• The Korean Journal of Ceramics
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• 제6권2호
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• pp.138-142
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• 2000

Thin film $LiNbO_3$MFS (metal-ferroelectric-semiconductor) capacitor showed improved characteristics such as low interface trap density, low interaction with Si substrate, and large remanent polarization. This paper reports ferroelectric $LiNbO_3$thin films grown directly on p-type Si (100) substrates by 13.56 MHz RF magnetron sputtering system for FRAM (ferroelectric random access memory) applications. RTA (rapid thermal anneal) treatment was performed for as-deposited films in an oxygen atmosphere at $600^{\circ}C$ for 60sec. We learned from X-ray diffraction that the RTA treated films were changed from amorphous to poly-crystalline $LiNbO_3$which exhibited (012), (015), (022), and (023) plane. Low temperature film growth and post RTA treatments improved the leakage current of $LiNbO_3$films while keeping other properties almost as same as high substrate temperature grown samples. The leakage current density of $LiNbO_3$films decreased from $10^{-5}$ to $10^{-7}$A/$\textrm{cm}^2$ after RTA treatment. Breakdown electric field of the films exhibited higher than 500 kV/cm. C-V curves showed the clockwise hysteresis which represents ferroelectric switching characteristics. Calculated dielectric constant of thin film $LiNbO_3$illustrated as high as 27.9. From ferroelectric measurement, the remanent polarization and coercive field were achieved as 1.37 $\muC/\textrm{cm}^2$ and 170 kV/cm, respectively.

• 서비스연구
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• 제12권1호
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• pp.49-68
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• 2022

본 연구는 인류의 지속가능한 삶을 위한 금융시스템 디자인을 위해 수행되었다. 인류는 끊임없는 위기를 맞고 이를 극복하면서 삶을 영위하고 있다. 경제위기나 바이러스에 의한 위기를 극복하는 과정에서 양극화는 심화되고 있다. 자본주의 경제시스템을 채택하고 있는 사회에서는 시간의 경과와 함께 양극화가 심화되는 것이 일반적인 현상이기는 하지만, 양극화의 심화는 공동체로서의 인류사회를 파괴할 수 있으므로, 이에 대한 적극적인 대책이 요구된다. 본 연구는 인간의 삶과, 인류사회의 유지 방식 관점에서 중요한 금융 관련 시스템을 새롭게 디자인하여 양극화의 심화를 방지하고 사회의 안정성을 높이려는 목적으로 수행되었다. 인류의 역사를 통하여 화폐 금융과 지속가능한 사회 관련 시스템을 분석하고, 현대와 미래사회에 이상적이면서 장기적으로 지속가능한 금융시스템 모델을 도출하였다. 장기 지속가능한 금융시스템의 조건은 양극화 심화 등 현 시스템의 문제를 해결할 수 있는 모델이어야 하며, 현대경제사회의 특성과 지속가능한 삶의 본질에 충실한 모델이어야 한다. 그리고 인류사회의 공통원리에 기반해야 지속가능할 수 있다. 인류사회가 요구하는 성장과 평등 등 핵심 가치를 보장하는 모델이어야 한다. 현 금융시스템의 문제를 분석하고, 새로운 시스템에 요구되는 조건을 분석한 후, 새로운 금융시스템이 바탕을 두어야 하는 기본 공리를 제시하고, 이에 기반하여 바람직한 모델을 도출하였다. 도출된 시스템은 서비스주의 금융시스템으로 명명하였다. 금융과 돈에 관하여 사회와 개인에게 필요한 두 방향이 서로 팽팽한 대립면을 공유하며 상호 균형을 이루고 있을 때, 시민이 행복한 안정된 사회가 가능하기 때문이다. 서비스주의 금융시스템의 구조와 구체적인 운용모델 및 구현방안을 제시하였다. 향후 본 모델을 구체화하는 후속 연구가 필요하다.

• 한국전자통신학회논문지
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• 제18권6호
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• pp.1015-1022
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• 2023

본 논문에서는 4.7 GHz 특화망 대역에 적용할 수 있는 개구결합 급전을 갖는 이중 선형편파 안테나를 제안하였다. 제안된 안테나는 격리도 향상을 위해 일반적인 개구 결합급전을 갖고 상층과 하층에 각각 급전점을 갖도록 설계하였다. 각각의 기판의 크기는 34.0 mm×34.0 mm (W×L)이며 두께(h) 1.0 mm, 그리고 비유전율이 4.4인 FR-4 기판을 사용하였다. 또한 상층의 윗면에 12.7 mm×14.6 mm (W2×L3)의 패치를, 하층의 아랫면에 24.0mm×1.6 mm의 급전선로를, 접지면에 1.0 mm×7.7 mm(S×T)의 크기를 갖는 슬롯을 설계하여 패치로 급전되도록 하였다. 제작 및 측정 결과로부터, -10 dB 반사손실을 기준으로 배열 안테나의 경우, 입력포트 1에서 300.0 MHz (4.52~4.82 GHz), 입력포트 2에서 170.0 MHz (4.65~4.82 GHz)의 대역폭을 얻었으며 전달계수 S21은 -30 dB 이하의 값을 얻었다. 또한 각 급전포트에서의 편파분리도를 얻었다.

• 대한환경공학회지
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• 제30권2호
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• pp.155-160
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• 2008

본 연구에서는 다단계 전기화학적 반응기를 이용하여 환원제의 투입, 전극의 종류, 수리학적 체류시간(HRT : Hydraulic Retention Time) 및 전류밀도 변화에 따른 질산성질소의 제거효율을 살펴보았다. 실험결과, 환원제 투입은 질산성질소 제거효율을 증가시켰으며 에너지투입량은 감소시켰다. 전극종류를 변화시켰을 경우, 질산성질소 제거효율 및 전류효율의 차이는 거의 없었으나 Zn 환원제의 회수를 위해 B-type(1단 : Pt-Zn, 2단 : Pt-Zn, 3단 : Pt-Zn, 4단 : Pt-Zn)을 선정하였다. 수리학적 체류시간 변화실험에서는 수리학적 체류시간과 무관하게 동일전류밀도를 공급한 실험과 수리학적 체류시간 변화에 따른 전류밀도 변화 실험 즉, 단위부피당 동일 전류량 공급 실험을 진행하였다. 실험 결과, 수리학적 체류시간과 전류밀도 변화에 의해 농도분극현상과 적용전류량의 부족현상이 발생하게 된다. 즉 수리학적 체류시간이 감소할수록 농도분극현상은 감소하지만 단위 부피당 적용전류량이 부족하게 된다. 따라서 수리학적 체류시간과 전류밀도 실험을 통해 적절한 운전조건을 도출할 수 있으며, 내부 스페이서의 설치로 확산을 증가시킬 경우 질소제거효율 및 에너지효율이 증가될 수 있을 것으로 예상된다.

• 한국세라믹학회지
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• 제39권9호
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• pp.829-834
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• 2002

$Er(NO_3)_3{\codt}5H_2O,\;Mn(CH_3CO_2)_2{\cdot}4H_2O$를 출발원료로 사용하여 졸-겔 법으로 Si(100) 기판 위에 코팅된 $ErMnO_3$ 박막의 강유전 특성에 관하여 연구하였다. $ErMnO_3$ 박막은 800$^{\circ}C$에서 결정화가 시작되었으며, (001)로 우선 배향된 $ErMnO_3$ 박막을 얻을 수 있었다. 본 실험에서 800$^{\circ}C$에서 1 h 열처리하여 얻은 $ErMnO_3$ 박막은 1∼100 KHz의 주파수 범위에서 유전 상수(k)는 26, 유전 손실(tan ${\delta}$)은 0.032의 값을 나타내었으며, 이때 $ErMnO_3$ 박막의 입자 크기는 10∼30 nm이었다. 강유전 특성은 (001) 배향성이 증가할수록 잔류 분극 값이 증가하였으며, 800$^{\circ}C$에서 1시간 열처리하여 $ErMnO_3$ 박막의 잔류 분극 값($P_r$)은 400 nC/$cm^2$를 나타내었다. 또한 열처리 시간이 증가할수록 치밀하고 균일한 박막을 얻어 낮은 항전계 ($E_c$) 값을 가졌다.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2005년도 ISMP
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• pp.201-212
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• 2005

[ $Epoxy/BaTiO_3$ ] composite embedded capacitor films (ECFs) were newly designed fur high dielectric constant and low tolerance (less than ${\pm}15\%$) embedded capacitor fabrication for organic substrates. In terms of material formulation, ECFs are composed of specially formulated epoxy resin and latent curing agent, and in terms of coating process, a comma roll coating method is used for uniform film thickness in large area. Dielectric constant of $BaTiO_3\;&\;SrTiO_3$ composite ECF is measured with MIM capacitor at 100 kHz using LCR meter. Dielectric constant of $BaTiO_3$ ECF is bigger than that of $SrTiO_3$ ECF, and it is due to difference of permittivity of $BaTiO_3\;and\;SrTiO_3$ particles. Dielectric constant of $BaTiO_3\;&\;SrTiO_3$ ECF in high frequency range $(0.5\~10GHz)$ is measured using cavity resonance method. In order to estimate dielectric constant, the reflection coefficient is measured with a network analyzer. Dielectric constant is calculated by observing the frequencies of the resonant cavity modes. About both powders, calculated dielectric constants in this frequency range are about 3/4 of the dielectric constants at 1 MHz. This difference is due to the decrease of the dielectric constant of epoxy matrix. For $BaTiO_3$ ECF, there is the dielectric relaxation at $5\~9GHz$. It is due to changing of polarization mode of $BaTiO_3$ powder. In the case of $SrTiO_3$ ECF, there is no relaxation up to 10GHz. Alternative material for embedded capacitor fabrication is $epoxy/BaTiO_3$ composite embedded capacitor paste (ECP). It uses similar materials formulation like ECF and a screen printing method for film coating. The screen printing method has the advantage of forming capacitor partially in desired part. But the screen printing makes surface irregularity during mask peel-off, Surface flatness is significantly improved by adding some additives and by applying pressure during curing. As a result, dielectric layer with improved thickness uniformity is successfully demonstrated. Using $epoxy/BaTiO_3$ composite ECP, dielectric constant of 63 and specific capacitance of 5.1nF/cm2 were achieved.

• 한국재료학회지
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• 제21권7호
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• pp.391-395
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• 2011

The structure and dielectric properties of poled <001>-oriented 0.7Pb($Mg_{1/3}Nb_{2/3})O_3-0.3PbTiO_3$ (PMN-0.3PT) crystals have been investigated for orientations both parallel and perpendicular to the [001] poling direction. An electric field induced monoclinic phase was observed for the initial poled sample. The phase remained stable after the field was removed. A quite different temperature dependence of dielectric constant has been observed between heating and cooling due to an irreversible phase transformation. The results of mesh scans and temperature dependence of the dielectric constant demonstrate that the initial monoclinic phase changes to a single domain tetragonal phase at 370K and to a paraelectric cubic phase at 405K upon heating. However, upon subsequent cooling from the unpoled state, the cubic phase changes to a poly domain tetragonal phase and to a rhombohedral phase. In the ferroelectric tetragonal phase with a single domain state, the dielectric constant measured perpendicular to the poling direction was dramatically higher than that of the parallel direction. A large dielectric constant implies easier polarization rotation away from the polar axis. This enhancement is believed to be related to dielectric softening close to the morphotropic phase boundary and at the phase transition temperature.

• Macromolecular Research
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• 제11권1호
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• pp.9-13
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• 2003

Poly (vinylidene fluoride) (PVDF) samples were implanted by using high energy (MeV)F$^{2+}$ and Cl$^{2+}$ ions. We observed that AC dielectric constant of the ion-implanted PVDF samples decreased from 10.5 to 2.5 at 1 kHz as the ion dosage increased from 10$^{11}$ to 3 $\times$ 10$^{14}$ ions/$\textrm{cm}^2$. From differential scanning calorimetry experiments, we observed that PVDF samples become more disordered state through the ion implantation. The decrease of the number of bonding of C-H and C-F and the increase of unsaturated bonding were observed from X-ray photoelectron spectroscopy experiments. The emission of HF and H$_2$ molecules during the ion implantation was detected by residual gas analyzer spectrum. Based upon the results, we analyzed that the low AC dielectric constant of the MeV ion-implanted PVDF samples originated from the reduction of polarization due to the structural change of the CF$_2$ molecules in the MeV ion-implanted PVDF samples.les.

• 한국신뢰성학회지:신뢰성응용연구
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• 제18권3호
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• pp.271-279
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• 2018

Purpose: Probabilistic safety analysis was performed to enhance the safety and reliability of nuclear power plants because traditional deterministic approach has limitations in predicting the risk of failure by crack growth. The study introduces a probabilistic approach to establish a basis for probabilistic safety assessment of passive components. Methods: For probabilistic modeling of fatigue crack growth rate (FCGR), various FCGR tests were performed either under constant load amplitude or constant ${\Delta}K$ conditions by using heat treated X-750 at low temperature with adequate cathodic polarization. Bayesian inference was employed to update uncertainties of the FCGR model using additional information obtained from constant ${\Delta}K$ tests. Results: Four steps of Bayesian parameter updating were performed using constant ${\Delta}K$ test results. The standard deviation of the final posterior distribution was decreased by a factor of 10 comparing with that of the prior distribution. Conclusion: The method for developing a probabilistic crack growth model has been designed and demonstrated, in the paper. Alloy X-750 has been used for corrosion fatigue crack growth experiments and modeling. The uncertainties of parameters in the FCGR model were successfully reduced using the Bayesian inference whenever the updating was performed.

• Journal of Electrical Engineering and Technology
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• 제13권2호
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• pp.892-901
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• 2018

Because of excellent electrical properties, epoxy resin is widely used in packaging and casting power equipment. Moisture and temperature in the environment are inclined to seriously affect the insulation tolerance of epoxy resin. This work focuses on the aging characteristics of epoxy resin in hygrothermal environment. Scanning electron microscopy images show that there are micro-crack, micro-slit and holes inside aged samples. The moisture absorption process undergoes three equilibrium stages and it does not follow the Fick's second law. Observing the change of hydrogen bonds in the infrared spectra of the dried samples, it is found that chemically moisture absorption immerges when the physical moisture absorption entered the third equilibrium stage. By Debye equation to fit the imaginary part of the dielectric constant, it is concluded that the uniformity of water molecule has a great influence on the electrical conductivity loss. Furthermore, the polarization loss can be more easily affected by water molecules than small free molecules. After the aged samples being dried, their real and imaginary part of the dielectric constant descend, but their original electrical properties cannot completely restored. After chemical moisture absorption appears inside the material, the residual space charges increase significantly and the charge dissipation rate slow down obviously.