the cell was largely improved by the treatment.

The Frost Heaving Susceptibility Evaluation of Subgrade Soils Using Laboratory Freezing System (실내 동상시스템을 이용한 노상토의 동상민감성 평가)

  • Shin, Eun Chul;Ryu, Byung Hyun;Park, Jeong Jun
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.2
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    • pp.13-23
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    • 2013
  • The Korean Peninsula is considered as a seasonal frozen area that is thawed in the spring and frozen in the winter. The influence of fines of the frost susceptibility of subgrade soils were established by laboratory freezing tests simulating closely the thermal conditions in the field. During the winter season, the climate is heavily influenced by the cold and dry continental high pressure. Because of siberian air mass, the temperature of January is $-6{\sim}-7^{\circ}C$ on average. This chilly weather generate the frost heaving by freezing the moisture of soil and damage potential of the geotechnical structure. In the freezing soil, the ice lenses increase the freeze portion of soil by absorbing the ground water with capillary action. However, the capillary characteristics differ from the sort of soil on the state of freezing condition. In this study, ten soil samples are prepared. The basic physical property tests were performed by following the Korean Industrial Standard and the soil specimens were classified by the Unified Soil Classification System (USCS). These classified soils are used to perform the laboratory opened systems freezing test in order to determine the frost heaving characteristics of soils such as unfrozen water content, heaving amount, and freezing depth.

Physicochemical Heterogeneity of the Supply Water Quality depending on Seasonal Changes in the Taejon Area, Korea (대전지역 상수도 물의 계절변화에 따른 물리화학적 불균질)

  • 이현구;이찬희;서호택
    • Economic and Environmental Geology
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    • v.33 no.6
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    • pp.505-517
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    • 2000
  • This study was undertaken to provide a drinking water quality on the basis of physicochemical properties. In this study, the 25 samples of supply waters of the Taejon area were sampled twice (February and August in 1999). Hydrochemistry of the supply water belongs to the $Ca^{2+}$-${HCO_3}^{-1}$ type, whereas the supply water was characterized by the relatively significant enrichment of ${Ca}^{2+}$, ${Na}^{2+}$, ${K}^{2+}$, ${Cl}^{2+}$ ions and heavy metals compared to the original water from the Daecheong lake. Generally, the supply water has a mean values for $10.7^{\circ}C$ of temperature, 6.86 of pH, -12 mV of Eh, 88 ${\mu}S$/cm of EC and 70.379 mg/l of TDS in February, whereas the waters of the same sites in August are a slightly high temperature ($26.1^{\circ}C$), TDS (78.069 mg/l) and extremely high EC (442 ${\mu}S$/cm) value. These values are similar with physicochemical properties of the original lake water depending on the seasonal differences. Results of speciation calculation indicate that potentially toxic ions might exist mainly in the forms of free metal (${Cu}^{2+}$ or ${Zn}^{2+}$) and a small amount of ${CO_3}^{2-}$and ${OH}^{-}$in the supply water. The water seemed to be in equilibrium with kaolinite field of the normal stability diagrams for the natural water. Based on enrichment parameter of the supply water normalized by original lake water composition, the average value of those parameter can be calculated with nearly 1.00, but the those values for Cu+Zn possible source of decrepit pipe lines are 126.75 in February and 115.63 in August samples. The parameter values varied with sampling sites, however, do not exceed by chemistry of drinking water standard. Solid compounds remained on the membrane filter papers after filtration are adhered to pale yellow or yellowish brown colored dissolved solids and precipitates, which are coated by 0.02 to 0.35 mm thick per 500 ml with colloidal particles of about 1 to 2${\mu}m$ size. The particles are mainly Fe-Cu-Zn compounds and partly detected to Mn and Pb.

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The Study on the Crystal Growing of Mn-Zn Ferrite Single Crystals by Floating Zone Method (Floating Zone법에 의한 Mn-Zn Ferrite 단결정성장에 관한 연구)

  • 정재우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.1
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    • pp.10-19
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    • 1992
  • Mn - Zn Ferrite has physical properties of the high initial permeability, saturation magnetic flux density, and low loss factor as a representative magnetic material of soft ferrites, in addition the mechanical property is excellent as a single crystal. Therefore it is important electronic components and used for VTR Head. Mn - Zn Ferrite single crystals with the diameter 8mm were grown in atmosphere mixed with $O_2$ and Ar gas by the Floating Zone(FZ) method that impurities can not be incorporated to the crystals because of not-using the crucible to put in the melt, and the sharp temperature gradient results from making a focus at one point utilizing the infrared ray emitted from the halogen lamp as a heat source. During the crystal growing, the highest temperature of melting area was maintained to be $1650^{\circ}C$, growth rate and rotation rate were 10 mm/hr, 20 rpm respectively. The phases and the growth directions of crystals were determined from the analysis of X RD patterns, Laue, TEM diffraction patterns and etch pit shapes were observed by the optical microscope through the chemical etching. The corelation of optimum conditions for acquiring the better crystals was found out with the growth rate, the length and diameter of melt at the interface according to the diameter of feed rod, and the patterns of growing interface also studied.

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Geostatistical Integrated Analysis of MASW and CPTu data for Assessment of Soft Ground (연약지반 평가를 위한 MASW탐사와 CPTu 자료의 지구통계학적 복합 분석)

  • Ji, Yoonsoo;Oh, Seokhoon;Im, Eunsang
    • Geophysics and Geophysical Exploration
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    • v.19 no.4
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    • pp.187-199
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    • 2016
  • In order to delineate the soft ground distribution, an integrated geostatistical analysis was performed using the MASW (Multichannel Analysis of Surface Wave) which has the information of overall region and CPTu (Piezo Cone Penetration Test) which provides the direct information of the measuring point of the ground. MASW results were known to have close relationship with the ground stiffness. This correlation was confirmed through the comparison of MASW data obtained from two survey lines to the laboratory test with extracted soil samples. 3D physical property distribution in the study area was acquired by geostatistical integrated analysis with the data of tip resistance ($q_c$) and pore pressure (u) from the CPTu obtained at 6 points within the study area. The integrated analysis was conducted by applying the COSGSIM (Sequential Gaussian Co-Simulation) technology which can carry out the simulation in accordance with the spatial correlation between the MASW results and both tip resistance and pore pressure. Besides the locations of CPTu, borehole investigations were also conducted at two different positions. As a result, the N value of SPT and borehole log could be secured, so these data were used for the analysis of the geotechnical engineering accuracy of the integrated analysis result. For the verification of reliability of the 3D distribution of tip resistance and pore pressure secured through integrated analysis, the geotechnical information gained from the two drilling areas was compared, and the result showed extremely high correlation.

Study on the Demand Characteristics of Epoxy Resins Applied to the Restoration of Ceramics (도자기 복원에 사용되는 에폭시계 고분자수지의 요구 특성 연구)

  • Nam, Byeongjik;Jeong, Seri;Jang, Sungyoon
    • Journal of Adhesion and Interface
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    • v.13 no.4
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    • pp.171-181
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    • 2012
  • The demand characteristics of the conventional 12 kinds of epoxy resins which have been used for restoration of the ceramic relics were investigated to provide standards of the effective materials in this study. The result of durability analysis showed that a liquid type is more effective in ceramic relics (low damage, high strength), and a paste type is more effective in earthenware relics (high damage, low strength). The result of workability analysis appears that the liquid type is higher than the paste type, and a slow curing type is higher than a fast curing type in surface hardness. Therefore, in the case of the liquid type which is hard to reprocess due to high surface hardness, it is necessary to conduct a study on improving physical properties by adding filler. The result of the gloss analysis on epoxy resins showed that the liquid type (colorless) has higher gloss than the paste type, and the slow curing type has higher gloss than the fast curing type in liquid types. CDK-520A/520B and Araldite SV 427-2/HV 427-1 showed the most similar gloss to $700^{\circ}C$ earthenware, Devcon 5 minute, EPO-TEK 301-2, and Quik Wood showed the most similar gloss to celadon and whiteware, Quik Wood, EPO-TEK 301-2, and Devcon 5 minute showed the most similar gloss to buncheongware. It is necessary for conservator to decide the range of the restoration surface by predicting the increase and decrease of the restoration surface because most of the epoxy resins caused the volume change in curing process.

The Change in Geotechnical Properties of Clay Liner and the Contamination Behavior of Groundwater Due to Contaminant (오염물질에 의한 점토 차수재의 역학적 특성변화 및 지하수 오염거동)

  • Ha, Kwang-Hyun;Lee, Sang-Eun;Chung, Sung-Rae;Chun, Byung-Sik
    • Journal of Soil and Groundwater Environment
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    • v.13 no.1
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    • pp.13-23
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    • 2008
  • The triaxial compression tests and consolidation tests using NaCl solution and leachates as substitute pore (or saturated) water in samples were carried out to find out the behavior characteristics of strength, deformation and permeability coefficient of contaminated clay. Also, the chemical property analysis on the clay samples using scanning electron microscope and energy dispersive x-ray spectrometer were involved. The magnitudes of composition ratio were shown in the order of O, C, Si, Al, and Fe as a result of chemical composition analysis for clay samples. Besides, as the results of triaxial compression tests and consolidation tests, the shear strength, compression and permeability properties were increased with increasing in the concentration of contaminant (NaCl). It may be considered that these circumstances be caused by the changes of soil structure to flocculent structure due to the decrease in the thickness of diffuse double layer with increasing in the concentration of electrolyte. MT3D model was also using to grasp the procedures that the groundwater may be contaminated by the leachates permeated through the clay liner. The results of contaminant transport analysis showed a tendency that the predicted concentration of groundwater was higher with increasing in the initial concentration of $Cl^-$ ion and increased as a nonlinear curves with time. The transportation distance calculated by the use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with increasing the initial concentration.

A Constitutive Model for Soil Using Mohr-Coulomb Criteria (Mohr-Coulomb식(式)을 사용한 흙의 구성(構成)모델)

  • Lee, Hyung Soo;Lee, Byung Dae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.6
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    • pp.1405-1415
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    • 1994
  • The soil on the behavior of the nonlinear elastic work-hardening plasticity has a variety of stress paths due to the state of soil and the test conditions. The soil with a specific volume ${\upsilon}$ in principal stress space (${\sigma}_1$, ${\sigma}_2$, ${\sigma}_3$, and ${\upsilon}$v) displays the shape of an irregular hexagonal pyramid with an end cap. With variations of ${\upsilon}$ the size of the cap is changed but its shape remains unchanged and the movement of the cap is controlled by the increase or decrease of the plastic volumetric strain. By reflecting such a property of soil various cap models have been developed by researchers. In this thesis, a constitutive model of soil with a combination of the nonlinear elastic work-hardening plastic cap and the failure surfaces of Mohr-Coulomb (M-C cap model) has been developed. According to the the results of analyses using the work-hardening plastic cap model, the normally consolidated soil under shearing has experienced the work-hardening and plastic flow (movement of the cap). But in the shearing of the overconsolidated soil the elastic behavior is shown until the stress path has reached the failure surface and the cap does not move.

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