• Title/Summary/Keyword: tetrahydrofuran

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Field Emission Characteristics of Double-walled Carbon Nanotubes Related with Hydrochloric Acid Treatment (이중벽 탄소나노튜브의 염산처리 시간에 따른 전계방출 특성 평가)

  • Jung, Da-Mi;Sok, Jung-Hyun
    • Journal of the Korean Vacuum Society
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    • v.20 no.1
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    • pp.70-76
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    • 2011
  • High-quality double-walled carbon nanotubes (DWCNTs) were synthesized by catalytic decomposition method at $800^{\circ}C$ using Tetrahydrofuran. The as-synthesized DWCNTs typically have catalytic impurities and amorphous carbon, which were removed by two-step purification process, consisting of thermal oxidation and H2O2, HNO3, HCl treatment. The DWCNT suspension was prepared by dispersing the purified DWCNTs in an aqueous sodium dodecylbenzenesulfonate solution with horn-type sonication. This was then sprayed on ITO glass to fabricate CNT field emitters. The quality of purified DWCNTs was estimated with X-ray diffraction and Thermal Gravity Analysis. The field emission properties were improved by increasing the process time of HCl treatment.

Preparation of Mullite Precursor Using Silicic Acid Extracted by Tetrahydrofuran from Sodium Silicate (규산나트륨으로부터 Tetrahydrofuran으로 추출된 규산을 이용한 Mullite 전구체 제조)

  • 노재성;홍성수;이범재;이병기;박은희;정홍호
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.915-920
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    • 1996
  • Fine mullite precursor was prepared by colloidal sol-gel processes. Aluminum isopropoxide $[Al(i-OC_3H_7)_3]$ as a starting material of $Al_2O_3$ and silicic acid extracted by THF from sodium silicate as a starting material of $SiO_2$ were used. Sodium silicate was first acidified by dilute sulfuric acid to form silicic acid. ; followed by extraction using THF, Mullite precursor was synthesized by sol-gel processes from aluminum isopropoxide and sillicic acid considering the degree of extraction of Si and the removal efficiency of Na. The impurity content of silicic acid extracted by THF was below 0.04% Synthetic mullite precursor consisted of $3Al_2O_3{\cdot}2SiO_2$ and showd spherical particles of $0.05{\mu}m$ diameter and below 0.462% of impurites. The mullite precursor was characterized by EDS, XRD, TG/DSC SEM, FT-IR spectroscopy ICP and TEM.

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A Study on the Synthesis of Dipyrrolylbenzenes (Dipyrrolylbenzene들의 합성에 관한 연구)

  • 정대일;변석인;송현애;이도훈;김윤영;이용균;박유미;최순규;한정태
    • Journal of Life Science
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    • v.13 no.6
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    • pp.836-842
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    • 2003
  • 1-(2-Aminophenyl)pyrrole 5 was synthesized by using 1,2-phenylenediamine with 2,5-dimethoxy-tetrahydrofuran in glacial acetic acid. 1-(3-Aminophenyl)pyrrole 7 and 1,3-dipyrrolylbenzene 8 were obtained by using 1,3-phenylene-diamine with 2,5-dimethoxytetrahydrofuran in glacial acetic acid. 1,4-Dipyrrolylbenzene 10 was synthesized by using 1,4-phenylenediamine with 2,5-dimethoxy-tetrahydrofuran in glacial acetic acid. Aminophenylpyrroles 5, 7 and dipyrrolylbenzenes 8, 10 were respectively synthesized by treatment of 1,2-phenylenediamine, 1,3-phenylenediamine, 1,4-phenylene-diamine and 2,5-dimethoxytetrahydrofuran in (1) no solvent or (2) acrylic acid or (3) silica gel or (4) acrylic acid and silica gel or (5) silica gel and glacial acetic acid instead of glacial acetic acid. The best yield for dipyrrolylbenzene 10 was obtained when silica gel and glacial acetic acid was used. 9-Phenyl-carbazole 11 was synthesized by treatment of 1-phenylpyrrole with 2,5-dimethoxy-tetrahydrofuran in glacial acetic acid.

Triglyceride Composition of Hazel Nut by HPLC (HPLC에 의한 개암종실중(種實中)의 트리글리세리드 조성(組成)에 관(關)한 연구(硏究))

  • Kim, Mi-Ran;Ko, Young-Su;Chung, Bo-Sup
    • Korean Journal of Food Science and Technology
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    • v.14 no.2
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    • pp.122-124
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    • 1982
  • The triglyceride composition of Korean hazel nut (Corylus heterophylla Fisch. var. Japonica koidz) was determined by high performance liquid chromatography (HPLC) using a $C_{18}$ micro Bondapack column with acetonitril-chloroform-tetrahydrofuran(75 : 15 : 10, v/v/v) and acetonitril-tetrahydrofuran (70 : 30, v/v) solvent mixtures as mobile phase. The triglyceride consisted of 4.14% $C_{38}$, 5.23% $C_{40}$, 10.03% $C_{42}$, 24.02% $C_{44}$, 48.73% $C_{46}$ and 7.85% $C_{48}$ with acetonitril-chloroform-tetrahydrofuran (75 : 15 : 10, v/v/v) mobile phase and 4.51% $C_{38}$, 5.98% $C_{40}$, 11.45% $C_{42}$, 25.14% $C_{44}$ and 52.92% $C_{46}$ with acetonitril-tetrahydrofuran (70 : 30, v/v) mobile phase.

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Bromocycloetherification Using NBS-Acetonitrile

  • Cook, Chae-Ho;Cho, Youn-Sang;Jew, Sang-sup;Jung, Young-Hoon
    • Archives of Pharmacal Research
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    • v.8 no.1
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    • pp.39-41
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    • 1985
  • Bromocycloetherification of a series of 3-and 4-olefinic alcohols using NBS-acetonitrile gave corresponding bromo-tetrahydrofuran with high regio and steroselectivity.

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Lithium Ion Selective Electrode Based on a Synthetic Neutural Carrier (중성운반체를 이용한 리튬이온 선택 전극)

  • Kim, Jae Sang
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.33-39
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    • 1992
  • THF-based crown-4 of 16-membered rings having tetrahydrofuran unit was synthesized by an acid-catalyzed condensation of furan and acetone followed by hydrogenation in an effort to obtain highly elective ionophores for lithium ions. The new ionophore was compared with previously reported ionophores under similar measurement conditions with the same plasticizer, tris(2-ethylhexyl) phosphate in poly(vinyl chloride)(PVC) membrane electrodes. Separate solution method was used to determine relative selectivity coefficients for the electrode. The selectivity coefficients($K_{LiM}^{POT}$) of lithium over ammonium, alkali and alkaline earth metal ions go from about $2.4{\times}10^{-1}$ to $2.3{\times}10^{-4}$ to working range and pH dependence have also been studied.

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