• Textile Coloration and Finishing
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• v.31 no.3
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• pp.147-154
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• 2019

In this study, poly(ethylene terephthalate)(PET) fibres dyed with Disperse Red 167 using supercritical $CO_2$ technology. The purpose of this study was to investigate relationship between PET fibers and supercritical $CO_2$ during dyeing. The effects of temperature, pressure, dyeing time and mass ratio between the dye and PET in the dyeing chamber were considered. Thermal and mechanical properties of the fibers were investigated. Tensile strength of dyed PET fibers decreased at higher temperature and pressure conditions. DSC and DMA results indicated that the Tg and Tm values decreased significantly when compared to the pure PET fibers. However, uniformly dyed PET fibers were typically observed.

• Textile Coloration and Finishing
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• v.32 no.4
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• pp.199-207
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• 2020

Recently, as the demand for masks increases, the use of filter-replaceable cotton masks is increasing. A filter-replaceable cotton mask is one of the ways to solve the environmental problems of a disposable nonwoven mask because only the filter can be replaced after washing. Cotton fiber products are known to be environmentally friendly, but cotton products dyed with general synthetic dyes are not safe for humans. In this study, to prepare of cotton mask applied with natural dyeing, the optimal dyeing conditions are set when dyeing with gallnut extract. A polychromatic natural dye that changes color by mordant, and the functionalities of gallnut dyeing fabrics are evaluated. The experimental method is dyed the gallnut by temperature and time by concentration to set the optimal conditions. The color fastness rating grade of aluminium potassium sulfate dodecahydrate, copper(ll) sulfate pentahydrate, and iron(ll) chloride tetrahydrate were evaluated after the pre/post mordanting.

• Textile Coloration and Finishing
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• v.34 no.2
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• pp.127-133
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• 2022

With the increasing interest in the expression of individuality and appearance of modern people, it is time to conduct research and development of novel hair coloring from various angles. Therefore, taking into account the order of discoloration of hair pigments, we selected a creative and novel emulsion as a novel material for hair coloring, rather than a cosmetic material such as hot water extract using natural products dealt with in previous studies, commercially available hair manicure, and oxidation hair dye for hair. Thus, the change in tensile strength and elongation of hair samples by color was studied. As a result of the study, hair with green emulsion paint had a significantly higher maximum load, maximum stress, maximum elongation and breaking load, breaking stress, breaking elongation values are shown. Maximum in terms of modulus, green emulsion applied hair and the control group were higher in the 0-15s strain and 15-145s sections, respectively, and the tangential modulus value was much higher in the control group than the experimental group hairs in all the 0-145s sections. This study, which analyzes the dynamic changes of hair samples that extend the daily color gamut, will greatly contribute to the development of innovative hair coloring materials in the research and production of hair beauty works, and it is judged that it will also contribute to the development of the beauty industry.

• Membrane Journal
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• v.32 no.4
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• pp.227-234
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• 2022

Wastewater is released from leather, textile, paint, wood, or dye processing industries as well as petroleum refining industries. Wastewater from these industries contains water pollutant such as heavy metals and nitrogen compounds and has high chemical oxygen demand (COD). While there various filtering pollutants from wastewater for safe disposal, membrane-based technology is one of the most efficient methods for its high efficiency and low cost. Among various membranes, zeolite membranes gain spotlight for its cost-effectiveness and have undergone a lot of research. This review is focused on recent progress in zeolite membrane for wastewater treatment in following order: i) wastewater treatment, ii) microfiltration membrane, iii) hollow fiber membrane, and iv) ultrafiltration membrane.

• Textile Coloration and Finishing
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• v.35 no.2
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• pp.67-81
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• 2023

This study aims to examine the possibility of using dried Dondropanax morbiferus extract as a functional dye. The leaves and branches of were extracted with distilled water and 30% ethanol, and the dyeability and functionality of silk fabrics were examined according to the color characteristics of the extract and dyeing conditions. As a result of analyzing the ultraviolet and visible light absorption spectrum of the extract, it was possible to confirm the peak of flavonoid belonging to polyphenol, and the peak of riboflavin expressing yellow color was confirmed. Adsorption equilibrium was observed at 4% dyeing concentration and 60 minutes of dyeing time, and as the temperature increased, dyeing amount increased without color change of Y-series. Aluminum mordanting also increased the yellow color. The color fastness of washing and UV irradiation was low, but the color fastness of rubbing was evaluated as relatively good. The silk fabric dyed with the distilled water extract of the leaves showed a 99.9% bacteriostatic reduction against Staphylococcus aureus and Klebsiella pneumoniae, showing excellent antibacterial properties.

• Journal of Conservation Science
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• v.28 no.2
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• pp.119-129
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• 2012

Excavated textiles provide very important research data on the costume culture of the Joseon dynasty. In particular, dyed textiles are indispensable for textile conservation research and for restoration of remains as well as for general costume culture research. Unfortunately, a prolonged burial environment causes the colors to change and gradually fade after excavation. Therefore, it is very difficult to identify the original color. In this study, natural dyed samples of red, yellow, purple and blue were prepared and analyzed using HPLC-PDA. Dyes of colorants extracted from excavated textile remains were analyzed by HPLC. In addition, mordants were analyzed using (SEM-EDX) in order to estimate the original color. The 16~17th Century's three samples were analyzed, sample 1, and 2 from Eunjin Song's Song Mun-Chang excavated at the Songchon-dong in Daejeon, and sample 3 from Yeosan Song's Song, Hee-Jong excavated at the Mokdal-dong in Daejeon. From the HPLC results, alizarin, purpurin, and indigo were detected on sample 1, alizarin and purpurin on sample 2, ellagic acid and indigo on sample 3. Therefore they were dyed with madder and indigo (sample 1), madder (sample2), pomagranted and indigo (sample 3). Al mordant was identified on three samples.

• Journal of Environmental Science International
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• v.20 no.9
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• pp.1087-1093
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• 2011

The mixotrophic marine ciliate Mesodinium rubrum possesses a highly modified algal endosymbiont as a nutrition source for the species. Accordingly, we assumed that the species can reflect the ecotoxicity on marine producer (as phytoplankton) and consumer (as zooplankton) both. A series of experiments were conducted to identify the potential of the species as a standard test species for marine ecotoxicological study. The comparison of species sensitivity on reference toxic materials was made using potassium dichromate for phytoplankton and copper chloride for zooplankton. The ciliate revealed the highest sensitivity on both reference materials among the seven test species including phytoplankton, benthic copepod and rotifer species. The toxicity end point of the species was 72hr-$EC_{50}$=1.52 mg/L (as potassium dichromate) estimated by population growth inhibition (PGI), which is more sensitive than the most sensitive phytoplankton Skeletonema costatum (72hr-$EC_{50}$=3.05 mg/L). As comparison to rotifer, it also revealed higher sensitivity on copper chloride; 72hr-$EC_{50}$=0.38 mg/L for ciliate and 48hr-$EC_{50}$=0.48 mg/L for rotifer. Also, the elutriate toxicity test of various ocean disposal wastes were conducted to identify the potential of ciliate toxicity test application using industrial waste sludges. The toxicity of leather processing waste sludge was highest on the ciliate, followed by dyeing waste sludge and dye production waste sludge as an increasing order of toxicity. 72h-$EC_{50}$ of ciliate PGI test was 1.83% and that of S. costatum 3.84% for leather waste sludge which showed highest toxicity. The toxicity test results also revealed that the highest sensitivity was observed on ciliate species on ocean disposed sludge wastes. Also, ciliate toxicity test well discriminated the degree of toxicity between sludge sources; 72h-$EC_{50}$ values were 1.83% for leather processing waste sludge, 16.75% for dye production waste sludge and 27.75% for textile production waste sludge. Even the laboratory culture methods of the species were not generally established yet, the species has high potential as the standard test species for marine toxicity test in terms of the dual reflection of phyto- and zooplankton toxicity from single test, sensitivity and test replicability.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.485-491
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• 2012

Due to increase in production of the domestic textile industry, energy consumption in textile industry is still growing. Traditional dyeing machine has high temperature and pressure. Accordingly, it uses an indirect cooling system that utilize a heat exchanger to cool after the dyeing. However, this indirect cooling system consumes a great deal of water, takes prolonged periods of time to process and, most importantly, because of the condensing of the dye at the cooling stage requires further energy in reduction cleaning and washing process. Therefore, in this paper, we propose a direct cooling washing machine that replaces the traditional indirect cooling system to provide coolant into the dyeing machine. The newly proposed direct cooling washing machine will still use parts of the traditional dying but will be able to skip the cooling as well as the reduction cleaning and washing process, resulting in less processing time and lower energy consumption. Also, we made a prototype. The prototype was applied to dyeing machine to test the direct cooling washing machine's ability and dyeing property. Additionally, we compared indirect cooling washing machine with direct cooling washing machine about ability, material and energy saving assessment.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.184-188
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• 2008

This study presented simple and efficient fabrication of chemical sensors for the detection of acidic gas using 1,3-bisdicyanovinylindane as an indicator because it can be promising materials having property of the rapid color change according to the variation of pH. The dissociation of proton and dye in acidic condition as changing of ion pairs give rise to dramatically change the absorbance intensity of 1,3-bisdicyanovinylindane, which can be easily applied to the development of chemical sensors. In addition, indicator dyes having negatively charge in aqueous phase can be easily fabricated using layer-by-layer (LBL) methods by way of electrostatic interaction. For the proof of concept, we demonstrated the abrupt presentation of skeleton symbol on the chemical sensor, which could be resulted from the reaction of 1,3-bisdicyanovinylindane as background color with acidic gas. Thus, the rapid appearance of symbol will induce user's caution under the emergency condition. The presented chemical gas sensor using 1,3-bisdicyanovinylindane have strong advantages. First, the fabrication process of gas sensor was very simple and low-cost. Secondly, sensors reacted by acidic gas could be reused for several times. Finally, the chemical gas sensor would be environmentally friend, which can be a basic tool for the realization of eco-organic sensor device.

• Textile Coloration and Finishing
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• v.35 no.4
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• pp.196-205
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• 2023

Water-dispersed pigment is on-going study for without air pollution in the textile and print industry. Primer treatment is essential for the substrate to improve the printing quality of eco-friendly water-dispersed pigment ink. Otherwise in the case of untreated primer, the water-dispersed pigment ink will dry onto the surface and cause defective images. This study was conducted on film substrate coating (primer) to fix eco-friendly water-dispersed pigment ink on film substrate. The drying, bleeding, and color strength of the pigment ink were examined depending on the composition and mixing ratio of the coating solution. The mixing ratio of silica gel in the coating film is increased to 0, 0.5, 1, 2 and 3 and results that DK-1-3 of silica gel ratio of 1 showed the lowest bleeding such as 52%, the letter thickness of 0.76mm and DK-1-5 of SG ratio of 3 showed the highest bleeding such as 304%, the letter thickness of 2.02mm. The mixing ratio of SPA in the coating film is increased to 2.5, 5, 7.5, SPA ratio of 7.5 has a bleeding ratio of 9% and letter thickness of 0.544mm. It showed the closest value to 0.5mm. According to the result, the optimal mixing ratio of binder, polymer coagulant, silica gel is 100:7.5:1.