• Title/Summary/Keyword: temperature standards

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A Study on the Treatment of Combustible Wastes and the Resource Recovery by Pyrolysis (熱分解에 의한 可燃性 廢棄物의 처리 및 資源回收에 관한 연구)

  • Kim, Sam-Cwan;Zong, Moon-Shik
    • Journal of Environmental Health Sciences
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    • v.13 no.1
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    • pp.17-33
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    • 1987
  • As a result of technical advances and industrialization, the characteristics of domestic and industrial wastes are becoming more complex. Accordingly, improved treatment and disposal systems are being continuously sought to take account of complex characteristics and to comply with economic restrictions. In this study, an application of pyrolysis to the treatment of industrial wastes, including waste scrap rubber, waste raw material used in making the slipper bottom and waste PVC pipe, and the effectiveness of pyrolysis in resource recovery from these wastes were investigated. Batches of wastes were pyrolysed by external heating to a temperature of 400-800$\circ$C in a 32 mm diameter x 0.9 m long silica tube to produce combustible gases, oils and chars. Before the start of pyrolysis runs, the entire system was purged with nitrogen gas to exclude the air. The temperature inside the retort was controlled by the thermocouple in the gas stream, and referred to as the pyrolysis temperature. Under these conditions three products were separately collected and further analyzed. The results were summarized as follows. 1. More gases and less chars were produced with higher pyrolyzing temperature and with higher rates of heating, but the yields of oils tended downwards at temperatures above 700$\circ$C. Accordingly, operating conditions of pyrolysis should be varied with desired material. 2. Calorific values and sulfur contents of produced oils were sufficient and suitable for fuel use. Chars from waste rubber had high heating values with low sulfur contents, but calorific values of chars from waste PVC and waste slipper were as low as 3, 065-4, 273 kcal/kg and 942-2, 545 kcal/kg, respectively. Therefore, char from these wastes are inappropriate for fuel. 3. Soluble contents of Pb, Cd, Cu and Zn in chars from waste rubber and waste slipper were below the Specific Hazardous Waste Treatment Standards. However soluble contents of Pb and Cd in chars from waste PVC were one or two times and five or seven times exceedingly the Specific Hazardous Waste Treatment Standards, respectively. 4. Post high heating is desirable for treatment method of waste PVC which generates toxic hydrogen chloride. 5. The proportions of hydrogen, methane and ethane in produced gases were in the range of 3.99-35.61% V/V, 18.22-32.50% V/V and 5.17-5.87% V/V, respectively. 6. Pyrolysis is a useful disposal method in case of waste slipper, which was hardly combustible, and thus investigations of this kind of materials are required for effective management of industrial waste. 7. Based upon the possible market development for products, overall pyroly economics to take account of treatment values of noncombustible or hazardous materials should be evaluated.

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The Effect of Contamination of Ion Source on Ionic Current of Quadrupole Mass Spectrometer (사중극 질량 분석기의 이온소스 오염이 이온전류에 미치는 영향)

  • Lee, K.C.;Park, C.J.;Kim, J.T.;Oh, E.S.;Hong, K.S.;Hong, S.S.;Lim, I.T.;Yun, J.Y.;Kang, S.W.;Shin, Y.H.
    • Journal of the Korean Vacuum Society
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    • v.18 no.3
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    • pp.197-202
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    • 2009
  • The long term stability of ion current of QMS has been one of key parameters for monitoring gas process in vacuum. The time dependence of ionic current was monitored while the pressure of nitrogen gas was kept at a fixed pressure by introducing the gas into vacuum chamber. The chamber was evacuated to ${\sim}3{\times}10^{-9}\;Torr$ to reduce background signals before the measurement. Two ion sources were tested; one had brownish or black color due to gas contamination and the other one was new, i.e. cleaner. At a nitrogen pressure of $1{\times}10^{-5}\;Torr$, the ionic currents measured by the contaminated ion source decreased faster with time. The decrease rate was respectively ${\sim}46%$ for cleaner one and ${\sim}84%$ for contaminated one after ${\sim}5.5%$ hours. In order to test the effect of filament material on the ion current decrease, we fabricated a tungsten(W) filament which consisted of two parts; one half was made of W and the other was coated with yttria. The similar decrease of ionic currents were shown for the two types of filaments, indicating that slight change of temperature of filament due to material difference i.e. baking effect could not improve the origin of ionic current decrease. Overall the decreasing rate of ionic current is more closely associated with contaminated ion source of QMS rather than its filament materials.

Magnetic Properties of $NdFe_{10.7}TiB_{0.3}N_x$ and $NdFe_{10.7}TiMo_{0.3}N_x$ ($NdFe_{10.7}TiB_{0.3}N_x$$NdFe_{10.7}TiMo_{0.3}N_x$의 자기특성)

  • Kim, Yun-Bae;Kim, Hui-Tae;Kim, Chang-Seok;Kim, Taek-Gi
    • Journal of the Korean Magnetics Society
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    • v.2 no.3
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    • pp.239-243
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    • 1992
  • It has been found that B is very effective for the increase of magnetization and Curie temperature in $NdFe_{11}TiN_x$-type compounds having $ThMN_{12}$-type structure. Experimental results have shown that magnetization and Curie temperature of $NdFe_{10.7}TiB_{0.3}N_x$ are 148 $Am^2$/kg and $560^{\circ}C,$ respectively, by about 20 $Am^2$/kg and $90^{\circ}C$ higher than those of $NdFe_{10.7}Ti_{1.3}N_x.$ On the other hand, Mo is effective for the increase of anisotropy field, and it seems to strongly inhibit the formation of ${\alpha}-Fe$ phase during the nitrification treatement. The anisotropy field of $NdFe_{10.7}TiMo_{0.3}N_x$ is about 7960 kA/m (100 kOe) which is about 1590 kA/m (20 kOe) higher than that of $NdFe_{10.7}Ti_{1.3}N_x$.

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Degradation Evaluation of High Pressure Reactor Vessel in field Using Electrical Resistivity Method (전기비저항법을 이용한 고압반응기 열화도 현장평가)

  • Park, Jong-Seo;Baek, Un-Bong;Nahm, Seung-Hoon;Han, Sang-In
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.5
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    • pp.377-383
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    • 2005
  • Because explosive fluid is used at high temperature or under high pressure in petrochemistry and refined oil equipment, the interest about safety of equipments is intensive. Specially, the safety of high pressure reactor vessel is required among them. The material selected in this study is 2.25Cr-1Mo steel that is widely used for high pressure reactor vessel material of petrochemical plant. Eight kinds of artificially aged specimens were prepared by differing from aging periods under three different temperatures. The material was iso-thermally heat treated at higher temperatures than $391^{\circ}C$ that is the operating temperature of high pressure reactor vessel. Vickers hardness properties and electrical resistivity properties about artificially aged material as well as un-aged material were measured, and master curves were made out from the correlation with larson-Miller parameter. And electrical resistivity properties as well as Victors hardness properties measured at high pressure reactor vessel of the field were compared with master curves made out in a laboratory. Degradation evaluation possibility in the field of high pressure reactor vessel by using electrical resistivity method was examined. Electrical resistivity property measured in the field is similar with that of artificially aged material in similar aging level.

Degradation Evaluation of Mechanical Properties for 12Cr Ferrite Heat Resisting Steel by Reversible Permeability (가역투자율에 의한 12Cr 페라이트 내열강의 역학적 물성의 열화평가)

  • Ryu, Kwon-Sang;Kim, Min-Gi;Nahm, Seung-Hoon;Kim, Chung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.464-470
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    • 2010
  • The integrity of the industrial equipment in use under high temperature and high pressure must be assessed by regularly measuring the degraded mechanical properties during service time. In order to nondestructively monitor the degraded mechanical properties of industrial equipment, a measuring method of the reversible permeability(RP) using surface type probe is presented. The method for measuring the RP is based on that RP is the differential value of hysteresis loop. The RP is exactly the foundation hatmonics induced in a detecting coil measured by lock-in amplifier tuned to a frequency of the alternating perturbing magnetic field. The peak of RP is measured around the coercive force. Steel material used in this work was 12Cr ferritic heat resisting steel. The eleven kinds of samples aged during different times under same temperature ($700^{\circ}C$) were prepared. Peak interval of reversible permeability(PIRP), Vickers hardness, and tensile strength measured for the aged samples decreased abruptly for short aging time (below 500 h), but the change became small at a long aging time. Vickers hardness and tensile strength linearly decreased as RIRP decreased, so the degraded mechanical properties of 12Cr ferritic heat resisting steel could be nondestructively evaluated by measuring RIRP.

Review of the Conceptual Design for the use of the HTS Cable to Power System (고온초전도케이블의 계통적용을 위한 개념설계)

  • Choi, Sang-Bong;Kim, Dae-Kyeong;Jeong, Seong-Hwan;Moon, Young-Hwan;Seong, Ki-Chul;Kim, Hak-Man
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.253-255
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    • 2002
  • The necessity of compact high temperature super conducting cables is more keenly felt in densely populated metropolitan areas. As the compact high temperature superconducting cables that can be installed in ducts and tunnels can reduce construction cost and make the use of underground space more effective, the effect of introducing it to power system will be huge. For this study, Seoul, Korea is selected as a review model, the loads are estimated by scenario based on a survey and analysis of 345kV and 154kV power supply networks in this area. Based on this, the following items on urban transmission system are examined. (1) A method of constructing a model system to introduce high temperature superconducting cables to metropolitan areas is presented. (2) A case study through the analysis of power demand is conducted, and the amount of high temperature superconducting cable to be introduced by scenario is examined. (3) The economy involved in expanding existing cables and introducing high temperature superconducting cables(ducts or tunnels) following load increase in urban areas is examined and compared. (4) The maximum external diameter of HTS cable to accommodate exiting ducts based on the design standards for current cable ducts is calculated. (5) The voltage level that can be accommodated by existing ducts is examined.

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The Effect of Changes in Polymerization Conditions of Orthodontic Acrylic Resin on Maximum Load (Orthodontic Acrylic Resin의 중합조건 변화가 최대하중에 미치는 영향)

  • Lee, Gyu Sun
    • Journal of Technologic Dentistry
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    • v.35 no.2
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    • pp.127-136
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    • 2013
  • Purpose: In order to find out the impact of changes in polymerization conditions of orthodontic acrylic resin on maximum load. Methods: While maintaining mixing ratio 3:1 of polymer and monomer in spray-on way in the production condition of polymerization temperature $25^{\circ}C$ or $37^{\circ}C$ for 10 minutes or 30 minutes of polymerization time by pressure $3kfg/cm^2$ or $6kfg/cm^2$ in the lab maintaining $25^{\circ}C$ of room temperature, the change in maximum load rise rate was tested by producing 5 acrylic resin specimens for orthodontics per group to meet the standards of $25mm{\times}2mm{\times}2mm$ and using INSTRON with the 3rd bar 2mm in diameter and parallel support bending device of $15{\pm}0.1mm$ as test equipment showing 30.00mm/min of crosshead speed, $50{\pm}16$ N/min of load ratio in the laboratory of $24^{\circ}C$ room temperature and as a result, the following results were obtained. Results: 1. When increasing pressure from $3kfg/cm^2$ to $6kfg/cm^2$, maximum load was lowered by -4.285%. 2. When increasing polymerization time from 10 minutes to 30 minutes, maximum load rose by 3.848%. 3. When increasing polymerization temperature from $27^{\circ}C$ to $37^{\circ}C$, maximum load rose by 5.854%. Conclusion: Considering the above test results that polymerization time and polymerization temperature when polymerizing acrylic resin for orthodontics according to changes in working conditions had an impact on the rate of rise of maximum load values but the rate of rise was lowered when increasing pressure from $3kfg/cm^2$ to $6kfg/cm^2$, we came to a conclusion that high pressure more than necessary does not affect the rate of rise of maximum load.

LEED Certification and Its Effectiveness on Urban Heat Island Effect

  • Kim, Hwan-Yong;Gu, Dong-Hwan
    • Journal of KIBIM
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    • v.5 no.4
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    • pp.30-36
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    • 2015
  • The Leadership in Energy and Environmental Design (LEED) has provided abundant resources and guidelines for a new project to become a sustainable anchor in the neighborhood. Paired with a range of checklist, LEED has strong influence on the standards for a sustainable building, and it also has played an iconic role in energy-efficient architecture. However, it is still unclear as to whether or not an LEED certified building enhances environmental benefits to its surroundings. If an LEED certification promises a baseline for an eco-friendly building, then a group of these structures should ensure significant environmental benefits to the society. This is the main question of this study, and the authors answer this hypothesis by examining the relationship of LEED certificates and their influence on outdoor temperature, especially in terms of urban heat island effect. The goal of this paper is to analyze the influence of the LEED certification on urban temperature as an indicator of sustainable architecture's regional interactions. If an LEED certificate is regarded as a strong contributor to a sustainable built environment, then a group of these certificates should result in greater benefits to society. To this extent, the authors question if there is any possible relationship between a large concentration of LEED certified sites and the temperature of their surroundings. To properly assess the research direction, Global Moran's I analysis, Local Moran's I analysis, and Hot Spot analysis are implemented to find the clustered areas of LEED certified buildings. For examining relationships between clustered area and its temperature, correlation efficients are calculated.

Integrated fire dynamics and thermomechanical modeling framework for steel-concrete composite structures

  • Choi, Joonho;Kim, Heesun;Haj-ali, Rami
    • Steel and Composite Structures
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    • v.10 no.2
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    • pp.129-149
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    • 2010
  • The objective of this study is to formulate a general 3D material-structural analysis framework for the thermomechanical behavior of steel-concrete structures in a fire environment. The proposed analysis framework consists of three sequential modeling parts: fire dynamics simulation, heat transfer analysis, and a thermomechanical stress analysis of the structure. The first modeling part consists of applying the NIST (National Institute of Standards and Technology) Fire Dynamics Simulator (FDS) where coupled CFD (Computational Fluid Dynamics) with thermodynamics are combined to realistically model the fire progression within the steel-concrete structure. The goal is to generate the spatial-temporal (ST) solution variables (temperature, heat flux) on the surfaces of the structure. The FDS-ST solutions are generated in a discrete form. Continuous FDS-ST approximations are then developed to represent the temperature or heat-flux at any given time or point within the structure. An extensive numerical study is carried out to examine the best ST approximation functions that strike a balance between accuracy and simplicity. The second modeling part consists of a finite-element (FE) transient heat analysis of the structure using the continuous FDS-ST surface variables as prescribed thermal boundary conditions. The third modeling part is a thermomechanical FE structural analysis using both nonlinear material and geometry. The temperature history from the second modeling part is used at all nodal points. The ABAQUS (2003) FE code is used with external user subroutines for the second and third simulation parts in order to describe the specific heat temperature nonlinear dependency that drastically affects the transient thermal solution especially for concrete materials. User subroutines are also developed to apply the continuous FDS-ST surface nodal boundary conditions in the transient heat FE analysis. The proposed modeling framework is applied to predict the temperature and deflection of the well-documented third Cardington fire test.

Energy Modeling of a Supertall Building Using Simulated 600 m Weather File Data

  • Irani, Ali;Leung, Luke;Sedino, Marzia
    • International Journal of High-Rise Buildings
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    • v.8 no.2
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    • pp.101-106
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    • 2019
  • Assessing the energy performance of supertall buildings often does not consider variations in energy consumption due to the change of environmental conditions such as temperature, pressure, and wind speed associated with differing elevations. Some modelers account for these changing conditions by using a conventional temperature lapse rate, but not many studies confirm to the appropriateness of applying it to tall buildings. This paper presents and discusses simulated annual energy consumption results from a 600 m tall skyscraper floor plate located in Dubai, UAE, assessed using ground level weather data, a conventional temperature lapse rate of $6.5^{\circ}C/km$, and more accurate simulated 600 m weather data. A typical office floorplate, with ASHRAE 90.1-2010 standards and systems applied, was evaluated using the EnergyPlus engine through the OpenStudio graphical user interface. The results presented in this paper indicate that by using ground level weather data, energy consumption at the top of the building can be overestimated by upwards of 4%. Furthermore, by only using a lapse rate, heating energy is overestimated by up to 96% due to local weather phenomenon such as temperature inversion, which can only be conveyed using simulated weather data. In addition, sizing and energy consumption of fans, which are dependent both on wind and atmospheric pressure, are not accurately captured using a temperature lapse rate. These results show that that it is important, with the ever increasing construction of supertall buildings, to be able to account for variations in climatic conditions along the height of the building. Adequately modeling these conditions using simulated weather data will help designers and engineers correctly size mechanical systems, potentially decreasing overall building energy consumption, and ensuring that these systems are able to provide the necessary indoor conditions to maintain occupant comfort levels.